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61. 发明授权

US08557931B2 Multistage process for the polymerization of ethylene 有权
标题翻译：乙烯聚合的多阶段方法
公开(公告)号：US08557931B2
公开(公告)日：2013-10-15
申请号：US13201202
申请日：2010-02-15
申请人： Diego Brita , Gianni Collina
发明人： Diego Brita , Gianni Collina
IPC分类号： C08F2/00 , C08F4/00 , C08F210/00 , C08F110/02
CPC分类号： C08F210/16 , C08F4/6543 , C08F2/001 , C08F2/38 , C08F2/14 , C08F210/08 , C08F2500/12 , C08F2500/17 , C08F2500/24 , C08F210/14
摘要： The present invention relates to a slurry process for preparing an ethylene polymer having a melt flow ratio F/P, according to ASTM 1238, of higher than 25, carried out in two or more stages of polymerization at temperatures in the range from 60 to 120° C., in which at least two of the said two or more polymerization stages are carried out under different concentration of a molecular weight regulator, said process being carried out in the presence of a catalyst system comprising the product obtained by contacting (A) a solid catalyst component comprising Ti, Mg, halogen, and having a porosity (PF), measured by the mercury method and due to pores with radius equal to, or lower than, 1 μm of at least 0.3 cm3/g and a surface area determined by BET method, of lower than 100 m2/g, and (B) of an organoaluminum compound.
摘要翻译：本发明涉及一种用于制备乙烯聚合物的浆料方法，所述乙烯聚合物的熔体流动比F / P（根据ASTM 1238）高于25，在60至120℃的温度范围内进行两个或多个聚合阶段其中所述两个或更多个聚合阶段中的至少两个在不同浓度的分子量调节剂下进行，所述方法在催化剂体系存在下进行，所述催化剂体系包含通过使（A）包含Ti，Mg，卤素的固体催化剂组分，并且具有通过汞法测量的孔隙率（PF），并且由于具有至少0.3cm 3 / g的半径等于或小于1μm的孔和表面积通过BET法测定，低于100m 2 / g，和（B）有机铝化合物。

62. 发明授权

US08497328B2 Catalyst components for the polymerization of olefins and catalysts therefrom obtained 有权
标题翻译：用于烯烃聚合的催化剂组分及其催化剂
公开(公告)号：US08497328B2
公开(公告)日：2013-07-30
申请号：US12737742
申请日：2009-08-13
申请人： Diego Brita , Gianni Collina
发明人： Diego Brita , Gianni Collina
IPC分类号： C08F4/54
CPC分类号： C08F10/00 , C08F110/02 , C08F4/651 , C08F2500/12 , C08F2500/18
摘要： A solid catalyst component comprising Ti, Mg, halogen and a couple of monofunctional electron donor compounds MD1 and MD2 selected from esters and ethers, said donors being present in amounts such that the molar ratio MD1/MD2 ranges from 20 to 800. The so obtained catalyst component when converted into a catalyst is able to produce ethylene polymers with good morphological properties even under drastic polymerization conditions.
摘要翻译：包含Ti，Mg，卤素和选自酯和醚的一对单官能电子给体化合物MD1和MD2的固体催化剂组分，所述供体以使得MD1 / MD2的摩尔比为20至800的量存在。如此获得当转化为催化剂时催化剂组分即使在剧烈聚合条件下也能够生产具有良好形态特性的乙烯聚合物。

63. 发明授权

US07060763B2 Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom 有权
标题翻译：二氯化镁 - 乙醇加合物和由其获得的催化剂组分
公开(公告)号：US07060763B2
公开(公告)日：2006-06-13
申请号：US10486877
申请日：2003-03-17
申请人： Daniele Evangelisti , Gianni Collina
发明人： Daniele Evangelisti , Gianni Collina
IPC分类号： C08F4/42
CPC分类号： C08F110/06 , C07F3/003 , C08F4/651 , C08F4/6465 , C08F4/6543 , C08F2500/15 , C08F2500/18
摘要： The present invention relates to a MgCl2.mEtOH adduct in which m is from 2.5 to 3.2 optionally containing water up to a maximum of 1% wt based on the total weight of the adduct, characterized by a DSC profile in which the highest melting Temperature (Tm) peak is over 109° C. and has an associated fusion enthalpy ( H) of 103 J/g or lower. Catalyst components obtained from the adducts of the present invention are capable to give catalysts for the polymerization of olefins characterized by enhanced activity with respect to the catalysts prepared from the adducts of the prior art.
摘要翻译：本发明涉及一种MgCl 2·mEtOH加合物，其中m为2.5至3.2，任选地含有至多最多1％wt的水，基于加合物的总重量，其特征在于DSC 其中最高熔融温度（Tm）峰值超过109℃，并且具有103J / g或更低的相关联的熔融焓（H）。从本发明的加合物获得的催化剂组分能够产生用于烯烃聚合的催化剂，其特征在于相对于由现有技术的加合物制备的催化剂具有增强的活性。

64. 发明授权

US06908967B2 High transparency and high flexibility elastoplastic polyolefin compositions 失效
标题翻译：高透明度和高弹性弹性聚烯烃组合物
公开(公告)号：US06908967B2
公开(公告)日：2005-06-21
申请号：US10305072
申请日：2002-11-27
申请人： Gianni Collina , Anteo Pelliconi , Enea Garagnani
发明人： Gianni Collina , Anteo Pelliconi , Enea Garagnani
IPC分类号： C08F297/08 , C08L23/10 , C08L23/14 , C08L23/16 , C08L53/00 , C08L23/04
CPC分类号： C08L23/10 , C08F297/08 , C08L53/00 , C08L2205/02 , C08L2666/04
摘要： Highly transparent and flexible elastoplastic polyolefin compositions which contain A) 10-20 parts by weight of a propylene homopolymer or copolymer with ethylene and/or one or more CH2═CHR α-olefins, the copolymer containing at least 95% by weight of propylene; B) 5-20 parts by weight of propylene copolymer fraction containing ethylene and insoluble in xylene at room temperature; and C) 60-80 parts by weight of a propylene copolymer fraction containing a comonomer selected from ethylene and mixtures of ethylene with one or more CH2═CHR α-olefin and soluble in xylene at room temperature, the fraction containing from 15 to 25% by weight of the comonomer, the percent by weight of the sum of the B and C components with respect to the total polyolefin composition being from 80% to 90%.
摘要翻译：高透明和柔性的弹性聚烯烃组合物，其含有A）10-20重量份的丙烯均聚物或与乙烯和/或一个或多个CH 2 -CHRα-烯烃的共聚物，该共聚物含有至少95重量％的丙烯; B）5-20重量份含乙烯的丙烯共聚物部分，在室温下不溶于二甲苯; 和C）60-80重量份的丙烯共聚物部分，其含有选自乙烯的共聚单体和乙烯与一种或多种CH 2 -CHRα-烯烃的混合物，并在室温下可溶于二甲苯，所述级分含有15至25重量％的共聚单体，相对于总聚烯烃组合物，B和C组分的总和的重量百分数为80％至90％。

65. 发明申请

US20110152482A1 CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS AND CATALYSTS THEREFROM OBTAINED 有权
标题翻译：用于获得烯烃和催化剂聚合的催化剂组分
公开(公告)号：US20110152482A1
公开(公告)日：2011-06-23
申请号：US12737742
申请日：2009-08-13
申请人： Diego Brita , Gianni Collina
发明人： Diego Brita , Gianni Collina
IPC分类号： C08F4/649 , B01J31/38
CPC分类号： C08F10/00 , C08F110/02 , C08F4/651 , C08F2500/12 , C08F2500/18
摘要： A solid catalyst component comprising Ti, Mg, halogen and a couple of monofunctional electron donor compounds MD1 and MD2 selected from esters and ethers, said donors being present in amounts such that the molar ratio MD1/MD2 ranges from 20 to 800. The so obtained catalyst component when converted into a catalyst is able to produce ethylene polymers with good morphological properties even under drastic polymerization conditions.
摘要翻译：包含Ti，Mg，卤素和选自酯和醚的一对单官能电子给体化合物MD1和MD2的固体催化剂组分，所述供体以使得MD1 / MD2的摩尔比为20至800的量存在。如此获得当转化为催化剂时催化剂组分即使在剧烈聚合条件下也能够生产具有良好形态特性的乙烯聚合物。

66. 发明申请

US20100168350A1 Catalyst Components for the Polymerization of Olefins 有权
标题翻译：用于烯烃聚合的催化剂组分
公开(公告)号：US20100168350A1
公开(公告)日：2010-07-01
申请号：US12224008
申请日：2007-02-09
申请人： Diego Brita , Gianni Collina
发明人： Diego Brita , Gianni Collina
IPC分类号： C08F4/64 , C08F4/609 , C08F4/602
CPC分类号： C08F10/00 , C08F210/16 , C08F4/651 , C08F210/08 , C08F2500/12 , C08F2500/17
摘要： The present invention relates to catalysts component for the polymerization of ethylene and its mixtures with olefins CH2═CHR, wherein R is an alkyl, cycloalkyl or aryl radical having 1-12 carbon atoms, comprising Ti, Mg, halogen, and electron donor belonging to 1,2-diethers as internal electron donor compound. The catalyst of the invention is suitably used in (co)polymerization processes of ethylene to prepare (co)polymers having narrow Molecular Weight Distribution (MWD) and high bulk density.
摘要翻译：本发明涉及用于乙烯及其与烯烃CH 2 = CHR的混合物的聚合的催化剂组分，其中R是具有1-12个碳原子的烷基，环烷基或芳基，包括Ti，Mg，卤素和属于 1,2-二醚作为内电子给体化合物。本发明的催化剂适用于乙烯的（共）聚合方法，以制备具有窄分子量分布（MWD）和高堆积密度的（共）聚合物。

67. 发明授权

US07307035B2 Magnesium dichloride-alcohol adducts and catalyst components obtained therefrom 失效
标题翻译：二氯化镁 - 醇加合物和由此获得的催化剂组分
公开(公告)号：US07307035B2
公开(公告)日：2007-12-11
申请号：US10493636
申请日：2003-07-04
申请人： Mario Sacchetti , Daniele Evangelisti , Diego Brita , Gianni Collina
发明人： Mario Sacchetti , Daniele Evangelisti , Diego Brita , Gianni Collina
IPC分类号： C08F4/42
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F4/65916 , C08F4/6543 , C08F4/6555 , C08F2500/07 , C08F210/08 , C08F2500/17
摘要： The present invention relates to an adduct comprising MgCl2, an alcohol (ROH) in which R is a C1-C10 hydrocarbon group, and a compound containing a transition metal M selected from the Groups 3 to 11 or the lanthanide or actinide groups of the Periodic Table of the Elements (new IUPAC version) in an amount such as to give a weight of M atoms lower than 10% based on the total weight of the adduct. The catalyst components that are obtained by reacting the adducts with halogenating agents show very high specific activity.
摘要翻译：本发明涉及包含M 2 Cl 2的加合物，其中R是C1-C10烃基的醇（ROH）和含有过渡金属的化合物 M选自元素周期表第3至11族或元素周期表的镧系元素或锕系元素（新的IUPAC版本），其用量可以基于加合物的总重量使M原子的重量低于10％。通过加合物与卤化剂反应获得的催化剂组分显示非常高的比活性。

68. 发明申请

US20050014632A1 Magnesium dichloride-ethanol adducts and catalyst components obtained therefrom 有权
标题翻译：二氯化镁 - 乙醇加合物和由其获得的催化剂组分
公开(公告)号：US20050014632A1
公开(公告)日：2005-01-20
申请号：US10486877
申请日：2003-03-17
申请人： Daniele Evangelisti , Gianni Collina
发明人： Daniele Evangelisti , Gianni Collina
IPC分类号： C07C31/08 , C07F3/00 , C08F4/00 , C08F4/646 , C08F4/651 , C08F4/654 , C08F4/655 , C08F4/658 , C08F10/00 , C08F110/06 , C01F5/30 , B01J31/00 , C08F4/44
CPC分类号： C08F110/06 , C07F3/003 , C08F4/651 , C08F4/6465 , C08F4/6543 , C08F2500/15 , C08F2500/18
摘要： The present invention relates to a MgCl2.mEtOH adduct in which m is from 2.5 to 3.2 optionally containing water up to a maximum of 1% wt based on the total weight of the adduct, characterized by a DSC profile in which the highest melting Temperature (Tm) peak is over 109° C. and has an associated fusion enthalpy ( H) of 103 J/g or lower. Catalyst components obtained from the adducts of the present invention are capable to give catalysts for the polymerization of olefins characterized by enhanced activity with respect to the catalysts prepared from the adducts of the prior art.
摘要翻译：本发明涉及MgCl 2，mEtOH加合物，其中m为2.5至3.2，任选地含有至多最多1％wt的水，基于加合物的总重量，其特征在于DSC分布，其中最高熔融温度（ Tm）峰超过109℃，并且具有103J / g或更低的相关联的熔融焓（H）。从本发明的加合物获得的催化剂组分能够产生用于烯烃聚合的催化剂，其特征在于相对于由现有技术的加合物制备的催化剂具有增强的活性。

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