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    • 61. 发明专利
    • CURABLE COMPOSITION
    • JPH10219099A
    • 1998-08-18
    • JP2691597
    • 1997-02-10
    • ASAHI GLASS CO LTD
    • KONDO SATOSHIYAMAMOTO HIROTSUGUSASAKURA HIDEFUMI
    • C08L27/12C08G18/10C08L29/10C08L33/04C08L75/04
    • PROBLEM TO BE SOLVED: To obtain a curable composition capable of developing excellent long-term weatherability, stain resistance and resistance to surface crack and useful as a sealing material, a waterproofing agent, etc., by compounding a polyurethane prepolymer as a curing component with a specific photosetting type fluorine-containing copolymer. SOLUTION: This curable composition contains (A) an isocyanate group-ended polyurethane prepolymer and (B) a photosetting type fluorine-containing copolymer containing a polymerization unit (B1 ) having a polyfluoroalkyl (B'1 ) and a polymerization unit (B2 ) having a photosetting type functional group (B'2 ) as essential components [e.g. a copolymer obtained by copolymerizing a monomer having a functional group (X) capable of introducing the unit B'2 with a monomer having the unit B'1 and introducing the unit B'2 such as (meth) acryloyl, cinnamoyl, azide group to the group X, having 300-100,000 number- average molecular weight and composed of 20-95mol% component B1 and 5-80mol% component B2 ], preferably so that a ratio of these components A/B becomes (100/0.1) to (100/40).
    • 68. 发明专利
    • Antireflective article and its manufacturing method
    • 反制品及其制造方法
    • JP2006082341A
    • 2006-03-30
    • JP2004268530
    • 2004-09-15
    • Asahi Glass Co Ltd旭硝子株式会社
    • ISHIZEKI KENJISHIMODA HIROSHIKONDO SATOSHI
    • B32B27/00C08G65/22
    • PROBLEM TO BE SOLVED: To provide an antireflective article having high-degree scratch resistance and abrasion resistance, excellent in anti-staining properties and stain removing properties and having high transparency, and its manufacturing method. SOLUTION: The antireflective article has an organic base material and the antireflection layer provided on the surface of the organic base material and successively composed of a hard coat layer, a high refractive index layer and a low refractive index layer from the base material side. The hard coat layer is a cured matter layer of an active energy ray curable coating composition (X) containing a compound having at least two polymerizable functional groups and the high refractive index layer is a cured matter layer of a polysilazane containing fine particles with a refractive index of 1.55 or above while the low refractive index layer is a cured matter layer of polysilazane containing a water and oil repellency imparting agent having a specific structure. COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:提供具有高度耐擦伤性和耐磨性,抗污染性和除污性优异且透明度高的抗反射制品及其制造方法。 防反射制品具有有机基材,抗反射层设置在有机基材的表面上,并从基材连续构成硬涂层,高折射率层和低折射率层 侧。 硬涂层是含有具有至少两个聚合性官能团的化合物的活性能量射线固化性涂料组合物(X)的固化物层,高折射率层是含有具有折射率的微粒的聚硅氮烷的固化物质层 指数为1.55以上,低折射率层为聚硅氮烷的固化物层,其含有具有特定结构的拒油拒油剂。 版权所有(C)2006,JPO&NCIPI
    • 69. 发明专利
    • Silane coupling group-containing fluorine-containing ether compound, solution composition, coating film and article
    • 含硅氟化合物的含硅氟化合物,溶液组合物,涂膜和文章
    • JP2005350404A
    • 2005-12-22
    • JP2004173788
    • 2004-06-11
    • Asahi Glass Co Ltd旭硝子株式会社
    • SHIRAKAWA DAISUKEOHARU KAZUYAKONDO SATOSHI
    • C09K3/18C07B61/00C07F7/18C09D183/08
    • PROBLEM TO BE SOLVED: To provide a new compound which can form a strong bond to each other or to any other member, is free from deterioration, and can be used as a coating for forming coating films having excellent water and oil-repelling properties, stain-removing property, lubricity and low refractive indexes, and the like.
      SOLUTION: This fluorine-containing ether compound represented by formula (1) : X-(Y(Z))
      a -X (1) {X is a perfluorosaturated hydrocarbon group represented by the general formula (2) : R
      F O(CF
      2 CF
      2 O)
      b (CF
      2 )
      p (CH
      2 )
      o - (2) [R
      F is a perfluoroalkyl or a group obtained by inserting an etheric oxygen atom between the carbon-carbon atoms of the perfluoroalkyl group; (b) is 3 to 200; (p) is ≥1; (o) is an integer of ≥0], a group obtained by inserting an etheric oxygen between the carbon-carbon atoms of the group; X does not have -OCF
      2 O- structure; Y is a group having two or more carbon atoms; Z is a group of formula (3) : -Si(Z
      1 )
      c (Z
      2 )
      (3-c) (3) [Z
      1 is a group capable of being released to condense; Z
      2 is H or a monovalent inactive organic group; (c) is an integer of 1 to 3; (a) is an integer of ≥1]}.
      COPYRIGHT: (C)2006,JPO&NCIPI
    • 要解决的问题:为了提供能够彼此形成强结合的新化合物或任何其它构件,不会变质,并且可以用作形成具有优异的油和油的涂膜的涂层, 排斥性,去污性,润滑性和低折射率等。 解决方案:由式(1)表示的含氟醚化合物:X-(Y(Z))-SX(1)äX是由通式(1)表示的全氟代烃基 (2):R(SP) O(CF 2 CF 2 / SB>)(CH 2 - (2)[R F SP]是全氟烷基或 通过在全氟烷基的碳 - 碳原子之间插入醚性氧原子获得的基团; (b)为3〜200; (p)≥1; (o)是≥0的整数],通过在该基团的碳 - 碳原子之间插入醚氧而获得的基团; X不具有-OCF 2 O-结构; Y是具有两个或更多个碳原子的基团; Z是式(3)的基团:-Si(Z 1 (Z 2 )SB(3-c) (3)[Z 1 是能够释放冷凝的基团; Z 2 是H或单价无活性有机基团; (c)为1〜3的整数。 (a)为≥1]}的整数。 版权所有(C)2006,JPO&NCIPI
    • 70. 发明专利
    • Composition for active energy ray-curing type coating and plastic molding
    • 用于活性能量固化型涂料和塑料模塑的组合物
    • JP2005054029A
    • 2005-03-03
    • JP2003285225
    • 2003-08-01
    • Asahi Glass Co Ltd旭硝子株式会社
    • KONDO SATOSHI
    • B32B27/08C09D4/00C09D5/00C09D7/12C09D175/16C09D183/10
    • PROBLEM TO BE SOLVED: To obtain a coating composition that is cured by irradiating with active energy ray and forms a coating film composed of a cured material having excellent abrasion resistance and transparency and developing excellent antistatic property, a coating composition that forms a coating film composed of a cured material having excellent lubricating properties and/or fingerprint adhesion resistance besides the above physical properties and a plastic molding having a coating film composed of the cured material of one of the coating compositions.
      SOLUTION: The coating composition comprises 100 parts by mass of an active energy ray-curable polymerizable monomer (A) containing an active energy ray-curable polymerizable monomer (AI) containing a group in which the hydrogen of an alcoholic hydroxy group is substituted with an alkali metal atom and 0.1-500 parts by mass (calculated as solid) of colloidal silica (B). The coating composition comprises a compound having a silicone-containing part or a fluorine-containing part. The plastic molding has a coating film composed of the cured material of one of the coating compositions.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题为了获得通过用活性能量射线照射而固化的涂料组合物,并形成由具有优异的耐磨性和透明性并且显影出优异的抗静电性的固化材料构成的涂膜,形成 除了上述物理性质外,由具有优异的润滑性和/或指纹粘附性的固化物构成的涂膜和具有由其中一种涂料组合物的固化材料构成的涂膜的塑料模制品。 < P>解决方案:涂料组合物包含100质量份含有活性能量射线固化型可聚合单体(AI)的活性能量射线固化型可聚合单体(A),其含有醇羟基的氢为 被碱金属原子取代为0.1〜500质量份(以固体计算)胶体二氧化硅(B)。 涂料组合物包含具有含硅氧烷的部分或含氟部分的化合物。 塑料模制品具有由一种涂料组合物的固化材料构成的涂膜。 版权所有(C)2005,JPO&NCIPI