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    • 69. 发明申请
    • NAPHTHALENE BASED EPOXY FOR HALOGEN-FREE AND FLAME RETARDANT COMPOSITIONS
    • 用于无卤素和阻燃组合物的基于萘基的环氧化合物
    • WO2016029452A1
    • 2016-03-03
    • PCT/CN2014/085580
    • 2014-08-29
    • BLUE CUBE IP LLCSONG, XiaomeiCHEN, HongyuMULLINS, Michael J.LU, Fujun
    • SONG, XiaomeiCHEN, HongyuMULLINS, Michael J.LU, Fujun
    • C08L63/00B32B15/14B32B15/092
    • C08G59/22C08G59/4071
    • A curable composition comprising, consisting of, or consisting essentially of a) an epoxy component comprising a dinaphthalene epoxy having the structure (X) wherein each R 1 group is independently a C1-C20 hydrocarbon; a is an integer in the range of from 0 to 6; m is an integer in the range of 0 to 5; and b) a hardener component comprising i) a naphthol novolac which is a reaction product of I) from 1 to 99 weight percent 1-naphthol and II) from 1 to 99 weight percent 2-naphthol; ii) a phosphorus-containing composition which is the reaction product of an etherified resole with 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide; and iii) optionally a phenolic resin selected from the group consisting of a molecule having at least one substituted or unsubstituted naphthalene ring, a high functionality phenolic resin, and combinations thereof, is disclosed. The curable composition can be used to prepare prepregs and electrical laminates.
    • 一种可固化组合物,其包含由以下组成或基本上由a组成的环氧组分,该环氧组分包含具有结构(X)的二萘环氧化物,其中每个R 1基团独立地为C 1 -C 20烃; a为0〜6的整数; m为0〜5的整数; 和b)硬化剂组分,其包含i)萘酚酚醛清漆,其为I)1至99重量%的1-萘酚和II)1至99重量%的2-萘酚的反应产物; ii)含醚组合物,其为醚化甲阶酚醛与9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物的反应产物; 和iii)任选地,选自具有至少一个取代或未取代的萘环的分子,高官能度酚醛树脂及其组合的酚醛树脂。 可固化组合物可用于制备预浸料和电层压材料。