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61. 发明授权

US06486359B1 Catalyst comprising a complex of a metal of subgroup viii based on a phosphinite ligand, and a method for hydroformylation 失效
标题翻译：包含基于磷化物配体的亚基viii金属的络合物的催化剂和加氢甲酰化的方法
公开(公告)号：US06486359B1
公开(公告)日：2002-11-26
申请号：US09719353
申请日：2000-12-12
申请人： Heiko Maas , Rocco Paciello , Michael Röper , Jakob Fischer
发明人： Heiko Maas , Rocco Paciello , Michael Röper , Jakob Fischer
IPC分类号： C07C4550
CPC分类号： C07F15/008 , B01J31/1875 , B01J2231/321 , B01J2531/0266 , B01J2531/56 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C45/50 , C07C253/10 , C07F9/657163 , C07F9/65719 , C07C47/02 , C07C255/04
摘要： The invention relates to a catalyst which comprises at least one complex of a metal of group VIII, which comprises at least one uni-, bi- or multidentate phosphinite ligand in which the phosphorus atom and the oxygen atom of the phosphinite group are part of a 5- to 8-membered heterocycle, and to processes for hydroformylation and hydrocyanation of compounds which contain at least one ethylenic double bond in the presence of a catalyst of this type.
摘要翻译：本发明涉及一种催化剂，其包含至少一种第VIII族金属的络合物，其包含至少一种一元，二元或多数的磷化物配位体，其中磷原子和磷酸基团的氧原子是 5至8元杂环，以及在这种催化剂存在下含有至少一个烯属双键的化合物的加氢甲酰化和氢化氰化方法。

62. 发明授权

US08877965B2 Process for preparing formic acid by reaction of carbon dioxide with hydrogen 有权
标题翻译：通过二氧化碳与氢气反应制备甲酸的方法
公开(公告)号：US08877965B2
公开(公告)日：2014-11-04
申请号：US13171928
申请日：2011-06-29
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
IPC分类号： C07C51/15 , C07F15/00 , C07C53/00 , C07C51/44 , C07C51/48
CPC分类号： C07C51/44 , C07C51/15 , C07C51/48 , C07C53/02
摘要： A process for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, where the work-up of the output (3) from the hydrogenation reactor (I) is carried out by addition of water so as to increase the distribution coefficient of the catalyst between the upper phase (4) and the lower phase.
摘要翻译：在含有元素周期表第8,9,10族元素的催化剂存在下，在氢化反应器（I）中，通过二氧化碳（1）与氢气（2）的反应制备甲酸的方法，每分子含有至少12个碳原子的极性溶剂和包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，其中后处理通过加入水进行加氢反应器（I）的输出（3），以增加催化剂在上相（4）和下相之间的分配系数。

63. 发明授权

US08791297B2 Process for preparing formic acid by reaction of carbon dioxide with hydrogen 有权
标题翻译：通过二氧化碳与氢气反应制备甲酸的方法
公开(公告)号：US08791297B2
公开(公告)日：2014-07-29
申请号：US13172123
申请日：2011-06-29
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Klaus-Dieter Mohl , Martin Schäfer , Stefan Rittinger , Daniel Schneider
IPC分类号： C07C51/44 , C07C53/02 , C07C51/15 , C07C51/48 , C07C51/487
CPC分类号： C07C53/02 , C07C51/15 , C07C51/48 , C07C51/487
摘要： A process for preparing formic acid by reaction of carbon dioxide (1) with hydrogen (2) in a hydrogenation reactor (I) in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine comprising at least 12 carbon atoms per molecule and a polar solvent comprising one or more monoalcohols selected from among methanol, ethanol, propanols and butanols and also water, to form formic acid/amine adducts as intermediates which are subsequently thermally dissociated, with work-up of the output (3) from the hydrogenation reactor (I) in a plurality of process steps, where a tertiary amine-comprising stream (13) from the work-up is used as selective solvent for the catalyst, is proposed.
摘要翻译：在含有元素周期表第8,9,10族元素的催化剂存在下，在氢化反应器（I）中，通过二氧化碳（1）与氢气（2）的反应制备甲酸的方法，每分子含有至少12个碳原子，以及包含一种或多种选自甲醇，乙醇，丙醇和丁醇的一元醇和极性溶剂的极性溶剂，以形成甲酸/胺加合物作为随后热解离的中间体，具有后处理提出了在多个工艺步骤中，来自加氢反应器（I）的输出物（3）的来自后处理的含叔胺的物流（13）用作催化剂的选择性溶剂。

64. 发明授权

US08785693B2 Process for the preparation of primary amines by homogeneously catalyzed alcohol amination 有权
标题翻译：通过均匀催化醇胺化制备伯胺的方法
公开(公告)号：US08785693B2
公开(公告)日：2014-07-22
申请号：US13415412
申请日：2012-03-08
申请人： Thomas Schaub , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
发明人： Thomas Schaub , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
IPC分类号： C07C209/16 , C07C209/18 , C07D265/30 , C07D241/04 , C07D295/00 , C07D207/18 , C07D207/06 , C07D295/02 , C07D317/00
CPC分类号： C07C209/16 , C07C213/02 , C07D207/04 , C07D207/20 , C07D295/023 , C07D307/52 , C07C211/07 , C07C211/09 , C07C215/08 , C07C217/08
摘要： Process for the preparation of primary amines which have at least one functional group of the formula (—CH2—NH2) by alcohol amination of starting materials which have at least one functional group of the formula (—CH2—OH), with ammonia, with the elimination of water, where the alcohol amination is carried out under homogeneous catalysis in the presence of at least one complex catalyst which comprises at least one element selected from groups 8 and 9 of the Periodic Table of the Elements, and also at least one phosphorus donor ligand of the general formula (I).
摘要翻译：具有至少一个式（-CH 2 -NH 2）官能团的伯胺的方法，其通过具有至少一个式（-CH 2 -OH）官能团的起始原料与氨进行醇胺化反应，与消除水，其中在均相催化下，在至少一种包含至少一种选自元素周期表第8和9族的元素的复合催化剂存在下进行醇胺化，以及至少一种磷通式（I）的供体配体。

65. 发明授权

US08623621B2 Method for producing optically active 2-methyl-alkanols 有权
标题翻译：光学活性2-甲基 - 链烷醇的制备方法
公开(公告)号：US08623621B2
公开(公告)日：2014-01-07
申请号：US12906654
申请日：2010-10-18
申请人： Christoph Jäkel , Gunnar Heydrich , Rainer Stürmer , Rocco Paciello
发明人： Christoph Jäkel , Gunnar Heydrich , Rainer Stürmer , Rocco Paciello
IPC分类号： C12P7/04
CPC分类号： C12P7/04 , C07B2200/07 , C07C29/14 , C07C29/141 , C07C29/172 , C12C11/02 , C07C33/025 , C07C31/125
摘要： A process for preparing optically active 2-methylalkan-1-ol of the general formula (III) comprising the following steps: (i) carbonyl-selective reduction of 2-methylalk-2-en-1-al of the general formula (I) to 2-methylalk-2-en-1-ol of the general formula (II), (ii) enantioselective hydrogenation of 2-methylalk-2-en-1-ol to the general formula (iii), (iii) increasing the optical yield of the optically active 2-methylalkan-1-ol (III) obtained in step (ii) by a lipase-catalyzed acylation reaction, where the radical R means C1-C10-alkyl.
摘要翻译：一种制备通式（III）的光学活性2-甲基烷-1-醇的方法，包括以下步骤：（i）通式（I）的2-甲基-α-烯-1-醇的羰基选择性还原）到通式（II）的2-甲基-2-烯-1-醇，（ii）2-甲基烯-2-烯-1-醇与通式（iii）的对映选择性氢化，（iii）增加通过脂肪酶催化的酰化反应在步骤（ii）中获得的光学活性2-甲基
链烷-1-醇（III）的光学收率，其中基团R是指C 1 -C 10 - 烷基。

66. 发明申请

US20130137901A1 SYNTHESIS OF POLYALKYLENEPOLYAMINES HAVING A LOW COLOR INDEX BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION IN THE PRESENCE OF HYDROGEN 有权
标题翻译：在氢存在下通过均相催化醇醇胺化合成具有低颜色指数的聚亚烷基酰胺的合成
公开(公告)号：US20130137901A1
公开(公告)日：2013-05-30
申请号：US13680625
申请日：2012-11-19
申请人： Julia STRAUTMANN , Thomas Schaub , Stephan Hueffer , Steffen Maas , Rocco Paciello
发明人： Julia STRAUTMANN , Thomas Schaub , Stephan Hueffer , Steffen Maas , Rocco Paciello
IPC分类号： C07C209/68 , C08G73/02
CPC分类号： C07C209/68 , C08G73/0213 , C07C211/11
摘要： Process for the preparation of polyalkylenepolyamines by homogeneously catalyzed alcohol amination, in which aliphatic amino alcohols are reacted with one another or aliphatic diamines or polyamines are reacted with aliphatic diols or polyols with the elimination of water in the presence of a homogeneous catalyst and in the presence of hydrogen gas. Polyalkylenepolyamines obtainable by such processes and polyalkylenepolyamines comprising hydroxy groups, secondary amines or tertiary amines. Uses of such polyalkylenepolyamines as adhesion promoters for printing inks, adhesion promoters in composite films, cohesion promoters for adhesives, crosslinkers/curing agents for resins, primers for paints, wet-adhesion promoters for emulsion paints, complexing agents and flocculating agents, penetration assistants in wood preservation, corrosion inhibitors, immobilizing agents for proteins and enzymes.
摘要翻译：通过均相催化的醇胺化制备聚亚烷基多胺的方法，其中脂肪族氨基醇彼此反应或脂族二胺或多胺与脂肪族二醇或多元醇在均相催化剂存在下与水反应，的氢气。可通过这些方法获得的聚亚烷基多胺和包含羟基，仲胺或叔胺的聚亚烷基多胺。使用这种聚亚烷基多胺作为印刷油墨的粘合促进剂，复合膜中的粘合促进剂，粘合剂的内聚力促进剂，树脂的交联剂/固化剂，油漆的底漆，乳液漆的湿粘合促进剂，络合剂和絮凝剂，渗透助剂木材保存，腐蚀抑制剂，蛋白质和酶的固定剂。

67. 发明申请

US20130102807A1 PROCESS FOR PREPARING FORMAMIDES AND FORMIC ESTERS 失效
标题翻译：制备形式和形式的方法
公开(公告)号：US20130102807A1
公开(公告)日：2013-04-25
申请号：US13559011
申请日：2012-07-26
申请人： Thomas Schaub , Rocco Paciello , Marek Pazicky , Giuseppe Fachinetti , Debora Preti
发明人： Thomas Schaub , Rocco Paciello , Marek Pazicky , Giuseppe Fachinetti , Debora Preti
IPC分类号： C07C231/10 , C07C67/36
CPC分类号： C07C231/10 , C07C67/36 , C07C233/03 , C07C69/06
摘要： A process for preparing carboxylic acid derivatives of the formula H—(C═O)—R, R is OR1 or NR2R3, R1 is optionally substituted C1-C15-alkyl, C5-C10-cycloalkyl, C5-C10-heterocyclyl, C5-C10-aryl or C5-C10-heteroaryl, substituents are C1-C15-alkyl, C1-C6-alkoxy, C5-C10-cycloalkyl or C5-C10-aryl; R2 and R3 are independently hydrogen or optionally substituted C1-C15-alkyl, C5-C10 cycloalkyl, C5-C10-heterocyclyl, C5-C10-aryl or C5-C10-heteroaryl, substituents are selected from the group consisting of C1-C15-alkyl, C5-C10-cycloalkyl and C5-C10-aryl or R2 and R3 together with the nitrogen atom form a five- or six-membered ring which optionally comprises one or more heteroatoms selected from O, S and N and bearing the substituent R4, R4 is hydrogen or C1-C6-alkyl; by reacting a reaction mixture comprising carbon dioxide, hydrogen and an alcohol of the formula R1—OH or an amine of the formula NHR2R3 in the presence of a catalyst comprising gold at a pressure from 0.2 to 30 MPa and a temperature from 20 to 200° C. in a hydrogenation reactor.
摘要翻译：制备式H-（C = O）-R，R的羧酸衍生物的方法是OR 1或NR 2 R 3，R 1是任选取代的C 1 -C 15 - 烷基，C 5 -C 10 - 环烷基，C 5 -C 10 - 杂环基， C 10 - 芳基或C 5 -C 10 - 杂芳基，取代基是C 1 -C 15 - 烷基，C 1 -C 6 - 烷氧基，C 5 -C 10 - 环烷基或C 5 -C 10 - 芳基; R 2和R 3独立地为氢或任选取代的C 1 -C 15 - 烷基，C 5 -C 10环烷基，C 5 -C 10 - 杂环基，C 5 -C 10 - 芳基或C 5 -C 10 - 杂芳基，取代基选自C 1 -C 15 - 烷基，C 5 -C 10 - 环烷基和C 5 -C 10 - 芳基或R 2和R 3与氮原子一起形成五元或六元环，其任选地包含一个或多个选自O，S和N的杂原子并带有取代基R4 R4是氢或C1-C6-烷基; 在包含金的催化剂的存在下，在0.2〜30MPa的压力和20〜200℃的温度下，使包含二氧化碳，氢和式R 1 -OH的醇或式NHR 2 R 3的胺的反应混合物反应， C.在氢化反应器中。

68. 发明申请

US20130046118A1 METHOD FOR PRODUCING OPTICALLY ACTIVE, RACEMIC MENTHOL 审中-公开
标题翻译：用于生产光学活性的，法定的MENTHOL的方法
公开(公告)号：US20130046118A1
公开(公告)日：2013-02-21
申请号：US13658003
申请日：2012-10-23
申请人： Gunnar Heydrich , Gabriele Gralla , Matthias Rauls , Joachim Schmidt-Leithoff , Klaus Ebel , Wolfgang Krause , Steffen Oehlenschläger , Christoph Jäkel , Marko Friedrich , Eike Johannes Bergner , Nawid Kashani-Shirazi , Rocco Paciello
发明人： Gunnar Heydrich , Gabriele Gralla , Matthias Rauls , Joachim Schmidt-Leithoff , Klaus Ebel , Wolfgang Krause , Steffen Oehlenschläger , Christoph Jäkel , Marko Friedrich , Eike Johannes Bergner , Nawid Kashani-Shirazi , Rocco Paciello
IPC分类号： C07C29/17
CPC分类号： C07C29/56 , C07B2200/07 , C07C29/172 , C07C29/78 , C07C45/62 , C07C45/82 , C07C2601/14 , C07C2601/16 , C07C47/21 , C07C35/12 , C07C35/17
摘要： The present invention relates to a particularly economic overall method for producing menthol, specifically for producing optically active, essentially enantiomerically and diastereomerically pure L-menthol and racemic menthol, starting from the starting material citral which is available inexpensively on an industrial scale. The method comprises the following steps a.1) catalytic hydrogenation of neral and/or geranial to give citronellal, b.1) cyclization of citronellal to isopulegol in the presence of an acidic catalyst, c.1) purification of isopulegol by crystallization and d.1) catalytic hydrogenation of isopulegol to give menthol.
摘要翻译：本发明涉及一种特别经济的制备薄荷醇的总体方法，特别用于制备光学活性的，基本上是对映异构体和非对映异构体纯的L-薄荷醇和外消旋薄荷醇，其原料柠檬醛以工业规模廉价地得到。该方法包括以下步骤a.1）在酸性催化剂的存在下，将柠檬醛和/或香叶醇进行催化氢化以产生香茅醛，b.1）将香茅醛环化成异胡仑醇，c.1）通过结晶和d进行异丙醇的纯化 .1）异丙醇的催化氢化得到薄荷醇。

69. 发明申请

US20130012739A1 PROCESS FOR PREPARING FORMIC ACID BY REACTING CARBON DIOXIDE WITH HYDROGEN 审中-公开
标题翻译：通过用氢气反应二氧化碳制备形式酸的方法
公开(公告)号：US20130012739A1
公开(公告)日：2013-01-10
申请号：US13542791
申请日：2012-07-06
申请人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Peter Bassler , Martin Schäfer , Stefan Rittinger
发明人： Thomas Schaub , Donata Maria Fries , Rocco Paciello , Peter Bassler , Martin Schäfer , Stefan Rittinger
IPC分类号： C07C51/15
CPC分类号： C07C51/44 , C07C51/48 , C07C51/487 , C07C53/02
摘要： A process for preparing formic acid by reacting carbon dioxide with hydrogen in a hydrogenation reactor in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine and a polar solvent to form formic acid-amine adducts which are subsequently dissociated thermally into formic acid and tertiary amine.
摘要翻译：在含有元素周期表第8,9或10族元素的催化剂存在下，在氢化反应器中使二氧化碳与氢反应制备甲酸的方法，叔胺和极性溶剂以形成甲酸 - 胺加成物随后被热分解成甲酸和叔胺。

70. 发明申请

US20120232294A1 PROCESS FOR PREPARING ALKANOLAMINES BY HOMOGENEOUSLY CATALYZED ALCOHOL AMINATION 有权
标题翻译：通过均相催化的醇醇胺化制备烷醇胺的方法
公开(公告)号：US20120232294A1
公开(公告)日：2012-09-13
申请号：US13415409
申请日：2012-03-08
申请人： Thomas SCHAUB , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
发明人： Thomas SCHAUB , Boris Buschhaus , Marion Kristina Brinks , Mathias Schelwies , Rocco Paciello , Johann-Peter Melder , Martin Merger
IPC分类号： C07C213/02 , C07D307/52
CPC分类号： C07C209/16 , C07C213/02 , C07D207/02 , C07D207/20 , C07D295/027 , C07D307/52 , C07C211/09 , C07C215/08 , C07C217/08 , C07C211/10 , C07C211/12
摘要： Process for preparing alkanolamines which have a primary amino group (—NH2) and a hydroxyl group (—OH) by alcohol amination of diols having two hydroxyl groups (—OH) by means of ammonia with elimination of water, wherein the reaction is carried out homogeneously catalyzed in the presence of at least one complex catalyst comprising at least one element selected from groups 8, 9 and 10 of the Periodic Table and also at least one donor ligand.
摘要翻译：制备具有伯氨基（-NH 2）和羟基（-OH）的链烷醇胺的方法，其通过用氨除去水而具有两个羟基（-OH）的二醇醇胺化，其中反应进行在包含至少一种选自元素周期表第8,9和10族的元素的复合催化剂的存在下，以及至少一种供体配体均匀催化。

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