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61. 发明授权

EP1517669B1 NEUE KUPPLERKOMPONENTEN 有权
公开(公告)号：EP1517669B1
公开(公告)日：2005-10-26
申请号：EP03789305.4
申请日：2003-12-17
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： KNÜBEL, Georg , HÖFFKES, Horst , NEMITZ, Ralph
IPC分类号： A61K7/13
CPC分类号： A61K8/415 , A61K8/411 , A61Q5/10 , C07C217/84 , C07C271/28 , C07D261/04 , D06P3/08
摘要： The invention relates to agents for dying keratin fibres, especially human hair, containing, in a cosmetically acceptable carrier as coupling components, at least one m-phenylendiamine derivative of formula (I), wherein R1 represents a C1-C4-alkyl group or a C1-C4-monohydroxyalkyl group, R2 represents a methyl group or an ethyl group, and R3 and R4 independently represent from each other a branched or non-branched C2- C6-hydroxyalkyl group. The inventive coupling components enable, especially with p--toluylendiamine, 1-(2-hydroxyethyl)-2,5-diaminobenzol, 2,4,5,6-tetraaminopyrimidine and bis-(2-hydroxy-5-aminophenyl) methane, dying to occur with high colour intensity and with good to very good fastness properties in the red and violet ranges.

62. 发明公开

EP1583511A1 NEUE KUPPLERKOMPONENTEN 有权
标题翻译：全新成色剂组分
公开(公告)号：EP1583511A1
公开(公告)日：2005-10-12
申请号：EP03795902.0
申请日：2003-12-17
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： KNÜBEL, Georg , HÖFFKES, Horst , NEMITZ, Ralph
IPC分类号： A61K7/13
CPC分类号： A61K8/415 , A61K8/411 , A61Q5/10 , C07C217/84 , C07C271/28 , C07D261/04 , D06P3/08
摘要： The invention relates to agents for colouring keratin fibres, in particular human hair, comprising at least one m-phenylene diamine derivative of formula (I) in a cosmetically acceptable carrier. In said formula, R1 represents a C1-C4 alkyl group or a C1-C4 monohydroxyalkyl group, R2 represents a hydrogen atom, a methyl or ethyl group and R3 and R4 represent independently of one another a branched or unbranched C2-C6 hydroxyalkyl group, with the proviso that the group R1O is in the o-position or m-position in relation to the two respective amino groups. The inventive coupling components, when used with p-toluylenediamine, 1-(2-hydroxyethyl)-2,5-diaminobenzole, 2,4,5,6-tetraaminopyrimidine and bis-(2-hydroxy-5-aminophenyl)methane, colour with a high colour intensity and good to excellent colour fastness in the red and violet range.

63. 发明公开

EP1542982A1 HAARFÄRBEMITTEL MIT M-PHENYLENDIAMINDERIVATEN ALS KUPPLERKOMPONENTEN 审中-公开
标题翻译：染发剂间苯二胺为偶合组分
公开(公告)号：EP1542982A1
公开(公告)日：2005-06-22
申请号：EP03750569.0
申请日：2003-09-18
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： KNÜBEL, Georg , MEINIGKE, Bernd , HÖFFKES, Horst , NEMITZ, Ralph
IPC分类号： C07D295/135 , A61K7/13
CPC分类号： A61K8/411 , A61Q5/10
摘要： The invention relates to agents for dyeing keratin fibers, especially human hair, containing at least one m-phenylenediamine derivative of formula (I) or one of the physiologically acceptable salts thereof as a coupling component in a cosmetically acceptable carrier, R1 in formula (I) representing a hydrogen atom, a halogen atom, a C1 to C4 alkyl group, a C1 to C4 monohydroxyalkyl group, a C2 to C4 polyhydroxyalkyl group, a C1 to C4 aminoalkyl group, a C1 to C4 alkoxy-(C1 to C4) alkyl group, or a C1 to C4 dialkylamino-(C1 to C4) alkyl group, R2 and R3 independently representing a hydrogen atom, a C1 to C4 alkyl group, a C2 to C4 monohydroxyalkyl group, a C3 to C4 polyhydroxyalkyl group, a C1 to C4 alkoxy-(C1 to C4) alkyl group, or a C1 to C4 aminoalkyl group, and X representing a saturated, 5-membered, 6-membered, or 7-membered heterocycle which comprises at least one nitrogen atom and an additional optional heteroatom selected among oxygen, sulfur, or nitrogen. Said heterocycle is linked to the aromatic ring system via a nitrogen atom and can optionally carry up to two substituents that are different from hydrogen and are selected among a halogen atom, a C1 to C4 alkyl group, a C1 to C4 monohydroxyalkyl group, a C2 to C4 polyhydroxyalkyl group, a C1 to C4 aminoalkyl group, a C1 to C4 alkoxy-(C1 to C4) alkyl group, or a C1 to C4 dialkylamino-(C1 to C4) alkyl group. The inventive coupling components allow for intensive shiny nuances with very good fastness properties, particularly in combination with p-phenylenediamine derivatives, diaminopyrazole derivatives, and oligo-aminopyrimidine derivatives.

64. 发明授权

EP1044245B1 FUNKTIONELLE FARBSTOFFE ALS INDIKATOR IN AEROB HÄRTENDEN ZUSAMMENSETZUNGEN 有权
标题翻译：功能性染料作为指示剂AEROB固化组合物
公开(公告)号：EP1044245B1
公开(公告)日：2004-01-28
申请号：EP98963458.9
申请日：1998-11-16
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： FRIESE, Carsten , KNÜBEL, Georg
IPC分类号： C09J4/06 , C08K5/00
CPC分类号： C09J175/16 , C08F290/147 , C08G18/672 , C08K5/0041 , C09D175/16 , C09J4/06 , C09J11/06 , Y10S435/808 , Y10T428/28 , Y10T428/2804 , Y10T428/2891 , Y10T428/2896 , C08L75/16

65. 发明授权

EP0971689B1 WÄSSRIGE PFLEGENDE HAUT- UND HAARBEHANDLUNGSMITTEL 失效
标题翻译：水滋养发处理剂
公开(公告)号：EP0971689B1
公开(公告)日：2002-08-21
申请号：EP98919190.3
申请日：1998-03-30
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： HÖFFKES, Horst , KNÜBEL, Georg , WALDMANN-LAUE, Marianne
IPC分类号： A61K7/50
CPC分类号： A61Q19/00 , A61K8/342 , A61K8/361 , A61K8/466 , A61Q5/12
摘要： Aqueous products which contain as active care principles a mixture of (a) sulphation and/or sulphonation products of saturated and/or unsaturated carboxylic and/or hydroxycarboxylic acids; and (b) fatty alcohols and/or acids, are characterised by their special gentleness and excellent skin and hair care effect.

66. 发明授权

EP0743849B1 VERWENDUNG VON 1,2,3,4-TETRAHYDROCHINOXALINEN ALS OXIDATIONSFARBSTOFFVORPRODUKTE IN OXIDATIONSFÄRBEMITTELN 有权
标题翻译： 1,2,3,4- tetrahydroquinoxalines如在氧化的氧化染料前体使用
公开(公告)号：EP0743849B1
公开(公告)日：2000-11-08
申请号：EP95908263.7
申请日：1995-02-04
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： KNÜBEL, Georg , ROSE, David , HÖFFKES, Horst , MEINIGKE, Bernd
IPC分类号： A61K7/13
CPC分类号： A61Q5/10 , A61K8/494
摘要： The use of 1,2,3,4-tetrahydroquinoxalines as oxidation dye precursors in oxidation dyes for dyeing keratin-containing fibres, in particular human hair, is disclosed, as well as new 1,2,3,4-tetrahydroquinoxalines and 1,2,3,4-tetrahydroquinoxaline-containing hair oxidation dyes.

67. 发明公开

EP0973484A1 ÖL-IN-WASSER-EMULSIONEN ZUR WIEDERHERSTELLUNG DER LAMELLARITÄT DER LIPIDSTRUKTUR GESCHÄDIGTER HAUT 无效
标题翻译：油包水乳液恢复脂质结构受损的皮肤层数
公开(公告)号：EP0973484A1
公开(公告)日：2000-01-26
申请号：EP97953710.7
申请日：1997-11-28
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： BORDAT, Pascal , ORTANDERL, Stefanie , KAMPMANN, Martina , WALDMANN-LAUE, Marianne , KNÜBEL, Georg , MAUSBERG, Marcus
IPC分类号： A61K7/00 , A61K7/48 , A61K9/107
CPC分类号： A61K8/062 , A61K8/0295 , A61K8/06 , A61K9/1274 , A61Q19/00 , Y10S514/938
摘要： Oil-in-water emulsions with lamellar, liquid crystal phases contain a cosmetic oil or fat component, a hydrophile emulsifier and a lipophile co-emulsifier which is a lipid of the formula R1-O-R2, in which R1 stands for a primary, linear alkyl group, alkenyl group or acyl group with 20 to 30 C-atoms and R2 stands for hydrogen or a hydroxyalkyl group, a hydroxyalkoxyalkyl group or a polyhydroxyalkyl group. Behenyl alcohol is preferably used as a lipophile co-emulsifier. The emulsions enhance the lamellarity and the degree of order of the epidermal lipid structures of the skin.

68. 发明授权

EP0684810B1 VERWENDUNG VON 1,8-DIHYDROXYNAPHTHALINEN ALS OXIDATIONSFARBSTOFFVORPRODUKTE IN OXIDATIONSFÄRBEMITTELN 失效
标题翻译： 1,8-二羟基萘类如氧化氧化染料前体使用
公开(公告)号：EP0684810B1
公开(公告)日：1997-06-18
申请号：EP94907559.2
申请日：1994-02-12
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： KNÜBEL, Georg , HÖFFKES, Horst , LIESKE, Edgar
IPC分类号： A61K7/13
CPC分类号： A61Q5/10 , A61K8/347
摘要： The object of the invention is the use of 1,8-dihydroxynaphthalene and certain halogen-substituted derivates as oxidation dye preliminary products in oxidation dyeing agents for dyeing keratinous fibers, in particular human hair. The 1,8-dihydroxynaphthalenes are particularly suitable as coupler components together with developer components.

69. 发明授权

EP0602083B1 VERFAHREN ZUR HERSTELLUNG VON 5,6-DIHYDROXYINDOLINEN 失效
公开(公告)号：EP0602083B1
公开(公告)日：1995-05-31
申请号：EP92917999.2
申请日：1992-08-24
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： KNÜBEL, Georg , KONRAD, Günther , MICHEL, Roswitha
IPC分类号： C07D209/08 , C07D209/42
CPC分类号： C07D209/42 , C07D209/08
摘要： 5,6-dihydroxyindolines of the general formula (I), in which the radicals R?1 and R3¿ are mutually independently hydrogen or alkyl groups with 1 to 4 C atoms and the radical R2 is hydrogen, an alkyl group with 1 to 4 C atoms or a carboxyl group, are easily obtainable by the reaction of 5,6-dialkoxyindolines with hydrobromic acid and subsequent direct crystallisation from the aqueous reaction mixture.
摘要翻译：（I）的5,6-二羟基二氢吲哚类，其中基团R 1和R 3相互独立地为氢或具有1至4个C原子的烷基，基团R 2为氢，具有1至4个碳原子的烷基 C原子或羧基，可以通过5,6-二烷氧基二氢吲哚与氢溴酸的反应并随后从含水反应混合物直接结晶而容易地获得。

70. 发明授权

EP1438294B1 ENTWICKLERKOMPONENTEN UND DEREN VERWENDUNG ZUR FÄRBUNG KERATINISCHER FASERN 有权
标题翻译：开发人员组件及其使用垂死角蛋白纤维
公开(公告)号：EP1438294B1
公开(公告)日：2007-12-05
申请号：EP02802296.0
申请日：2002-10-17
申请人： Henkel Kommanditgesellschaft auf Aktien
发明人： KNÜBEL, Georg , HÖFFKES, Horst , MEINIGKE, Bernd , GIESA, Helmut
IPC分类号： C07D233/54 , C07D233/64 , A61Q5/10
CPC分类号： A61Q5/10 , A61K8/4946 , C07D231/12 , C07D233/56 , C07D249/08
摘要： The invention relates to means for dying keratin fibers, particularly human hair, which contain, in a cosmetically acceptable carrier, at least one p-phenylenediamine derivative of formula (I), whereby: A represents a branched or unbranched alkylene group with 1 to 6 carbon atoms, which can optionally carry one or more substituents selected from hydroxy group(s) and halogen atom(s); X represents an optionally substituted imidazolyl radical; R?1, R2 and R3¿, independent of one another, represent a hydrogen atom, a C¿1? to C4 alkyl group, a C1 to C4 monohydroxyalkyl group or a C2 to C6 polyhydroxyalkyl group, and; R?4 and R5¿, independent of one another, represent a hydrogen atom, a C¿1? to C4 alkyl group, a C1 to C4 alkoxy group, a C1 to C4 monohydroxyalkyl group, a C2 to C4 polyhydroxyalkyl group or a halogen atom. The inventive developer constituents are characterized by exhibiting intensive color results with excellent fastness to perspiration and cold wave fastness. The loss of color of colorations combined with customary colorant intermediate products is shifted somewhat bluish compared to colorings with p-toluylenediamine.

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