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61. 发明公开

KR1020040027104A 열가소성 난연성 수지 조성물 有权
标题翻译：热塑性阻燃树脂组合物
公开(公告)号：KR1020040027104A
公开(公告)日：2004-04-01
申请号：KR1020020058847
申请日：2002-09-27
申请人： 제일모직주식회사
发明人： 홍상현 , 안성희 , 배수학
IPC分类号： C08L55/02 , C08L25/12 , C08L71/12 , C08K5/527
CPC分类号： C08L55/02 , C08J2300/22 , C08K5/527 , C08L25/08 , C08L25/12 , C08L71/12 , C08L2201/02 , C08L2205/02 , C08L2205/035
摘要： PURPOSE: Provided is a composition of styrene thermoplastic fire retardant which has excellent fire retardant property as well as heat resistance, tensile strength and impact strength. CONSTITUTION: The composition comprises: (A) 40-95wt.% rubber-modified styrene resin containing (a1) 20-100wt.% of styrene-acrylonitrile graft copolymer having 10-60wt.% rubber and 18-50wt.% of styrene-acrylonitrile except the rubber content and (a2) 0-80wt.% of styrene-acrylonitrile copolymer resin having 18-50wt.% of acrylonitrile; (B) 5-60wt.% of polyphenylene ether resin; (C) 10-40wt.% of styrene resin; (D) 2-30wt.% of styrene-acrylonitrile copolymer resin (based on 100wt.% of (A)+(B)+(C)) having 5-18wt.% of acrylonitrile; and (E) 0.5-30wt.% of cyclic alkyl phosphonic acid compound (based on 100wt.% of the basic resin of (A)+(B)+(C)).
摘要翻译：目的：提供苯乙烯热塑性阻燃剂的组合物，其具有优异的阻燃性能，耐热性，拉伸强度和冲击强度。组成：该组合物包含：（A）40-95重量％的橡胶改性苯乙烯树脂，其含有（a1）20-100重量％的具有10-60重量％橡胶的苯乙烯 - 丙烯腈接枝共聚物和18-50重量％的苯乙烯 - 除了橡胶含量以外的丙烯腈和（a2）含有18-50重量％丙烯腈的苯乙烯 - 丙烯腈共聚物树脂的0-80重量％（B）5-60重量％的聚苯醚树脂; （C）10-40重量％的苯乙烯树脂; （D）2-30重量％的苯乙烯 - 丙烯腈共聚物树脂（基于100重量％的（A）+（B）+（C）），丙烯腈为5-18重量％和（E）0.5-30重量％的环烷基膦酸化合物（基于（A）+（B）+（C））的碱性树脂的100重量％。

62. 发明授权

KR100397366B1 난연성 열가소성 수지조성물 失效
标题翻译： 난연성열가소성수지조성물
公开(公告)号：KR100397366B1
公开(公告)日：2003-09-13
申请号：KR1020010042730
申请日：2001-07-16
申请人： 제일모직주식회사
发明人： 홍상현 , 안성희 , 장영길
IPC分类号： C08K5/521
摘要： PURPOSE: Provided is a fire retardant thermoplastic resin composition which has good fire retardancy irrespective of the kind of a resin by using en epoxy resin having a good char generating property together with a phosphorus-based compound. CONSTITUTION: The thermoplastic resin composition comprises 100 parts by weight of a thermoplastic resin; 0.1-50 parts by weight of an epoxy derivative represented by the formula 1; 1-50 parts by weight of a phosphorus-based compound; and optionally 0-50 parts by weight of at least one additive selected from the group consisting of a dropping preventer, a plasticizer, a heat stabilizer, an antioxidizing agent, a photo stabilizer, a compatibilizer, a pigment and/or dye and an inorganic additive. In formula 1, X is an alkyl group of C1-C34, an aryl group, an aryl group substituted with an alkyl group, an aralkyl group, or an O, N, P or S-containing alkyl, aryl or aryl group substituted with an alkyl group.
摘要翻译：目的：提供一种阻燃热塑性树脂组合物，其通过使用具有良好炭生成性能的环氧树脂与磷基化合物一起使用，不管树脂的种类如何，都具有良好的阻燃性。构成：热塑性树脂组合物包含100重量份的热塑性树脂; 0.1-50重量份的由式1表示的环氧衍生物; 1-50重量份的磷基化合物; 和任选的0-50重量份的至少一种选自防滴剂，增塑剂，热稳定剂，抗氧化剂，光稳定剂，增容剂，颜料和/或染料以及无机颜料的添加剂添加剂。在式1中，X是C1-C34的烷基，芳基，被烷基取代的芳基，芳烷基或被含有O，N，P或S的烷基，芳基或芳基取代的烷基。

63. 发明授权

KR100379879B1 내열성과 내충격성이 우수한 열가소성 수지 조성물 失效
标题翻译： 내열성과내충소이우수한열가소성수지조성물
公开(公告)号：KR100379879B1
公开(公告)日：2003-04-11
申请号：KR1020000083858
申请日：2000-12-28
申请人： 제일모직주식회사
发明人： 장복남 , 안성희 , 양재호 , 홍상현 , 장영길 , 배수학
IPC分类号： C08L55/02
摘要： PURPOSE: Provided is a thermoplastic resin composition excellent in heat-resistance and impact-resistance, which contains a styrene-acrylonitrile copolymer as a compatibilizer and can be recycled. CONSTITUTION: The thermoplastic resin composition comprises: 50-90wt% of an acrylonitrile-butadiene-styrene(ABS) copolymer resin produced by graft-copolymerizing 10-60wt% of a butadiene rubber with an average particle size of 0.1-4 micrometer and 40-90wt% of a monomer mixture comprising 50-82wt% of an aromatic vinyl monomer and 50-18wt% of an unsaturated nitrile monomer, wherein the aromatic vinyl monomer is styrene, alpha-methyl styrene, or p-methyl styrene and the unsaturated nitrile monomer is acrylonitrile or methacrylonitrile; 5-45wt% of a polyphenylene ether resin such as poly(2,6-dimethyl-1,4-phenylene)ether; 5-20wt% of the styrene-acrylonitrile copolymer resin containing 5-18wt% of acrylonitrile.
摘要翻译：目的：提供一种耐热性和耐冲击性优异的热塑性树脂组合物，其包含作为增容剂的苯乙烯 - 丙烯腈共聚物并可再循环。构成：热塑性树脂组合物包括：50-60％重量的通过将10-60％重量的平均粒径为0.1-4微米的丁二烯橡胶和40％重量的丁二烯橡胶接枝共聚而制得的丙烯腈 - 丁二烯 - 苯乙烯（ABS） 90重量％的包含50-82重量％的芳族乙烯基单体和50-18重量％的不饱和腈单体的单体混合物，其中所述芳族乙烯基单体为苯乙烯，α-甲基苯乙烯或对甲基苯乙烯，并且不饱和腈单体是丙烯腈或甲基丙烯腈; 聚苯醚树脂如聚（2,6-二甲基-1,4-亚苯基）醚; 5-45wt％ 5-20wt％的含5-18wt％丙烯腈的苯乙烯 - 丙烯腈共聚物树脂。

64. 发明授权

KR100359903B1 열가소성 난연성 수지 조성물 失效
公开(公告)号：KR100359903B1
公开(公告)日：2002-11-07
申请号：KR1020000033619
申请日：2000-06-19
申请人： 제일모직주식회사
发明人： 장영길 , 장복남 , 안성희 , 양재호 , 홍상현
IPC分类号： C08L25/12 , C08L51/04 , C08L71/12 , C08L53/00
摘要： 본 발명은 (A) (a
1 ) 스티렌 함유 그라프트 공중합체 수지 20∼90 중량부, (a
2 ) 스티렌 함유 공중합체 수지 0∼80 중량부 및 (a
3 ) 스티렌계 수지 5∼40 중량부로 이루어지는 고무변성 스티렌계 수지 40∼95 중량부; (B) 폴리페닐렌에테르계 수지 5∼60 중량부; (C) 상기 기초수지 (A)+(B) 100 중량부에 대하여 아크릴로니트릴 함량이 5∼18 중량%인 스티렌-아크릴로니트릴 공중합체 수지 2∼30 중량부; (D) 상기 기초수지 (A)+(B) 100 중량부에 대하여 방향족 인산에스테르계 화합물 5∼30 중량부; 및 (E) 상기 기초수지 (A)+(B) 100 중량부에 대하여 스티렌-고무 블록 공중합체 0.5∼5 중량부로 이루어지는 열가소성 수지 조성물에 관한 것이다.

65. 发明公开

KR1020010063603A 난연성 고무강화 폴리스티렌 수지 조성물 失效
标题翻译：阻燃橡胶增强聚苯乙烯树脂组合物
公开(公告)号：KR1020010063603A
公开(公告)日：2001-07-09
申请号：KR1019990060779
申请日：1999-12-23
申请人： 제일모직주식회사
发明人： 양재호 , 장복남 , 안성희 , 홍상현 , 장영길
IPC分类号： C08L25/06
CPC分类号： C08L25/06 , C08K3/02 , C08K5/5333 , C08K2003/026 , C08L25/10 , C08L71/12 , C08L2201/02
摘要： PURPOSE: A fire retardant rubber reinforced polystyrene resin composition is provided which has excellent mechanical properties, thermostability, fire-retardancy and processability. CONSTITUTION: The fire retardant rubber reinforced polystyrene resin composition comprises: (A) 50-90 part by weight of rubber reinforced polystyrene resin; (B) 50-10 part by weight of polyphenylene ether resin; (C) 5-30 part by weight of aromatic phosphoric ester based on 100 part by weight of a base resin of (A)+(B); and (D) 0.5-5 part by weight of a red-phosphorous based on 100 part by weight of a base resin of (A)+(B).
摘要翻译：目的：提供具有优异的机械性能，耐热性，阻燃性和加工性的阻燃橡胶增强聚苯乙烯树脂组合物。构成：阻燃橡胶增强聚苯乙烯树脂组合物包括：（A）50-90重量份橡胶增强聚苯乙烯树脂; （B）50-10重量份聚苯醚树脂; （C）基于100重量份的（A）+（B）的基础树脂，5-30重量份的芳族磷酸酯; 和（D）基于100重量份的（A）+（B）的基础树脂的0.5-5重量份的红磷。

66. 发明公开

KR1020000055391A 쉬트 압출 다이 이형성이 우수한 스티렌계 열가소성 수지 조성물 失效
标题翻译：苯乙烯类型热塑性树脂组合物，具有优异的表面挤出功能
公开(公告)号：KR1020000055391A
公开(公告)日：2000-09-05
申请号：KR1019990003978
申请日：1999-02-05
申请人： 제일모직주식회사
发明人： 심형민 , 안성희 , 정종훈 , 안경현
IPC分类号： C08L25/08
CPC分类号： C08L25/08 , C08L25/10
摘要： PURPOSE: A styrene type thermoplastic resin composition which has excellent sheet extrusion die releasability, thereby improving work efficiency is provided by introducing fatty acids having an average diameter of 100 micrometer or less as a lubricant to ABS resin. CONSTITUTION: A styrene type thermoplastic resin composition which has excellent sheet extrusion die releasability is characteristically comprised of (A) graft copolymer resin of 25-40 wt.% containing styrene with rubber particles having average diameter of 0.28-0.40 micrometer, (B) base resin hundred parts by weight comprised of 60-70 wt.% of copolymer resin containing styrene, and (C) fatty acids having average diameter of 100 micrometer or less as a lubricant of 0.4-1.0 parts by weight. The graft copolymer resin containing styrene(A) has a grafting degree of 50-70 wt.% and a weight average molecular weight of 50000-60000, and the copolymer resin(B) has a weight average molecular weight of 120000-60000.
摘要翻译：目的：通过将平均粒径为100微米以下的脂肪酸作为润滑剂引入ABS树脂，提供了具有优异的片材挤出模头剥离性，从而提高加工效率的苯乙烯型热塑性树脂组合物。构成：具有优异的片材挤出模头剥离性的苯乙烯类热塑性树脂组合物的特征在于：（A）含有苯乙烯的25〜40重量％的接枝共聚物树脂，平均直径为0.28〜0.40微米的橡胶粒子，（B）树脂100重量份，包含60-70重量％的含苯乙烯的共聚物树脂，和（C）平均粒径为100微米或更小的脂肪酸作为0.4-1.0重量份的润滑剂。含有苯乙烯（A）的接枝共聚物树脂的接枝度为50-70重量％，重均分子量为50000-60000，共聚物树脂（B）的重均分子量为120000-60000。

67. 发明公开

KR1020150016852A 탄소나노튜브 분산액 및 이의 제조방법 无效
标题翻译：碳纳米管分散溶液及其制备方法
公开(公告)号：KR1020150016852A
公开(公告)日：2015-02-13
申请号：KR1020130092828
申请日：2013-08-05
申请人： 제일모직주식회사
发明人： 김용태 , 김병열 , 안성희 , 김중인
IPC分类号： C01B31/02 , B82B1/00 , B82B3/00
CPC分类号： C01B32/174 , B82B1/008 , B82B3/0033 , B82B3/0095 , C01B2202/04 , C01B2202/28
摘要： 본 발명의 탄소나노튜브 분산액은 입도 분포의 D99값이 50 ㎛ 이하인 탄소나노튜브; 니트릴 고무; 및 용매;를 포함하는 것을 특징으로 한다. 상기 탄소나노튜브 분산액은 경제적으로 탄소나노튜브를 용매에 균일하게 분산시킨 것이다.
摘要翻译：本发明的目的是提供一种能够将碳纳米管经济均匀地分散在溶剂上的碳纳米管分散体; 及其制造方法。更具体地说，本发明的碳纳米管分散体包含（A）具有0.5〜50μm的D99的粒径分布的碳纳米管; （B）丁腈橡胶; 和（C）溶剂。根据本发明，提供了通过使用碳纳米管分散体制造的电子材料。

68. 发明授权

KR101447456B1 포스피네이트계 난연제의 제조방법 有权
标题翻译：制备磷酸盐阻燃剂的方法
公开(公告)号：KR101447456B1
公开(公告)日：2014-10-06
申请号：KR1020110144099
申请日：2011-12-28
申请人： 제일모직주식회사
发明人： 강용희 , 김만석 , 이은주 , 안성희 , 홍상현
IPC分类号： C09K21/12 , C07F9/46
CPC分类号： C09K21/12 , C07F9/657172
摘要： (메타)아크릴산 무수물 및 하기 화학식 1로 표시되는 포스피네이트계 알코올을 0-100℃에서 전환율이 85 ~ 100 %가 될 때까지 2 내지 12시간 동안 에스테르 반응되는 것을 특징으로 하는 하기 화학식 2로 표시되는 포스피네이트계 난연제의 제조 방법을 제공한다. 본 발명의 포스피네이트계 난연제 제조방법은 합성수율이 우수하고, 상기 제조방법으로 제조된 포스피네이트계 난연제는 순도 및 착색성이 우수하다.
[화학식 1]

(상기 화학식 1에서 R1은 C1-C4의 포화 또는 불포화 탄화수소기임.)
[화학식 2]

(상기 화학식 2에서 R1은 C1-C4의 포화 또는 불포화 탄화수소기이고, R2는 H 또는 메틸기임.)

69. 发明公开

KR1020140077577A 열가소성 수지 조성물 및 이로부터 형성된 성형품 有权
标题翻译：热塑性树脂组合物及其生产的物品
公开(公告)号：KR1020140077577A
公开(公告)日：2014-06-24
申请号：KR1020120146542
申请日：2012-12-14
申请人： 제일모직주식회사
发明人： 이재원 , 박동민 , 최동길 , 배수학 , 신승식 , 안성희
IPC分类号： C08L51/04 , C08L25/12 , C08L67/04 , C08J9/04
CPC分类号： C08L51/04 , C08J9/04 , C08L25/12 , C08L67/04
摘要： According to the present invention, a thermoplastic resin composition comprises: (A) a rubber-modified vinyl-based graft copolymer; (B) a vinyl cyanide-aromatic vinyl-based copolymer; and (C) an α-methylene-γ-butyrolactone (MBL)-vinyl-based copolymer. The thermoplastic resin composition has excellent chemical resistance, thereby preventing chemical corrosion by a foaming agent.
摘要翻译：根据本发明，热塑性树脂组合物包含：（A）橡胶改性的乙烯基类接枝共聚物; （B）乙烯基氰 - 芳族乙烯基类共聚物; 和（C）α-亚甲基-γ-丁内酯（MBL） - 乙烯基类共聚物。热塑性树脂组合物具有优异的耐化学性，从而防止发泡剂的化学腐蚀。

70. 发明公开

KR1020130139733A 당알코올 이무수물을 포함하는 미가공 반응생성물 및 이의 제조방법 无效
标题翻译：含有DIANHYDRO糖酒精的原料反应产物及其制备方法
公开(公告)号：KR1020130139733A
公开(公告)日：2013-12-23
申请号：KR1020120130383
申请日：2012-11-16
申请人： 제일모직주식회사
发明人： 김만석 , 김선대 , 안성희 , 홍상현
IPC分类号： C07D493/04 , C07C31/26 , C07C29/80 , C07H3/00
摘要： The present invention relates to a crude reaction product comprising: (A) 90 to 100 wt% of dianhydro sugar as a solid; and (B) 0 to 10 wt% of a reaction byproduct as a solid. The crude reaction product is prepared by comprising the steps of: (a) preparing monoanhydro sugar alcohol by a reaction of sugar alcohol with a primary cyclization catalyst; and (b) preparing dianhydro sugar by a reaction of the monoanhydro sugar alcohol with a secondary cyclization catalyst. [Reference numerals] (AA) Existing synthesis path;(BB) Direct conversion reaction (catalyst = sulfuric acid);(CC) [first cyclization]: 1.4-sorbitan main production reaction;(DD) heterogenous (zeolite based) catalyst utilization in the existing patent;(EE) [Secondary cyclization]: isosorbide production reaction : heterogeneous catalyst utilization;(FF) Excess production of carbonized material;(GG) 80% (existing synthesis level);(HH) Existing homogeneous catalyst utilization reaction level: a large ratio of Xylitol production
摘要翻译：本发明涉及粗反应产物，其包含：（A）90至100重量％的作为固体的二氢糖; 和（B）0〜10重量％的作为固体的反应副产物。通过包括以下步骤制备粗反应产物：（a）通过糖醇与初级环化催化剂的反应制备单糖醇; 和（b）通过单酐糖醇与二级环化催化剂的反应制备二氢糖。（AA）现有合成路径（BB）直接转化反应（催化剂=硫酸）;（CC）[第一次环化]：1.4-脱水山梨醇主要生产反应;（DD）异质（沸石基）催化剂的利用现有专利;（EE）[二次环化]：异山梨醇生产反应：非均相催化剂利用;（FF）碳化材料过量生产;（GG）80％（现有合成含量）;（HH）现有均相催化剂利用反应水平：木糖醇生产比例很大

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