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    • 61. 发明专利
    • DE502004001613D1
    • 2006-11-09
    • DE502004001613
    • 2004-03-19
    • BASF AG
    • DEININGER JUERGENDEMETER JUERGENKORY GADSOETJE OLIVERWINTERLING HELMUTZEHNER PETERHEEGER MICHAELGANN MARTINPOLT AXELTREULING ULRICHWEINLE WERNER
    • C08G69/00C08G69/04C08G69/16C08G69/28
    • Polyamides, oligomers thereof or mixtures thereof, if required with further reaction products, are prepared by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine, and, if required, further polyamide-forming monomers and/oligomers with water in a reactor ( 1 ) having a vertically oriented longitudinal axis, by a process in which, in the reactor ( 1 ), the reaction product is removed from the bottom and ammonia formed and any further low molecular weight compounds formed and water are taken off via the top ( 2 ), wherein the reactor ( 1 ) has at least two chambers ( 4 ) arranged one on top of the other in the longitudinal direction, the chambers ( 4 ) being separated from one another by liquid-tight trays ( 5 ), each chamber ( 4 ) being connected by a liquid overflow ( 6 ) to the chamber ( 4 ) directly underneath and a liquid product stream being taken off by the liquid overflow ( 6 ) of the lowermost chamber ( 4 ), the gas space ( 7 ) above the liquid level in each chamber ( 4 ) being connected to the chamber ( 4 ) arranged directly above in each case by one or more conduit pipes ( 8 ) which in each case opens or open into a gas distributor ( 9 ) having orifices ( 11 ) for gas exit below the liquid level, and comprising in each case at least one baffle plate ( 12 ) which is arranged vertically around each gas distributor ( 9 ) and whose upper end terminates below the liquid level and whose lower end terminates above the liquid-tight tray ( 5 ) of the chamber ( 4 ) and which separates each chamber ( 4 ) into one or more gassed ( 13 ) and into one or more ungassed ( 14 ) spaces.
    • 62. 发明专利
    • AT340819T
    • 2006-10-15
    • AT04721865
    • 2004-03-19
    • BASF AG
    • DEININGER JUERGENDEMETER JUERGENKORY GADSOETJE OLIVERWINTERLING HELMUTZEHNER PETERHEEGER MICHAELGANN MARTINPOLT AXELTREULING ULRICHWEINLE WERNER
    • C08G69/00C08G69/04C08G69/16C08G69/28
    • Polyamides, oligomers thereof or mixtures thereof, if required with further reaction products, are prepared by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitrile, dinitrile and diamine, and, if required, further polyamide-forming monomers and/oligomers with water in a reactor ( 1 ) having a vertically oriented longitudinal axis, by a process in which, in the reactor ( 1 ), the reaction product is removed from the bottom and ammonia formed and any further low molecular weight compounds formed and water are taken off via the top ( 2 ), wherein the reactor ( 1 ) has at least two chambers ( 4 ) arranged one on top of the other in the longitudinal direction, the chambers ( 4 ) being separated from one another by liquid-tight trays ( 5 ), each chamber ( 4 ) being connected by a liquid overflow ( 6 ) to the chamber ( 4 ) directly underneath and a liquid product stream being taken off by the liquid overflow ( 6 ) of the lowermost chamber ( 4 ), the gas space ( 7 ) above the liquid level in each chamber ( 4 ) being connected to the chamber ( 4 ) arranged directly above in each case by one or more conduit pipes ( 8 ) which in each case opens or open into a gas distributor ( 9 ) having orifices ( 11 ) for gas exit below the liquid level, and comprising in each case at least one baffle plate ( 12 ) which is arranged vertically around each gas distributor ( 9 ) and whose upper end terminates below the liquid level and whose lower end terminates above the liquid-tight tray ( 5 ) of the chamber ( 4 ) and which separates each chamber ( 4 ) into one or more gassed ( 13 ) and into one or more ungassed ( 14 ) spaces.
    • 63. 发明专利
    • METHOD FOR PRODUCING ALDEHYDES AND/OR ALCOHOLS OR AMINES
    • MY124357A
    • 2006-06-30
    • MYPI9903495
    • 1999-08-14
    • BASF AG
    • ZEHNER PETERULONSKA ARMINPACIELLO ROCCO
    • B01J3/00B01J3/02B01J10/00B01J19/00B01J19/24B01J19/26C07B61/00C07C45/50C07C47/02C07C209/60C07C211/00
    • A PROCESS FOR THE PREPARATION OF ALDEHYDES AND/OR ALCOHOLS OR AMINES BY REACTING OLEFINS IN THE LIQUID PHASE WITH CARBON MONOXIDE AND HYDROGEN,A PART OF THESE GASES BEING DISPERSED IN THE FORM OF GAS BUBBLES IN THE REACTION LIQUID AND ANOTHER PART BEING DISSOLVED IN THE REACTION LIQUID, IN THE PRESENCE OR ABSENCE OF A PRIMARY OR SECONDARY AMINE AND IN THE PRESENCE OF A COBALT CARBONYL, RHODIUM CARBONYL, PALLADIUM CARBONYL OR RUTHENIUM CARBONYL COMPLEX DISSOLVED HOMOGENEOUSLY IN THE REACTION LIQUID AND HAVING A PHOSPHORUS-, ARSENIC-, ANTIMONY-OR NITROGEN-CONTAINING LIGAND, AT ELEVATED TEMPERATURES AND AT 0.1 TO 10 MPA (1 TO 100 BAR), WHEREIN THE REACTION IS CARRIED OUT IN A VERTICALLY ARRANGED, TUBULAR REACTOR (1) COMPRISING A REACTOR BODY (2) AND AT LEAST ONE CIRCULATION LINE (3), A PART OF THE REACTION LIQUID IS FED CONTINUOUSLY VIA THE CIRCULATION LINE (3) TO AT LEAST ONE NOZZLE (5) WHICH IS MOUNTED IN THE UPPER PART OF THE REACTOR BODY AND IS COORDINATED WITH A GUIDE MEMBER (6), OPEN AT THE TOP AND BOTTOM AND BOUNDED BY PARALLEL WALLS, IN THE INTELIOR OF THE REACTOR AND WITH A BAFFLE (7) PRESENT BELOW THE LOWER OPENING OF THE GUIDE MEMBER (6), AND A DOWNWARD-DIRECTED LIQUID STREAM CONTAINING DISPERSED GAS BUBBLES IS PRODUCED BY MEANS OF THIS NOZZLE (5) IN THIS GUIDE MEMBER (6) AND, AFTER LEAVING THE GUIDE MEMBER (6), IS DEFLECTED INTO A STREAM FLOWING UPWARD IN THE SPACE BETWEEN THE WALL OF THE GUIDE MEMBER (6) AND THE WALL OF THE REACTOR BODY (2) AND IS SUCKED INTO THE GUIDE MEMBER (6) AT THE UPPER END OF THE GUIDE MEMBER (6) BY THE JET OF THE NOZZLE (5) COORDINATED WITH THE GUIDE MEMBER (6).(FIGURE 1)
    • 66. 发明专利
    • Method for producing alkyl aromatic compounds
    • AU2004230225A1
    • 2004-10-28
    • AU2004230225
    • 2004-04-14
    • BASF AG
    • ZEHNER PETERSTEINBRENNER ULRICHBENFER REGINAUNGER JORGZIMDAHL SOERENNARBESHUBER THOMAS
    • C07C2/66C07C15/107C07C303/06C07C303/08C07C309/31C07C2/70
    • Production of alkylaromatic compounds (I), by reacting 3-30C olefins (II) (or alcohols forming (II) under the reaction conditions) with aromatic hydrocarbons (III) in presence of an alkylation catalyst (IV), is carried out in a cascade of at least two reactors each containing (IV), where at least 80 % of (III) is supplied to the first reactor of the cascade and at least 40 % of (II) is supplied after the first reactor. An independent claim is included for the preparation of alkylarylsulfonates (A), by: (1) converting a 4C olefin mixture over a metathesis catalyst to give an olefin mixture containing 2-pentene and/or 2-hexene; (2) catalytically dimerizing the 2-pentene and/or 2-hexene (optionally after isolation) to give a mixture containing 10-12C olefins, optionally separating the 10-12C olefins and separating 5-30 wt. % (based on the 10-12C olefins) of low-boiling components of the 10-12C olefins; (3) reacting the obtained 10-12C olefin mixture with (III) in presence of (IV) to give alkylaromatic compounds (I'), optionally with addition of 0-60 wt. % (based on the 10-12C olefin mixture) of linear olefins before the reaction; (4) sulfonating (I') and neutralizing to give (A), optionally with addition of 0-60 wt. % (based on (I')) of linear alkylbenzenes (provided that no mixing has been carried out in the previous step); and (5) optionally mixing the obtained (A) with optionally with addition of 0-60 wt. % (based on (A)) of linear aralkylsulfonates (provided that no mixing has been carried out either of the previous two steps); The novel feature being that the reaction in the alkylation stage (3) is carried out as for the present procedure for preparing (I).
    • 67. 发明专利
    • METHOD FOR PRODUCING POLYAMIDES
    • CA2519816A1
    • 2004-10-07
    • CA2519816
    • 2004-03-19
    • BASF AG
    • DEMETER JURGENDEININGER JURGENWINTERLING HELMUTHEEGER MICHAELZEHNER PETERGANN MARTINKORY GADSOTJE OLIVERPOLT AXELTREULING ULRICHWEINLE WERNER
    • C08G69/00C08G69/04C08G69/16C08G69/28
    • The invention relates to a method for producing polyamides, their oligomers or mixtures thereof, optionally containing other reaction products, by reacting aminonitriles or dinitriles and diamines or a mixture containing aminonitril e, dinitrile and diamine and optionally additional polyamide-forming monomers and/or oligomers with water in a reactor (1) with a vertical longitudinal axis. According to said method, the reaction product is exfiltrated from the sump in the reactor (1) and accumulated ammonia and optionally other accumulated low-molecular compounds and water are drawn off via the head (2) . The invention is characterised in that the reactor (1) comprises at least tw o chambers (4) arranged in a longitudinal direction one above the other, that the chambers (4) are separated from one another by liquid-tight floors (5), that each chamber (4) is connected to the one (4) immediately below by a respective liquid overflow (6) and a liquid product stream is drawn off via the liquid overflow (6) of the lowest chamber (4), that the gas chamber (7) above the liquid level in each chamber (4) is connected to the respective chamber (4) lying immediately above it via one or several conduits (8), whic h open respectively into a gas diffuser (9) comprising orifices (11) for the discharge of gas below the liquid level. The reactor also comprises at least one respective deflector plate (12) positioned vertically around each gas diffuser (9), the upper end of said plate terminating below the liquid level and the lower end terminating above the liquid-tight floor (5) of the chambe r (4), thus sub-dividing each chamber (4) into one or more compartments suppli ed with gas (13) and one or more compartments without gas (14).