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    • 62. 发明授权
    • Novel process for producing pyrimidine nucleosides and novel pyrimidine
nucleosides obtained thereby
    • 制备嘧啶核苷的新方法和由此获得的新的嘧啶核苷
    • US4324895A
    • 1982-04-13
    • US735777
    • 1976-10-28
    • Masanao MatsuiTomoya Ogawa
    • Masanao MatsuiTomoya Ogawa
    • C07F7/22C07D405/04
    • C07F7/2256C07F7/2232
    • The present invention relates to a novel process for producing pyrimidine nucleosides by a reaction between bis(tri-lower alkylstannyl)-5-halogenouracil and 2-substituted tetrahydrofurane. The novel process of the present invention makes it possible to obtain, depending upon the manner of substitution of tetrahydrofurane residue on two nitrogen atoms N.sub.1 and N.sub.3 of 5-halogenouracil, N.sub.1 -mono-substituted compound, N.sub.3 -mono-substituted compound and N.sub.1,N-di-substituted compound among which the last can be converted by hydrolysis thereof into N.sub.1 -mono-substituted compound. The present invention further relates to novel N.sub.3 -mono-substituted compounds and N.sub.1,N.sub.3 -di-substituted compounds obtained by such process. The present invention still further relates to novel bis-(tri-lower alkylstannyl)-5-halogenouracil used in the present invention as a raw compound.
    • 本发明涉及通过双(三 - 低级烷基甲锡烷基)-5-卤代尿嘧啶和2-取代的四氢呋喃之间的反应制备嘧啶核苷的新方法。 根据本发明的新方法,可以根据5-卤代尿嘧啶,N1-单取代化合物,N 3 - 单取代化合物和N 1的两个氮原子N 1和N 3上的四氢呋喃残基的取代方式, N-二取代的化合物,其中最后的化合物可以通过其水解转化成N1-单取代的化合物。 本发明还涉及新的N 3 - 单取代的化合物和通过这种方法获得的N,N 3 - 二取代的化合物。 本发明还涉及本发明中用作原料化合物的新型双 - (三低级烷基甲锡烷基)-5-卤代尿嘧啶。
    • 63. 发明授权
    • Fuel cell system and fuel cell vehicle
    • 燃料电池系统和燃料电池车
    • US09368850B2
    • 2016-06-14
    • US12810471
    • 2008-12-11
    • Michio YoshidaTomoya Ogawa
    • Michio YoshidaTomoya Ogawa
    • H01M16/00B60L11/18H01M8/04
    • H01M16/006B60L11/1887B60L11/1894B60L2240/421B60W2510/081H01M8/04365H01M8/04559H01M8/04589H01M8/04604H01M8/04619H01M8/04753H01M8/0488H01M8/0491Y02E60/50Y02T10/642Y02T90/34
    • There is disclosed a fuel cell system having a motor which can be driven and generate a regenerative power by receiving the supply of a power, wherein an influence on power supply control is decreased. The fuel cell system fuel cell system comprises a fuel cell which generates a power by an electrochemical reaction of a fuel gas and an oxidant gas; a motor which can be driven and generate the regenerative power by receiving the supply of a power; an inverter which converts a direct-current power output from the fuel cell into an alternate-current power to supply the power to the motor, thereby controlling the driving of the motor; a battery which is connected to the motor in parallel with the fuel cell, and which can be charged with the power generated by the fuel cell and the regenerative power generated by the motor and which can discharge the charged powers to the motor; a rotation number detector which detects the rotation number of the motor; and a control unit which determines whether or not to allow the stop of the control by the inverter with respect to the motor based on the present rotation number of the motor. The control unit compares the present rotation number of the motor with a threshold value which varies in accordance with operation modes of the fuel cell, to perform the determination.
    • 公开了一种具有电动机的燃料电池系统,其能够通过接收电力的供给而被驱动并产生再生电力,其中对供电控制的影响减小。 燃料电池系统燃料电池系统包括通过燃料气体和氧化剂气体的电化学反应产生电力的燃料电池; 可以通过接收电力的供给来驱动并产生再生电力的电动机; 逆变器,其将从燃料电池单元输出的直流电力转换为交流电力,以向电动机供电,从而控制电动机的驱动; 电池,其与燃料电池并联连接到电动机,并且可以对由燃料电池产生的电力和由电动机产生的再生电力进行充电,并且可以将充电电力放电到电动机; 旋转数检测器,其检测电动机的转数; 以及控制单元,其基于电动机的当前旋转数来确定是否允许逆变器相对于电动机的控制停止。 控制单元将当前的电机转数与根据燃料电池的运行模式而变化的阈值进行比较,以进行确定。
    • 64. 发明授权
    • Fuel cell system
    • 燃料电池系统
    • US09240602B2
    • 2016-01-19
    • US12743911
    • 2008-11-11
    • Hiroyuki ImanishiKota ManabeTomoya Ogawa
    • Hiroyuki ImanishiKota ManabeTomoya Ogawa
    • H01M8/04B60L11/18
    • H01M8/04559B60L11/1894B60L2240/545B60L2240/547H01M8/04268H01M8/0488Y02E60/50Y02T90/34
    • Provided is a fuel cell system capable of supplying electric power to external loads without excess or deficiency even when switching occurs between operation states. A warm-up timing judgment part judges whether it is time to operate warm-up based on the temperature of a fuel cell stack. A target shift voltage determination part determines a target output voltage of the fuel cell stack used during a warm-up operation, and a voltage change speed determination part determines a voltage change speed based on electric power required from the fuel cell stack, the target output voltage of the fuel cell stack used during the warm-up operation which is output from the target shift voltage determination part and a current output voltage detected by a voltage sensor. A voltage decrease execution part operates voltage decrease processing according to the voltage change speed indicated by the voltage change speed determination part.
    • 提供一种即使在操作状态之间发生切换的情况下也能够向外部负载提供电力而没有过多或不足的燃料电池系统。 预热定时判断部判断是否有时间基于燃料电池堆的温度进行预热。 目标偏移电压确定部分确定在预热操作期间使用的燃料电池堆的目标输出电压,并且电压变化速度确定部分基于从燃料电池堆所需的电力来确定电压变化速度,目标输出 从目标换档电压判定部输出的预热运转中使用的燃料电池堆的电压和由电压传感器检测出的电流输出电压。 电压降低执行部根据电压变化速度决定部所表示的电压变化速度进行电压降低处理。
    • 66. 发明授权
    • Fuel cell system
    • 燃料电池系统
    • US08460835B2
    • 2013-06-11
    • US12675709
    • 2008-08-22
    • Hiroyuki ImanishiKota ManabeTomoya Ogawa
    • Hiroyuki ImanishiKota ManabeTomoya Ogawa
    • H01M8/04
    • H01M8/0488H01M8/04223H01M8/04225H01M8/04619H01M2250/20Y02T90/32
    • A fuel cell system increases an output voltage of a fuel cell if an electric power generation command value Pref for the fuel cell abruptly reduces while the fuel cell is being warmed up at a low-efficiency operation, which has lower electric power generation efficiency than that of a normal operation. Thus, the surplus electric power Ws corresponding to the difference between an electric power generation amount Pmes of the fuel cell and the electric power generation command value Pref is stored into a capacitive component of the fuel cell, thereby matching the electric power supplied to an external load of the fuel cell (Pmes-Ws) with the electric power generation command value Pref. This makes it possible to conduct control not to supply the surplus electric power to the external load when the electric power required from the fuel cell suddenly reduces during the low-efficiency operation.
    • 如果燃料电池的发电指令值Pref在燃料电池处于低效率运行时被加热的情况下,燃料电池的发电指令值Pref突然降低,则燃料电池系统增加燃料电池的输出电压,其发电效率比其低 的正常操作。 因此,对应于燃料电池的发电量Pmes与发电指令值Pref的差的剩余电力Ws被存储在燃料电池的电容部件中,从而将供给到外部的电力的电力 具有发电指令值Pref的燃料电池(Pmes-Ws)的负载。 这使得当在低效率操作期间当燃料电池所需的电力突然降低时,可以进行不向外部负载供应剩余电力的控制。
    • 70. 发明申请
    • FUEL CELL SYSTEM AND CURRENT CONTROL METHOD OF SAME
    • 燃料电池系统及其电流控制方法
    • US20100136451A1
    • 2010-06-03
    • US12598532
    • 2008-06-27
    • Hiroyuki ImanishiKota ManabeTomoya Ogawa
    • Hiroyuki ImanishiKota ManabeTomoya Ogawa
    • H01M8/04
    • H01M8/04552B60L11/1881B60L11/1887B60L11/1892B60L11/1894H01M8/0491Y02T90/34
    • A control unit 80, when calculating a request current I0 according to a system request electric power Preq and calculating a target current I1 by correcting the request current I0 with PI compensation calculation based on a minimum cell voltage Vm detected by a cell monitor 101, variably changes a proportional gain Kp according to the current value at the present time when calculating a current limit value ΔI as the amount of correction of a request current I0 according to the equation ΔI=ΔV×Kp+ΔΣV×Ki, thereby enhancing controllability to control the current of a fuel cell 20 to a target current value I1. When controlling the current of a fuel cell by determining a target current value by correcting a request current by PI compensation using the difference between a minimum cell voltage and a threshold voltage, controllability to control the current of the fuel cell to the target current value can be enhanced.
    • 控制单元80,当根据系统请求电力Preq计算请求电流I0并且通过基于由单元监视器101检测到的最小单元电压Vm的PI补偿计算来校正请求电流I0来计算目标电流I1时,可变地 根据等式&Dgr计算电流限制值&Dgr; I作为请求电流I0的校正量,根据当前值根据当前值改变比例增益Kp; I =&Dgr; V×Kp +&Dgr;&Sgr ; V×Ki,从而提高了将燃料电池20的电流控制为目标电流值I1的可控性。 当通过使用最小单元电压和阈值电压之间的差校正PI补偿的PI补偿来确定目标电流值来控制燃料电池的电流时,可以将燃料电池的电流控制到目标电流值 加强。