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    • 67. 发明专利
    • BR9916426A
    • 2001-09-04
    • BR9916426
    • 1999-12-15
    • EXXONMOBIL CHEM PATENTS INC
    • MARKEL ERIC JWENG WEIQINGDEKMEZIAN ARMENAG H
    • C08F4/642C08F4/659C08F4/6592C08F10/06C08F210/06C08F210/16
    • Branched ethylene-propylene compositions which have improved melt strength and shear thinning are provided. The weight average branching index g' for the higher molecular weight region of the ethylene-propylene composition is less than 0.95. Additionally, a novel process is provided for efficiently producing a branched ethylene-propylene composition comprising: a) contacting propylene monomers and ethylene monomers in a reactor with an inert hydrocarbon solvent or diluent and a catalyst composition comprising one or more single site catalyst compounds capable of producing an ethylene-propylene polymer at a temperature from about 50° C. to about 180° C., wherein the ratio in the reactor of the propylene and ethylene monomers to the inert hydrocarbon solvent or diluent is less than 2.0, and further, wherein the propylene and ethylene monomers and the inert hydrocarbon solvent or diluent comprise no more than 90 percent of the total contents of the reactor; and b) recovering a branched ethylene-propylene composition, wherein the weight average branching index g' for the higher molecular weight region of the ethylene-propylene composition is less than 0.95.
    • 68. 发明专利
    • BR9913647A
    • 2001-06-05
    • BR9913647
    • 1999-08-16
    • EXXONMOBIL CHEM PATENTS INC
    • WENG WEIQINGMARKEL ERIC JDEKMEZIAN ARMENAG HARJUNAN PALANISAMY
    • C08L23/00C08F2/06C08F4/645C08F4/659C08F10/06C08F110/06C08L23/10C08L23/12
    • Branched polypropylene compositions which have improved melt strength and good processability are provided. The branched polypropylene compositions of the present invention have a polydispersity of less than 4.0 and a melt point greater than 90° C. Further, the weight average branching index g of the polypropylene compositions is less than 0.95. Additionally, a novel process is provided for efficiently producing a branched polypropylene composition comprising:a) contacting propylene monomers in a reactor with an inert hydrocarbon solvent or diluent and a catalyst composition comprising one or more single site catalyst compounds capable of producing stereospecific polypropylene at a temperature from about 40° C. to about 120° C., wherein the ratio in the reactor of the propylene monomers to the inert hydrocarbon solvent or diluent is less than 9.0, and further, wherein the propylene monomers and the inert hydrocarbon solvent or diluent comprise at least 50 weight percent of the total contents of the reactor; andb) recovering a branched polypropylene composition having a polydispersity of less than or equal to 4.0 and a melting point greater than 90° C. wherein the weight average branching index, g, of the branched polypropylene composition is less than 0.95.