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61. 发明授权

US06310141B1 Fluoropolymer-containing compositions 有权
标题翻译：含氟聚合物的组合物
公开(公告)号：US06310141B1
公开(公告)日：2001-10-30
申请号：US09604139
申请日：2000-06-27
申请人： Lisa P. Chen , Harald Kaspar , Klaus Hintzer , Robert E. Kolb , Albert Killich
发明人： Lisa P. Chen , Harald Kaspar , Klaus Hintzer , Robert E. Kolb , Albert Killich
IPC分类号： C08L2712
CPC分类号： C08L51/003 , C08F259/08 , C08L27/12 , C08L2205/02 , C09D127/12 , C08L2666/04 , C08F214/18
摘要： Cured, latex-blended compositions featuring a fluoroelastomer and a fluoroplastic, and curable core-shell polymers having a fluoroelastomer precursor-containing shell and a fluoroplastic-containing core.
摘要翻译：固化的，具有氟弹性体和氟塑料的胶乳混合组合物，以及具有含氟弹性体前体的壳和含氟塑料的芯的可固化核 - 壳聚合物。

62. 发明授权

US06255536B1 Fluorine containing vinyl ethers 有权
标题翻译：含氟乙烯醚
公开(公告)号：US06255536B1
公开(公告)日：2001-07-03
申请号：US09470497
申请日：1999-12-22
申请人： Allan T. Worm , George G. I. Moore , Miguel A. Guerra , Werner Schwertfeger , Klaus Hintzer , Zai-Ming Qiu , Erik D. Hare
发明人： Allan T. Worm , George G. I. Moore , Miguel A. Guerra , Werner Schwertfeger , Klaus Hintzer , Zai-Ming Qiu , Erik D. Hare
IPC分类号： C07F4311
CPC分类号： C07C41/24 , C07C41/18 , C07C41/48 , C07C67/307 , C07C2601/14 , C07C69/708 , C07C43/17 , C07C43/192 , C07C43/313
摘要： The present invention describes a novel process for the preparation of perfluorovinyl ethers. The process involves providing a hydrocarbon precursor that may be partially halogenated, fluorinating the precursor to provide a perfluorinated intermediate, and converting the perfluorinated intermediate to the desired perfluorinated ether. Novel perfluorovinyl ethers are also provided.
摘要翻译：本发明描述了制备全氟乙烯基醚的新方法。该方法包括提供可以部分卤化的烃前体，氟化前体以提供全氟化中间体，并将全氟化中间体转化为所需的全氟化醚。还提供了新的全氟乙烯基醚。

63. 发明授权

US5576402A Process for the preparation of a modified polytetrafluoroethylene and its use 失效
标题翻译：制备改性聚四氟乙烯的方法及其用途
公开(公告)号：US5576402A
公开(公告)日：1996-11-19
申请号：US554466
申请日：1995-11-07
申请人： Bernd Felix , Klaus Hintzer , Gernot L ohr , Thomas Sch ottle
发明人： Bernd Felix , Klaus Hintzer , Gernot L ohr , Thomas Sch ottle
IPC分类号： C08F2/18 , C08F2/22 , C08F4/06 , C08F4/08 , C08F4/30 , C08F214/26 , C08F2/00
CPC分类号： C08F214/262
摘要： If the employment of polymerization auxiliaries in ammonium form is avoided in the preparation of a polytetrafluoroethylene having a content of 0.02 to 1% by weight of units of a perfluoro-(alkyl vinyl) ether by the suspension process, a polymer which does not tend to discoloration on heating is obtained.
摘要翻译：如果在通过悬浮法制备含有全氟（烷基乙烯基）醚的单位为0.02〜1重量％的聚四氟乙烯的情况下避免使用铵形式的聚合助剂，则不倾向于得到加热变色。

64. 发明授权

US4987254A Fluorinated carboxylic acid fluorides 失效
标题翻译：氟化氟酸氟化物
公开(公告)号：US4987254A
公开(公告)日：1991-01-22
申请号：US389367
申请日：1989-08-03
申请人： Werner Schwertfeger , Klaus Hintzer , Peter Blickle
发明人： Werner Schwertfeger , Klaus Hintzer , Peter Blickle
IPC分类号： B01J27/12 , B01J27/135 , C07B61/00 , C07C51/58 , C07C59/135
CPC分类号： C07C51/58
摘要： Fluorinated carboxylic acid fluorides of the formula I ##STR1## can be prepared from fluorinated vinyl ethers of the formula II ##STR2## by reacting the vinyl ethers with an oxygen-containing gas in the presence of a catalytic amount of a Lewis acid. Perfluorinated carboxylic acids and derivatives thereof can be prepared from the carboxylic acid fluorides by secondary reactions, for example hydrolysis, esterification or aminolysis.
摘要翻译：式I（I）的氟化羧酸氟化物可以由式II（II）的氟化乙烯基醚通过乙烯基醚与含氧气体在催化量的路易斯酸。全氟羧酸及其衍生物可以通过二次反应由羧酸氟化物制备，例如水解，酯化或氨解。

65. 发明授权

US4808651A Solutions of fluoropolymers, and their use 失效
标题翻译：含氟聚合物的溶液及其用途
公开(公告)号：US4808651A
公开(公告)日：1989-02-28
申请号：US96653
申请日：1987-09-15
申请人： Peter Blickle , Klaus Hintzer , Gernot Lohr , Werner Schwertfeger
发明人： Peter Blickle , Klaus Hintzer , Gernot Lohr , Werner Schwertfeger
IPC分类号： C08L27/12 , B01D65/10 , B01D67/00 , B01D71/32 , C08J3/09 , C08J5/22 , C08J5/06
CPC分类号： C08J5/2237 , B01D65/108 , B01D67/0011 , B01D71/32 , C08J3/095 , B01D2323/12 , C08J2327/12
摘要： The invention relates to solutions of fluoropolymers which preferably contain carbonate groups, in solvents of the general formula (I) ##STR1## These solutions are suitable, in particular, for the production of membranes for liquid permeation processes, such as electrolysis.
摘要翻译：本发明涉及在通式（I）的溶剂中优选含有碳酸酯基的含氟聚合物的溶液。（I）这些溶液特别适用于生产用于液体渗透方法如电解的膜。

66. 发明授权

US09156926B2 Peroxide curable fluoroelastomers containing modifiers and iodine or bromine endgroups 有权
标题翻译：含有改性剂和碘或溴端基的过氧化物固化的含氟弹性体
公开(公告)号：US09156926B2
公开(公告)日：2015-10-13
申请号：US13813691
申请日：2011-07-26
申请人： Kai Helmut Lochhaas , Klaus Hintzer , Michael Jürgens , Harald Kaspar , Alain Verschuere
发明人： Kai Helmut Lochhaas , Klaus Hintzer , Michael Jürgens , Harald Kaspar , Alain Verschuere
IPC分类号： C08F214/18 , C08F214/22 , C08F214/26 , C08F214/28 , C08F14/18
CPC分类号： C08F14/18 , C08F214/18 , C08F214/184 , C08F214/222 , C08F214/262 , C08F214/28 , Y10T428/139
摘要： Provided are curable fluoroelastomers. Further provided are methods of making the curable elastomers, curable fluoroelastomer compositions and methods of making them and shaped articles made from the curable fluoroelastomer compositions.
摘要翻译：提供可固化的含氟弹性体。进一步提供制备可固化弹性体，可固化含氟弹性体组合物及其制备方法和由可固化含氟弹性体组合物制成的成型制品的方法。

67. 发明授权

US08614265B2 Method of making fluoropolymer dispersion 有权
标题翻译：制备含氟聚合物分散体的方法
公开(公告)号：US08614265B2
公开(公告)日：2013-12-24
申请号：US13494260
申请日：2012-06-12
申请人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael Jürgens , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G. I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08L1/00
CPC分类号： C08L27/12 , C08L71/02 , Y02C20/30 , C08L2666/22
摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear fully fluorinated aliphatic group or a linear fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.
摘要翻译：首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示线性全氟化亚烷基，Rf表示直链全氟化脂族基团或被一个氧原子间隔的直链全氟化脂肪族基团，Xi +表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于分散体的总重量，同时保持或增加分散体中固体的量。

68. 发明申请

US20120252949A1 METHOD OF MAKING FLUOROPOLYMER DISPERSION 有权
标题翻译：制备氟聚合物分散体的方法
公开(公告)号：US20120252949A1
公开(公告)日：2012-10-04
申请号：US13494260
申请日：2012-06-12
申请人： Klaus Hintzer , Michael JÜRGENS , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G.I. Moore , Jay F. Schulz , Richard M. Flynn
发明人： Klaus Hintzer , Michael JÜRGENS , Harald Kaspar , Herbert Koenigsmann , Kai Helmut Lochhaas , Andreas R. Maurer , Werner Schwertfeger , Tilman Zipplies , Ludwig Mayer , Michael C. Dadalas , George G.I. Moore , Jay F. Schulz , Richard M. Flynn
IPC分类号： C08L27/18 , C08K5/095
CPC分类号： C08L27/12 , C08L71/02 , Y02C20/30 , C08L2666/22
摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear fully fluorinated alkylene group, Rf represents a linear fully fluorinated aliphatic group or a linear fully fluorinated aliphatic group interrupted with one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.
摘要翻译：首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备方法，所述含氟聚合物分散体具有以下通式：[Rf-OL-COO-] iXi +（I）其中L表示线性全氟化亚烷基，Rf表示直链全氟化脂族基团或被一个氧原子间隔的直链全氟化脂肪族基团，Xi +表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于分散体的总重量，同时保持或增加分散体中固体的量。

69. 发明申请

US20100292362A1 Dental Composition Containing a Surfactant and an F-Containing Compound, Process of Production and Use Thereof 有权
标题翻译：含有表面活性剂和含F化合物的牙科用组合物，其制造及使用方法
公开(公告)号：US20100292362A1
公开(公告)日：2010-11-18
申请号：US12747927
申请日：2008-12-17
申请人： Joachim W. Zech , Peter U. Osswald , Henning Hoffmann , Andreas R. Maurer , Peter Bissinger , Klaus Hintzer
发明人： Joachim W. Zech , Peter U. Osswald , Henning Hoffmann , Andreas R. Maurer , Peter Bissinger , Klaus Hintzer
IPC分类号： A61K6/10
CPC分类号： A61K6/10 , A61K6/083 , C08L51/085 , C08L51/08
摘要： The invention relates to a curable dental composition comprising a) a curable organopolysiloxane polymer, b) a crosslinker compound capable of crosslinking said organopolysiloxane polymer, c) a catalyst capable of catalyzing a crosslinking reaction of component (A) and component (B), d) a surfactant, e) a F-containing compound, wherein the F-containing compound has the following formula: (G1-L1-O)s-Rfa-O-L2-G2 wherein: G1 and G2 each independently represents a non-ionic endgroup that is free of polyoxyalkylene groups or contains polyoxyalkylene such that the total amount thereof in the F-containing compound is not more than 10% by weight based on the molecular weight of the F-containing compound; L1 and L2 each independently represents an aliphatic hydrocarbon group or a partially or fully fluorinated aliphatic hydrocarbon group; Rfa represents a mono-valent or divalent partially or fully fluorinated aliphatic group or a partially or fully fluorinated aliphatic group interrupted by one or more oxygen atoms; with the proviso that at least one of the following conditions is fulfilled: (i) at least one of the moieties L1-G1 and L2-G2 is partially or fully fluorinated or (ii) Rf is a partially or fully fluorinated aliphatic group interrupted by one or more oxygen atoms. The invention also relates to a kit of parts and a method of producing a dental composition as well as the use of the dental composition for the preparation of or as impression material or for the preparation of crowns and bridges.
摘要翻译：本发明涉及一种可固化牙科用组合物，其包含a）可固化的有机基聚硅氧烷聚合物，b）能够交联所述有机聚硅氧烷聚合物的交联剂化合物，c）能够催化组分（A）和组分（B）的交联反应的催化剂，d ）表面活性剂，e）含F化合物，其中所述含F化合物具有下式：（G1-L1-O）s-Rfa-O-L2-G2其中：G1和G2各自独立地表示非 - 不含聚氧化烯基团或含有聚氧化烯的离子性端基，使得其含氟化合物的总量相对于含F化合物的分子量为10重量％以下; L1和L2各自独立地表示脂族烃基或部分或完全氟化的脂族烃基; Rfa表示被一个或多个氧原子间隔的一价或二价部分或完全氟化的脂族基团或部分或全部氟化脂族基团; 条件是满足以下条件中的至少一个：（i）部分L1-G1和L2-G2中的至少一个部分或完全氟化，或（ii）Rf是部分或完全氟化的脂族基团，被一个或多个氧原子。本发明还涉及一种用于制备牙科用组合物的试剂盒和牙科用组合物的制备方法，或用作制备印模材料或用于制备牙冠和牙桥的牙科用组合物。

70. 发明申请

US20100256412A1 FLUORINATED POLYETHERS AND POLYETHER OILS AND METHODS OF PREPARATION 审中-公开
标题翻译：氟化聚醚和聚醚油及其制备方法
公开(公告)号：US20100256412A1
公开(公告)日：2010-10-07
申请号：US12679123
申请日：2008-08-26
申请人： Werner Schwertfeger , Klaus Hintzer , Harald Kaspar , Egon Obermaier
发明人： Werner Schwertfeger , Klaus Hintzer , Harald Kaspar , Egon Obermaier
IPC分类号： C07C41/54 , C07C69/66 , C07C235/02
CPC分类号： C08G65/007
摘要： Provided are fluorinated polyethers and polyether oils and methods of preparation. The preparation involves a catalytic oxidation process of fluorinated vinyl ethers employing free oxygen.
摘要翻译：提供氟化聚醚和聚醚油及其制备方法。该制备涉及使用游离氧的氟化乙烯基醚的催化氧化方法。

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