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    • 64. 发明授权
    • ELASTOMERIC POLYMER BLENDS AND PROCESSES FOR THEIR PRODUCTION
    • 维多利亚·温哥华ZU IHRER HERSTELLUNG的ELASTOMERER POLYMERMISCHUNGEN
    • EP2536784B1
    • 2017-03-22
    • EP11704350.5
    • 2011-01-27
    • ExxonMobil Chemical Patents Inc.
    • KOLB, RainerCHU, John W.KISS, GaborREYNOLDS, Robert, P.SCHAUDER, Jean-RochSUN, Thomas T.
    • C08L23/14
    • C08L23/142C08L2205/02C08L2314/06C08L2666/06
    • Elastomeric polymer blends and processes for their production are described. Specifically, the polymer blends comprise a first polymer and a second polymer, where the first polymer comprises from about 70 wt % to about 90 wt % units derived from propylene and from about 10 wt % to about 30 wt % units derived from ethylene and/or a C4-C10 alpha-olefin, and the second polymer comprises from about 88 wt % to about 98 wt % units derived from propylene and from about 2 wt % to about 12 wt % units derived from ethylene and/or a C4-C10 alpha-olefin. The elastomeric polymer blends are further characterized by having two or more of the following properties: an overall propylene content of between about 75 wt % and about 90 wt %, a melting point between about 110° C. and about 145° C., a Vicat softening point greater than about 45° C., a tensile stress at 300% strain of less than about 500 psi (3447 kPa), as determined by a stress strain test according to ASTM D412, or an average maximum force for pellet separation of less than about 10 N in an accelerated storage stability test. The polymer blends are produced in a dual reactor process, in which the first polymer and the second polymer are prepared using differing catalyst systems.
    • 描述了弹性聚合物共混物及其制备方法。 具体地,聚合物共混物包含第一聚合物和第二聚合物,其中第一聚合物包含约70重量%至约90重量%的衍生自丙烯的单元和约10重量%至约30重量%的衍生自乙烯和/ 或C 4 -C 10α-烯烃,并且第二聚合物包含衍生自丙烯的约88重量%至约98重量%的单元和衍生自乙烯和/或C 4 -C 10的约2重量%至约12重量%的单元 α-烯烃。 弹性体聚合物共混物的进一步特征在于具有两种或更多种以下性能:总丙烯含量为约75重量%至约90重量%,熔点为约110℃至约145℃, 维卡软化点大于约45℃,通过根据ASTM D412的应力应变测试确定的小于约500psi(3447kPa)的300%应变下的拉伸应力或丸粒分离的平均最大力 在加速储存稳定性试验中小于约10N。 聚合物共混物在双重反应器方法中制备,其中使用不同的催化剂体系制备第一聚合物和第二聚合物。