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    • 70. 发明申请
    • ETHYLENIC RANDOM COPOLYMER, PROCESS FOR PREPARING THE SAME, AND RUBBER COMPOSITION
    • 乙烯随机共聚物,其制备方法和橡胶组合物
    • WO1997045466A1
    • 1997-12-04
    • PCT/JP1997001815
    • 1997-05-28
    • MITSUI PETROCHEMICAL INDUSTRIES, LTD.HAKUTA, TakashiHOSOYA, MikioTOJO, TetsuoKAWASAKI, Masaaki
    • MITSUI PETROCHEMICAL INDUSTRIES, LTD.
    • C08F210/18
    • C08F210/18C08F4/68C08F210/06C08F232/00C08F2500/25C08F2500/17
    • A process for preparing an ethylene/ alpha -olefin/norbornene nonconjugated polyene random copolymer, comprising preparing an ethylene random copolymer simultaneously meeting the following requirements (1) to (5): (1) the molar ratio of ethylene (a) to an alpha -olefin (b) having 3 to 20 carbon atoms ranges from 40:60 to 95:5; (2) a given amount of non conjugated polyene (c) has a norbornene skeleton; (3) the available network chain density nu is not less than 1.5 x 10 /cm after press cross-linking of the copolymer using a dicumyl peroxyde; (4) the ratio of the rate gamma 1 of shear showing a shearing stress of 0.4 x 10 dyn/cm as determined from the melt flow curve at 100 DEG C and the rate gamma 2 of shear showing a shearing stress of 2.4 x 10 dyn/cm , that is, gamma 2/ gamma 1 and the available network chain density nu has a relationship represented by the following general formula: 0.04 x 10 ; and (5) the intrinsic viscosity [ eta ] ranges from 0.5 to 10 dl/g as measured in decalin at 135 DEG C. The copolymer has excellent cross-linkability, can be cross-linked with a small amount of a peroxide or the like, and a cross-linked rubber composition prepared using this copolymer has excellent heat aging resistance, mechanical strength, weather resistance, and ozone resistance.
    • 一种制备乙烯/α-烯烃/降冰片烯非共轭多烯无规共聚物的方法,包括同时满足以下要求(1)至(5)制备乙烯无规共聚物:(1)乙烯(a)与α- 具有3-20个碳原子的α-烯烃(b)的范围为40:60至95:5; (2)给定量的非共轭多烯(c)具有降冰片烯骨架; (3)使用二枯基过氧化物进行共聚物的压制交联后,可用网络链密度nu不小于1.5×10 20 / cm 3; (4)从100℃的熔体流动曲线确定的剪切应力为剪切应力为0.4×10 6 dyn / cm 2的剪切速率γ1与剪切速率γ2的剪切比 2.4×10 6 dyn / cm 2的应力,即γ2 /γ1,可用的网络链密度nu具有由以下通式表示的关系:0.04×10 对数(γ2 /γ1)/ nu <0.20×10 <-19>; 和(5)在135℃萘烷中测定的特性粘度η为0.5-10dl / g。该共聚物具有优异的交联性,可与少量的过氧化物等进行交联 并且使用该共聚物制备的交联橡胶组合物具有优异的耐热老化性,机械强度,耐候性和耐臭氧性。