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    • 63. 发明授权
    • Conducting polymer-transition metal electro-catalyst compositions for fuel cells
    • 导电用于燃料电池的聚合物 - 过渡金属电催化剂组合物
    • US09318762B2
    • 2016-04-19
    • US11704873
    • 2007-02-12
    • Bor Z. JangAruna Zhamu
    • Bor Z. JangAruna Zhamu
    • H01M4/90H01M8/10H01B1/12H01M4/86H01M4/92
    • H01M8/1004H01B1/122H01M4/8605H01M4/8652H01M4/9008H01M4/921H01M2008/1095Y02E60/521Y02E60/523
    • An electro-catalyst composition for use as an electrode, gas diffusion layer-supported electrode, catalytic electrode-coated solid electrolyte layer, and/or membrane-electrode assembly in a proton exchange membrane (PEM) type fuel cell. The composition comprises: (a) a proton- and electron-conducting polymer having at least one heteroatom per backbone monomer unit thereof and a plurality of neutral transition metal atoms covalently bonded to at least a portion of the heteroatoms; wherein the polymer has an electronic conductivity no less than 10−4 S/cm and a proton conductivity no less than 10−5 S/cm. Preferably, the electro-catalyst composition further comprises (b) a plurality of catalytically active particles of a transition metal, nucleated around the covalently bonded transition metal atoms. Also preferably, additional catalytically active catalyst particles with an average dimension smaller than 2 nm (most preferably smaller than 1 nm) are physically dispersed in such a polymer and typically not chemically bonded thereto. A hydrogen-oxygen PEM fuel cell or a direct methanol fuel cell (DMFC) featuring such an electro-catalyst composition in a thin-film electrode exhibits a superior current-voltage response.
    • 一种在质子交换膜(PEM)型燃料电池中用作电极的电催化剂组合物,气体扩散层支撑电极,催化电极涂覆的固体电解质层和/或膜 - 电极组件。 该组合物包含:(a)每个其主链单体具有至少一个杂原子的质子和导电聚合物和共价键合至至少一部分杂原子的多个中性过渡金属原子; 其中所述聚合物具有不小于10 -4 S / cm的电子传导率和不小于10-5S / cm的质子传导性。 优选地,电催化剂组合物还包含(b)多个催化活性的过渡金属颗粒,其在共价键合的过渡金属原子周围成核。 还优选地,平均尺寸小于2nm(最优选小于1nm)的另外的催化活性催化剂颗粒物理分散在这种聚合物中,并且通常不与其化学键合。 在薄膜电极中具有这种电催化剂组合物的氢氧PEM燃料电池或直接甲醇燃料电池(DMFC)表现出优异的电流 - 电压响应。
    • 64. 发明申请
    • Production of highly conductive graphitic films from polymer films
    • 从聚合物薄膜生产高导电性石墨膜
    • US20160059444A1
    • 2016-03-03
    • US14121387
    • 2014-08-29
    • Yanbo WangBor Z. JangDavid BurtonLucy FuAruna Zhamu
    • Yanbo WangBor Z. JangDavid BurtonLucy FuAruna Zhamu
    • B29C35/02C01B31/04
    • C01B31/04C01B32/20C01P2006/10C01P2006/32C01P2006/40
    • A one-step (direct graphitization) process for producing a graphitic film, comprising directly feeding a precursor polymer film, without going through a carbonization step, to a graphitization zone preset at a graphitization temperature no less than 2,200° C. for a period of residence time sufficient for converting the precursor polymer film to a porous graphitic film having a density from 0.1 g/cm3 to 1.5 g/cm3 and retreating the porous graphitic film from the graphitization zone. Preferably, the precursor polymer film is selected from the group consisting of polyimide, polyamide, phenolic resin, polyoxadiazole, polybenzoxazole, polybenzobisoxazole, polythiazole, polybenzothiazole, polybenzobisthiazole, poly(p-phenylene vinylene), polybenzimidazole, polybenzobisimidazole, polyacrylonitrile, and combinations thereof. Preferably, the precursor polymer film contains an amount of graphene sheets or expanded graphite flakes, preferably from 1% to 90% by weight, sufficient for promoting or accelerating graphitization.
    • 用于生产石墨膜的一步(直接石墨化)方法,包括直接将前体聚合物膜直接进料到不经过碳化步骤的石墨化区域,石墨化区域以石墨化温度不低于2200℃预设一段时间 将前体聚合物膜转化为密度为0.1g / cm 3至1.5g / cm 3的多孔石墨膜,并从石墨化区域中回收多孔石墨膜的足够的停留时间。 优选地,前体聚合物膜选自聚酰亚胺,聚酰胺,酚醛树脂,聚恶二唑,聚苯并恶唑,聚苯并双恶唑,聚噻唑,聚苯并噻唑,聚苯并二噻唑,聚(对亚苯基亚乙烯基),聚苯并咪唑,聚苯并双咪唑,聚丙烯腈及其组合。 优选地,前体聚合物膜含有足以促进或加速石墨化的量的石墨烯片或膨胀石墨片,优选为1重量%至90重量%。
    • 65. 发明申请
    • Graphene foam-protected anode active materials for lithium batteries
    • 用于锂电池的石墨烯泡沫保护阳极活性材料
    • US20160043384A1
    • 2016-02-11
    • US14121151
    • 2014-08-07
    • Aruna ZhamuBor Z. Jang
    • Aruna ZhamuBor Z. Jang
    • H01M4/133H01M4/04H01M4/587
    • H01M4/133H01M4/0471H01M4/134H01M4/1393H01M4/364H01M4/366H01M4/386H01M4/387H01M4/587H01M10/052H01M2004/021
    • A lithium-ion battery anode layer, comprising an anode active material embedded in pores of a solid graphene foam composed of multiple pores and pore walls, wherein (a) the pore walls contain a pristine graphene material having essentially no (less than 0.01%) non-carbon elements or a non-pristine graphene material having 0.01% to 5% by weight of non-carbon elements; (b) the anode active material is in an amount from 0.5% to 95% by weight based on the total weight of the graphene foam and the anode active material combined, and (c) some of the multiple pores are lodged with particles of the anode active material and other pores are particle-free, and the graphene foam is sufficiently elastic to accommodate volume expansion and shrinkage of the particles of the anode active material during a battery charge-discharge cycle to avoid expansion of the anode layer. Preferably, the solid graphene foam has a density from 0.01 to 1.7 g/cm3, a specific surface area from 50 to 2,000 m2/g, a thermal conductivity of at least 100 W/mK per unit of specific gravity, and/or an electrical conductivity no less than 1,000 S/cm per unit of specific gravity.
    • 一种锂离子电池阳极层,包括嵌入由多个孔和孔壁组成的固体石墨烯泡沫的孔中的阳极活性物质,其中(a)孔壁含有基本上没有(小于0.01%)的原始石墨烯材料, 非碳元素或具有0.01重量%至5重量%的非碳元素的非原始石墨烯材料; (b)所述负极活性物质的量相对于所述石墨烯泡沫和所述负极活性物质的总重量为0.5〜95重量%,(c)所述多个孔中的一些与所述 阳极活性材料和其它孔是无颗粒的,并且石墨烯泡沫具有足够的弹性,以适应在电池充放电循环期间阳极活性材料颗粒的体积膨胀和收缩,以避免阳极层膨胀。 优选地,固体石墨烯泡沫的密度为0.01至1.7g / cm 3,比表面积为50至2,000m 2 / g,每单位比重至少为100W / mK的热导率和/或电 电导率不低于每单位比重1000 S / cm。
    • 66. 发明申请
    • Highly conductive graphene foams and process for producing same
    • 高导电性石墨烯泡沫及其制造方法
    • US20160019995A1
    • 2016-01-21
    • US14120959
    • 2014-07-17
    • Aruna ZhamuBor Z. Jang
    • Aruna ZhamuBor Z. Jang
    • H01B1/04H01B13/32H01B13/00H01B13/30C01B31/04H01B5/16
    • A process for producing a solid graphene foam composed of multiple pores and pore walls The process comprises: (a) preparing a graphene dispersion having a graphene material dispersed in a liquid medium, which contains an optional blowing agent; (b) dispensing and depositing the graphene dispersion onto a supporting substrate to form a wet layer of graphene material having a preferred orientation; (c) partially or completely removing the liquid medium from the wet layer of graphene material to form a dried layer of graphene material having a content of non-carbon elements no less than 5% by weight (including blowing agent weight); and (d) heat treating the layer of graphene material at a first heat treatment temperature from 80° C. to 3,200° C. at a desired heating rate sufficient to induce volatile gas molecules from the non-carbon elements or to activate the blowing agent for producing the graphene foam having a density from 0.01 to 1.7 g/cm3 or a specific surface area from 50 to 3,000 m2/g.
    • 一种生产由多孔和孔壁组成的固体石墨烯泡沫的方法该方法包括:(a)制备分散在含有任选的发泡剂的液体介质中的石墨烯材料的石墨烯分散体; (b)将石墨烯分散体分配并沉积到支撑基底上以形成具有优选取向的石墨烯材料的湿层; (c)从石墨烯材料的湿层部分或完全地去除液体介质以形成具有不少于5重量%(包括发泡剂重量)的非碳元素含量的石墨烯材料干燥层; 和(d)以足以从非碳元素诱导挥发性气体分子或活化发泡剂的所需加热速率在第一热处理温度从80℃至3200℃下热处理所述石墨烯材料层 用于生产密度为0.01至1.7g / cm 3或比表面积为50至3,000m 2 / g的石墨烯泡沫。
    • 70. 发明申请
    • Cathode active material-coated discrete graphene sheets for lithium batteries and process for producing same
    • 用于锂电池的阴极活性材料涂层离散石墨烯片及其制造方法
    • US20150044556A1
    • 2015-02-12
    • US13987567
    • 2013-08-08
    • Yanbo WangBor Z. JangHui HeAruna Zhamu
    • Yanbo WangBor Z. JangHui HeAruna Zhamu
    • H01M4/36H01M4/04
    • H01M4/366H01M4/04H01M4/0421H01M4/13H01M4/139H01M4/625H01M10/056H01M2004/028Y10T156/1075
    • The present invention provides a cathode (positive electrode) of a lithium battery and a process for producing this cathode. The electrode comprises a cathode active material-coated graphene sheet and the graphene sheet has two opposed parallel surfaces, wherein at least 50% area (preferably >80%) of one of the two surfaces is coated with a cathode active material coating. The graphene material is in an amount of from 0.1% to 99.5% by weight and the cathode active material is in an amount of at least 0.5% by weight (preferably >80% and more preferably >90%), all based on the total weight of the graphene material and the cathode active material combined. The cathode active material is preferably an inorganic material, an organic or polymeric material, a metal oxide/phosphate/sulfide, or a combination thereof. The invention also provides a lithium battery, including a lithium-ion, lithium-metal, or lithium-sulfur battery.
    • 本发明提供锂电池的阴极(正电极)及其制造方法。 电极包括阴极活性材料涂覆的石墨烯片,并且石墨烯片具有两个相对的平行表面,其中两个表面中的一个表面的至少50%面积(优选> 80%)涂覆有阴极活性材料涂层。 石墨烯材料的量为0.1重量%至99.5重量%,正极活性物质的量为至少0.5重量%(优选> 80重量%,更优选> 90重量%),均基于总量 石墨烯材料和阴极活性材料的重量相结合。 阴极活性材料优选为无机材料,有机或聚合材料,金属氧化物/磷酸盐/硫化物或其组合。 本发明还提供一种锂电池,其包括锂离子,锂金属或锂硫电池。