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61. 发明授权

US08519060B2 Amphiphilic graft polymers based on polyalkylene oxides and vinyl esters 有权
标题翻译：基于聚环氧烷和乙烯基酯的两亲接枝聚合物
公开(公告)号：US08519060B2
公开(公告)日：2013-08-27
申请号：US12302386
申请日：2007-05-29
申请人： Dieter Boeckh , Lidcay Herrera Taboada , Asimina Kavarnou-Seiler , Gerd Konrad , Birgit Reinhard , Arturo Luis Casado Dominguez , James Danziger , Frank Huelskoetter
发明人： Dieter Boeckh , Lidcay Herrera Taboada , Asimina Kavarnou-Seiler , Gerd Konrad , Birgit Reinhard , Arturo Luis Casado Dominguez , James Danziger , Frank Huelskoetter
IPC分类号： C08F283/06
CPC分类号： C08F283/06 , C11D3/3788
摘要： Amphiphilic graft polymers based on water-soluble polyalkylene oxides (A) as a graft base and side chains formed by polymerization of a vinyl ester component (B), said polymers having an average of ≦1 graft site per 50 alkylene oxide units and mean molar masses Mw of from 3000 to 100 000.
摘要翻译：基于作为接枝基的水溶性聚环氧烷（A）和通过乙烯基酯组分（B）的聚合形成的侧链的两亲性接枝聚合物，所述聚合物平均具有每50个氧化烯单元的1个接枝部位和平均摩尔数质量Mw为3000〜100000。

62. 发明授权

US08507613B2 Process for the alkoxylation of amino group containing polymers 有权
标题翻译：含氨基聚合物的烷氧基化方法
公开(公告)号：US08507613B2
公开(公告)日：2013-08-13
申请号：US12743754
申请日：2008-11-17
申请人： Dieter Boeckh , Stefan Frenzel , Christian Bittner , Andrea Misske , Ulrich Annen , Wilfried Sager , Sophia Ebert , Andreas Eichhorn
发明人： Dieter Boeckh , Stefan Frenzel , Christian Bittner , Andrea Misske , Ulrich Annen , Wilfried Sager , Sophia Ebert , Andreas Eichhorn
IPC分类号： C08G65/00 , C08G65/30
CPC分类号： C08G65/2618 , C08G65/2633 , C08G65/2648 , C08L71/02 , C08L77/00 , C08L79/00 , C08L2666/20
摘要： The present invention relates to a process for the alkoxylation of a first polymer comprising at least one monomer unit having NH groups and optionally NH2 groups, wherein the first polymer has a molecular weight Mw of at least 500 g/mol, comprising the steps of (a) reacting the first polymer with alkylene oxide in a reaction mixture comprising a solvent until the average degree of alkoxylation of each NH group and each optional NH2 group, calculated as two NH groups, is from 0.75 to 1.25; (b) adding a second polymer of formula (I), wherein R is a linear or branched alkyl group having from 1 to 20 carbon atoms, each R′ is independently a linear or branched alkyl group having from 1 to 20 carbon atoms or hydrogen, each n is independently from 1 to 5 and m is from 5 to 40, to the reaction mixture of step (a); (c) at least partially removing the solvent from the reaction mixture of step (b); and (d) further reacting the reaction mixture of step (c) with alkylene oxide at a given temperature until the average degree of alkoxylation of each NH group and each optional NH2 group, calculated as two NH groups, of the first polymer is from 2 to 40. The present invention also relates to a polymer composition obtainable from that process and the use of such a polymer composition.
摘要翻译：本发明涉及第一聚合物的烷氧基化方法，其包含至少一个具有NH基团和任选的NH 2基团的单体单元，其中第一聚合物的分子量Mw至少为500g / mol，包括步骤（ a）在包含溶剂的反应混合物中使第一聚合物与烯化氧反应，直到每个NH基团和每个任选的NH 2基团的平均烷氧基化程度计算为两个NH基团为0.75至1.25; （b）添加式（I）的第二聚合物，其中R是具有1至20个碳原子的直链或支链烷基，每个R'独立地是具有1至20个碳原子的直链或支链烷基或氢相对于步骤（a）的反应混合物，每个n独立地为1至5，m为5至40。（c）至少部分地从步骤（b）的反应混合物中除去溶剂; 和（d）在给定温度下使步骤（c）的反应混合物与烯化氧进一步反应，直到第一聚合物的NH基团和每个任选的NH 2基团的平均烷氧基化程度计算为两个NH基团为2 本发明还涉及可从该方法获得的聚合物组合物和这种聚合物组合物的用途。

63. 发明授权

US08097579B2 Cleaning compositions with amphiphilic water-soluble polyalkylenimines having an inner polyethylene oxide block and an outer polypropylene oxide block 有权
标题翻译：具有内聚环氧乙烷嵌段和外部聚环氧丙烷嵌段的两亲性水溶性聚亚烷基亚胺的清洗组合物
公开(公告)号：US08097579B2
公开(公告)日：2012-01-17
申请号：US12266791
申请日：2008-11-07
申请人： James Lee Danziger , Frank Hulskotter , Dieter Boeckh , Sophia Ebert , Andrea Misske , Stefan Frenzel
发明人： James Lee Danziger , Frank Hulskotter , Dieter Boeckh , Sophia Ebert , Andrea Misske , Stefan Frenzel
IPC分类号： C11D3/37 , C11D3/30
CPC分类号： C11D3/3723
摘要： Laundry detergent and cleaning compositions comprising amphiphilic water-soluble alkoxylated polyalkylenimine polymer having an inner polyethylene oxide block comprising 20 to 50 polyethylene oxide units and an outer polypropylene oxide block comprising 10 to 50 polyethylene oxide units and especially to such alkoxylated polyalkylenimines wherein the ratio of polyethylene oxide units and polypropylene oxide units is proportionally related to the square root of the number of polyalkylenimine units present in the backbone.
摘要翻译：包含两亲性水溶性烷氧基化聚亚烷基亚胺聚合物的洗衣洗涤剂和清洁组合物，其具有包含20至50个聚环氧乙烷单元的内部聚环氧乙烷嵌段和包含10至50个聚环氧乙烷单元的外部聚环氧丙烷嵌段，特别是该烷氧基化聚亚烷基亚胺，其中聚乙烯氧化物单元和聚环氧丙烷单元与存在于主链中的聚亚烷基亚胺单元的数量的平方根成比例地相关。

64. 发明申请

US20110281782A1 CARE POLYMERS 有权
公开(公告)号：US20110281782A1
公开(公告)日：2011-11-17
申请号：US13105201
申请日：2011-05-11
申请人： Rajan Keshav Panandiker , Julie Ann Menkhaus , Dieter Boeckh , Rainer Dobrawa , Frank Huelskoetter , Valentin Cepus , Jack Tinsley , Klaus Muehlbach , Markus Brym , Sophia Ebert , Ivette Garcia Castro
发明人： Rajan Keshav Panandiker , Julie Ann Menkhaus , Dieter Boeckh , Rainer Dobrawa , Frank Huelskoetter , Valentin Cepus , Jack Tinsley , Klaus Muehlbach , Markus Brym , Sophia Ebert , Ivette Garcia Castro
IPC分类号： C11D17/00 , B08B3/00 , D06L1/16
CPC分类号： C11D3/373 , C11D3/001 , C11D3/3749 , D06M15/227 , D06M15/643 , D06M2200/50
摘要： The present application relates to care polymers and fabric and home care compositions comprising such care polymers, as well as processes for making and using such care polymers and such compositions. The performance of the care polymers that Applicants teach, can be further increased by following the emulsification teaching of the present specification and/or combining such care polymers with silicone materials.

65. 发明申请

US20110245142A1 FABRIC CARE COMPOSITIONS COMPRISING COPOLYMERS 有权
标题翻译：包含共聚物的织物护理组合物
公开(公告)号：US20110245142A1
公开(公告)日：2011-10-06
申请号：US13078067
申请日：2011-04-01
申请人： Yonas Gizaw , Matthew Lawrence Lynch , Valentin Cepus , Travis Kyle Hodgdon , Marcia Mary Ketcha , Lorenzo Matteo Pierre Gualco , Dieter Boeckh , Christofer Arisandy , Fleumingue Jean-Mary , Frank Hulskotter , Phillip Kyle Vinson , Jodi Lee Brown
发明人： Yonas Gizaw , Matthew Lawrence Lynch , Valentin Cepus , Travis Kyle Hodgdon , Marcia Mary Ketcha , Lorenzo Matteo Pierre Gualco , Dieter Boeckh , Christofer Arisandy , Fleumingue Jean-Mary , Frank Hulskotter , Phillip Kyle Vinson , Jodi Lee Brown
IPC分类号： C11D3/60
CPC分类号： C11D3/3769 , C11D3/001 , C11D3/373 , C11D3/50
摘要： Fabric care composition comprising copolymers exhibit increased fabric active deposition and acceptable composition stringiness.
摘要翻译：包含共聚物的织物护理组合物表现出增加的织物活性沉积和可接受的组合物拉伸性。

66. 发明授权

US07999035B2 Amphiphilic water-soluble alkoxylated polyalkylenimines with an internal polyethylene oxide block and an external polypropylene oxide block 有权
标题翻译：具有内部聚环氧乙烷嵌段和外部聚丙烯氧化物嵌段的两亲性水溶性烷氧基化聚亚烷基亚胺
公开(公告)号：US07999035B2
公开(公告)日：2011-08-16
申请号：US11911590
申请日：2006-04-12
申请人： Dieter Boeckh , Christian Bittner , Andrea Misske , Arturo Luis Casado Dominguez
发明人： Dieter Boeckh , Christian Bittner , Andrea Misske , Arturo Luis Casado Dominguez
IPC分类号： C08L53/00 , C08G73/00 , C08G73/04
CPC分类号： C11D3/3723 , C08G73/0206
摘要： Amphiphilic water-soluble alkoxylated polyalkylenimines of the general formula I in which the variables are each defined as follows: R are identical or different, linear or branched C2-C6-alkylene radicals; B is a branch; E is an alkylenoxy unit of the formula R1 is 1,2-propylene, 1,2-butylene and/or 1,2-isobutylene; R2 is ethylene; R3 is 1,2-propylene; R4 are identical or different radicals: hydrogen; C1-C4-alkyl; x, y, z are each from 2 to 150, where the sum of x+y+z means a number of alkylenimine units which corresponds to an average molecular weight Mw of the polyalkylenimine before the alkoxylation of from 300 to 10 000; m is a rational number from 0 to 2; n is a rational number from 6 to 18; p is a rational number from 3 to 12, where 0.8≦n/p≦1.0(x+y+z)1/2; and quaternization products thereof.
摘要翻译：通式I的两亲性水溶性烷氧基化聚亚烷基亚胺，其中各变量各自定义如下：R相同或不同，为直链或支链C 2 -C 6亚烷基; B是一个分支; E是式R 1的亚烷氧基单元是1,2-亚丙基，1,2-亚丁基和/或1,2-异丁烯; R2是乙烯; R3是1,2-亚丙基; R4是相同或不同的基团：氢; C 1 -C 4 - 烷基; x，y，z分别为2〜150，x + y + z的和表示烷氧基化前的聚亚烷基亚胺的平均分子量Mw为300〜10000的亚烷基亚胺单元数; m是从0到2的有理数; n是6到18的合理数; p是3到12的有理数，其中0.8＆nlE; n / p＆nlE; 1.0（x + y + z）1/2; 及其季铵化产物。

67. 发明申请

US20110130318A1 ENZYME COMPOSITION COMPRISING ENZYME CONTAINING POLYMER PARTICLES 有权
标题翻译：包含聚合物颗粒的酶的酶组合物
公开(公告)号：US20110130318A1
公开(公告)日：2011-06-02
申请号：US13003087
申请日：2009-07-07
申请人： Steffen Maas , Volker Schwendemann , Lidcay Herrera Taboada , Heike Pfistner , Dieter Boeckh , Ole Simonsen
发明人： Steffen Maas , Volker Schwendemann , Lidcay Herrera Taboada , Heike Pfistner , Dieter Boeckh , Ole Simonsen
IPC分类号： C11D17/00 , B29B9/16
CPC分类号： C11D3/38672 , C11D3/3757 , C11D3/3769 , C11D3/38663 , C11D11/0082
摘要： The present invention relates to an enzyme composition comprising enzyme containing polymer particles, which is useful for detergent compositions, in particular for liquid detergent compositions. In these enzyme containing particles, the particles comprise i) at least one enzyme, and ii) at least one polymer P, which is selected from homo- and copolymers having a backbone, wherein the C—C-backbone carries carboxylgroups, which may be present in the acidic form or in the neutralized form, and wherein the C—C-backbone comprises hydrophobic repeating units.
摘要翻译：本发明涉及一种包含含酶聚合物颗粒的酶组合物，其可用于洗涤剂组合物，特别是用于液体洗涤剂组合物。在这些含酶颗粒中，颗粒包含i）至少一种酶，和ii）至少一种聚合物P，其选自具有主链的均聚物和共聚物，其中C-C主链带有羧基，其可以是以酸性形式或以中和形式存在，并且其中C-C主链包含疏水性重复单元。

68. 发明授权

US07790667B2 Water-soluble copolymers of monoethylenically unsaturated polyalkylene oxide monomers and dipolar monomers containing at least one nitrogen atom 有权
标题翻译：单烯属不饱和聚环氧烷单体和含有至少一个氮原子的偶极单体的水溶性共聚物
公开(公告)号：US07790667B2
公开(公告)日：2010-09-07
申请号：US10579795
申请日：2004-11-16
申请人： Dieter Boeckh , Thomas Pfeiffer , Stefan Becker , Marcus Guzmann , Pramod Kakumanu Reddy , John Davis Aiken, III
发明人： Dieter Boeckh , Thomas Pfeiffer , Stefan Becker , Marcus Guzmann , Pramod Kakumanu Reddy , John Davis Aiken, III
IPC分类号： C11D3/37 , C08F220/00
CPC分类号： C11D3/3757 , C08F220/28 , C11D3/3723 , C11D3/3769
摘要： Water-soluble copolymers which comprise, in copolymerized form, (a) 60 to 99% by weight of at least one monoethylenically unsaturated polyalkylene oxide monomer of the formula I H2C═CR1—X—YR2—OnR3 I in which the variables have the following meanings: X is —CH2— or —C(O)—, if Y is —O—; is —C(O)—, if Y is —NH—; is —O— or —O—(CH2)4—, if Y is a chemical bond; Y is —O—, —NH— or a chemical bond; R1 is hydrogen or methyl; R2 is C2-C4-alkylene radicals, which may be identical or different and also linear or branched, but where at least 50% of the radicals R2 are ethylene; R3 is C1-C22-alkyl, phenyl, p-(C1-C12-alkyl)phenyl or hydrogen; n is an integer from 6 to 50, (b) 1 to 40% by weight of at least one nonquaternized dipolar monomer comprising at least one nitrogen atom, (c) 0 to 39% by weight of other nonionic monoethylenically unsaturated monomers and (d) 0 to 10% by weight of other anionic monoethylenically unsaturated monomers and have an average molecular weight Mw of from 2000 to 500 000 D, and the use of the copolymers as dispersants and sequestrants for pigmented materials, as additive for detergents, laundry pretreatment compositions, cleaners for hard surfaces, dentifrices and bodycare compositions, and as auxiliaries for textile processes, paper making and paper processing and deinking processes.
摘要翻译：以共聚形式包含（a）60-99重量％的至少一种式I的单烯键式不饱和聚环氧烷单体H 2 C = CR 1 -X-YR 2 -OnR 3 I的水溶性共聚物，其中变量具有以下含义：X是-CH 2 - 或-C（O） - ，如果Y是-O-; 是-C（O） - ，如果Y是-NH-; 是-O-或-O-（CH 2）4 - ，如果Y是化学键; Y是-O - ， - NH-或化学键; R1是氢或甲基; R 2是C 2 -C 4亚烷基，其可以相同或不同，并且也是直链或支链的，但是其中至少50％的基团R 2是亚乙基; R 3是C 1 -C 22 - 烷基，苯基，对（C 1 -C 12 - 烷基）苯基或氢; n为6〜50的整数，（b）1〜40重量％的至少一种含有至少一个氮原子的非季铵化偶极单体，（c）0〜39重量％的其他非离子单烯属不饱和单体和（d ）0至10重量％的其它阴离子单烯属不饱和单体，并且其平均分子量Mw为2000至500000 D，并且使用共聚物作为着色材料的分散剂和螯合剂，作为洗涤剂的添加剂，洗衣预处理组合物，硬表面清洁剂，洁齿剂和身体护理组合物，以及纺织工艺，造纸和纸张处理和脱墨过程的辅助材料。

69. 发明申请

US20090176935A1 AMPHIPHILIC GRAFT POLYMERS BASED ON POLYALKYLENE OXIDES AND VINYL ESTERS 有权
标题翻译：基于聚亚烷基氧化物和乙烯基酯的聚丙烯酰胺聚合物
公开(公告)号：US20090176935A1
公开(公告)日：2009-07-09
申请号：US12302386
申请日：2007-05-29
申请人： Dieter Boeckh , Lidcay Herrera Taboada , Asimina Kavarnou-Seiler , Gerd Konrad , Birgit Reinhard , Arturo Luis Casado Dominguez , James Danziger , Frank Huelskoetter
发明人： Dieter Boeckh , Lidcay Herrera Taboada , Asimina Kavarnou-Seiler , Gerd Konrad , Birgit Reinhard , Arturo Luis Casado Dominguez , James Danziger , Frank Huelskoetter
IPC分类号： C08G63/91
CPC分类号： C08F283/06 , C11D3/3788
摘要： Amphiphilic graft polymers based on water-soluble polyalkylene oxides (A) as a graft base and side chains formed by polymerization of a vinyl ester component (B), said polymers having an average of ≦1 graft site per 50 alkylene oxide units and mean molar masses Mw of from 3000 to 100 000.
摘要翻译：基于作为接枝基的水溶性聚环氧烷（A）和通过乙烯基酯组分（B）的聚合形成的侧链的两亲性接枝聚合物，所述聚合物平均每50个环氧烷单元具有<= 1个接枝部位和平均值摩尔质量Mw为3000〜100000。

70. 发明申请

US20090124531A1 CLEANING COMPOSITIONS WITH AMPHIPHILIC WATER-SOLUBLE POLYALKYLENIMINES HAVING AN INNER POLYETHYLENE OXIDE BLOCK AND AN OUTER POLYPROPYLENE OXIDE BLOCK 有权
标题翻译：具有内含聚乙烯氧化物嵌段和外部聚丙烯氧化物嵌段的水溶性聚亚烷基二胺的清洁组合物
公开(公告)号：US20090124531A1
公开(公告)日：2009-05-14
申请号：US12266791
申请日：2008-11-07
申请人： James Lee Danziger , Frank Hulskotter , Dieter Boeckh , Sophia Ebert , Andrea Misske , Stefan Frenzel
发明人： James Lee Danziger , Frank Hulskotter , Dieter Boeckh , Sophia Ebert , Andrea Misske , Stefan Frenzel
IPC分类号： C11D3/37 , C08F16/28
CPC分类号： C11D3/3723
摘要： Laundry detergent and cleaning compositions comprising amphiphilic water-soluble alkoxylated polyalkylenimine polymer having an inner polyethylene oxide block comprising 20 to 50 polyethylene oxide units and an outer polypropylene oxide block comprising 10 to 50 polyethylene oxide units and especially to such alkoxylated polyalkylenimines wherein the ratio of polyethylene oxide units and polypropylene oxide units is proportionally related to the square root of the number of polyalkylenimine units present in the backbone.
摘要翻译：包含两亲性水溶性烷氧基化聚亚烷基亚胺聚合物的洗衣洗涤剂和清洁组合物，其具有包含20至50个聚环氧乙烷单元的内部聚环氧乙烷嵌段和包含10至50个聚环氧乙烷单元的外部聚环氧丙烷嵌段，特别是该烷氧基化聚亚烷基亚胺，其中聚乙烯氧化物单元和聚环氧丙烷单元与存在于主链中的聚亚烷基亚胺单元的数量的平方根成比例地相关。

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