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    • 65. 发明授权
    • Thermosetting compositions containing carbamate-functional polylmers prepared using atom transfer radical polymerization
    • 含有使用原子转移自由基聚合制备的氨基甲酸酯官能聚合物的热固性组合物
    • US06306965B1
    • 2001-10-23
    • US09375020
    • 1999-08-16
    • Lawrence G. AndersonJames B. O'DwyerDennis A. SimpsonDaniela White
    • Lawrence G. AndersonJames B. O'DwyerDennis A. SimpsonDaniela White
    • C08F830
    • C08F220/36C08G18/3831C09D201/025
    • A thermosetting composition is provided comprising: (a) a crosslinking agent having at least two functional groups that are reactive with carbamates; and (b) a non-gelled, carbamate functional polymer prepared by atom transfer radical polymerization, in the presence of an initiator having at least one radically transferable group. The polymer contains at least one of the following polymer chain structures: —{(M)p—(G)q}x— or —{(G)q—(M)p}x— wherein M is a residue, that is free of carbamate functionality, of at least one ethylenically unsaturated radically polymerizable monomer; G is a residue, that has carbamate functionality, of at least one ethylenically unsaturated radically polymerizable monomer; p and q represent average numbers of residues occurring in a block of residues in each polymer chain structure; and p, q, and x are each independently selected for each structure such that the carbamate functional polymer has a number average molecular weight of at least 250. Also provided by the present invention are methods of coating a substrate using compositions of the present invention and substrates coated by such methods, as well as color-plus-clear composite coatings.
    • 提供一种热固性组合物,其包括:(a)具有至少两个与氨基甲酸酯反应的官能团的交联剂; 和(b)在具有至少一个可自由基转移基团的引发剂的存在下通过原子转移自由基聚合制备的非胶凝的氨基甲酸酯官能聚合物。 所述聚合物含有至少一种以下聚合物链结构:或其中M是不含氨基甲酸酯官能团的至少一种烯属不饱和自由基聚合单体的残基; G是具有氨基甲酸酯官能团的至少一种烯属不饱和自由基聚合单体的残基; p和q表示在每个聚合物链结构的残基块中发生的残基的平均数目; 对于每种结构,p,q和x各自独立地选择,使得氨基甲酸酯官能聚合物的数均分子量至少为250.本发明还提供了使用本发明的组合物涂覆底物的方法和 通过这些方法涂覆的基材,以及彩色 - 透明复合涂层。
    • 66. 发明授权
    • Thermosetting coating compositions containing flow modifiers prepared by controlled radical polymerization
    • 含有通过控制自由基聚合制备的流动改性剂的热固性涂料组合物
    • US06197883B1
    • 2001-03-06
    • US09325226
    • 1999-06-03
    • Karl F. SchimmelKaren A. BarkacKurt A. HumbertJonathan D. GoetzJames B. O'Dwyer
    • Karl F. SchimmelKaren A. BarkacKurt A. HumbertJonathan D. GoetzJames B. O'Dwyer
    • C08L5300
    • C09D153/00C08F293/005C08L53/00Y10S524/904Y10S525/934
    • Thermosetting coating compositions, e.g., powder coating compositions, are provided and comprise: (a) a first reactant having functional groups, e.g., an epoxide functional (meth)acrylic polymer; (b) a second reactant having functional groups that are co-reactive with the functional groups of the first reactant, e.g., a carboxylic acid functional crosslinking agent; and (c) a polymeric flow control agent. The flow control agent is a block copolymer prepared by controlled radical polymerization and comprises: (i) a first block containing residues of at least one first ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality; and (ii) a second block containing residues of at least one second ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality. The second monomer of the flow control agent has a calculated Tg of at least 20° C. greater than that of the first monomer. The first and second blocks of the flow control agent may each independently contain a minor amount of hydroxy functional monomer residues.
    • 提供热固性涂料组合物,例如粉末涂料组合物,其包括:(a)具有官能团的第一反应物,例如环氧官能的(甲基)丙烯酸聚合物; (b)具有与第一反应物的官能团共反应的官能团的第二反应物,例如羧酸官能交联剂; 和(c)聚合物流动控制剂。 流动控制剂是通过受控自由基聚合制备的嵌段共聚物,并且包括:(i)含有至少一种不含羟基官能团的至少一种第一烯属不饱和自由基可聚合单体残基的第一嵌段; 和(ii)含有不含羟基官能团的至少一种第二烯属不饱和自由基聚合性单体残基的第二嵌段。 流动控制剂的第二单体的计算Tg比第一单体的Tg高至少20℃。 流动控制剂的第一和第二嵌段可各自独立地含有少量的羟基官能单体残基。