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61. 发明公开

EP1036786A1 Rosin amine anti-fouling agents 审中-公开
标题翻译： Colophane Amine Derivate und ihre Anwendung als GegenmittelfürKesselstein
公开(公告)号：EP1036786A1
公开(公告)日：2000-09-20
申请号：EP99105349.7
申请日：1999-03-16
申请人： Bayer Aktiengesellschaft , UNIVERSITE LIBRE DE BRUXELLES , Nederlandse Organisatie voor toegepast natuurwetenschappelijk onderzoek , SIGMA COATINGS B.V.
发明人： Kunisch, Franz, Dr. , Kugler, Martin, Dr. , Braekman, Jean-Claude, Prof. Dr. , Plehiers, Mark, Dr. , Ferrari, Gabriele M., Dr. , Vos, Marcel, Dr.
IPC分类号： C07C233/02 , C09D5/16 , C07C331/24 , C07C265/08
CPC分类号： A01N37/34 , A01N37/18 , A01N47/40 , A01N47/44 , A01N47/46 , C07C233/02 , C07C265/08 , C07C331/24 , C07C2603/26 , C09D5/1625
摘要： The invention relates to new and known compounds as well as methods for preventing the attachment of aquatic organisms to surfaces which are submerged for extensive periods of time in water. More particularly, this invention relates to the protection of submerged surfaces with new isonitrile, formamide, isocyanate and isothiocyanate anti-fouling agents.
摘要翻译：本发明涉及新的和已知的化合物以及用于防止水生生物附着到在水中浸没大量时间的表面的方法。更具体地说，本发明涉及用新的异腈，甲酰胺，异氰酸酯和异硫氰酸酯防污剂保护浸没表面。

62. 发明公开

EP0927230A1 LIGHT- AND BRIGHT-COLOURED ANTIFOULING PAINTS 失效
标题翻译：浅色和高翊防污PAINTINGS
公开(公告)号：EP0927230A1
公开(公告)日：1999-07-07
申请号：EP97943871.0
申请日：1997-09-19
申请人： SIGMA COATINGS B.V.
发明人： KRAMER, Johannes, Petrus , VOS, Marcel
IPC分类号： A01N43 , C09D5 , C09D201
CPC分类号： C09D5/1625 , A01N43/36 , A01N2300/00
摘要： 2-Trihalogenomethyl-3-halogeno-4-cyano pyrrole derivatives which are substituted in position 5 and optionally in position 1 are used as barnaclecide in antifouling paints, which can therefore be formulated as light- or bright-coloured, particularly as bright white. The halogens in positions 2 and 3 are independently selected from the group consisting of fluorine, chlorine and bromine, preferably fluorine in position 2 and bromine in position 3. The substituent in position 5 is selected from the group consisting of C1-8 alkyl, C1-8 monohalogenoalkyl, C5-6 cycloalkyl, C5-6 monohalogenocycloalkyl, benzyl, phenyl, mono- and di-halogeno-benzyl or -phenyl, mono- and di-C1-4 alkyl benzyl or phenyl, and monohalogeno mono-C1-4-alkyl benzyl or phenyl, the halogen being selected from the group consisting of chlorine and bromine, preferably chlorine; the most preferred substituent in position 5 is para-chlorophenyl. The optional substituent in position 1 is selected from the group consisting of C1-4 alkyl and C1-4 alkoxy C1-4 alkyl; it is preferred that no substituent be present in position 1. The most preferred compound for use as barnaclecide in the invention is 2-trifluoromethyl-3-bromo-4-cyano-5-parachlorophenyl pyrrole. Antifouling paints may contain 0.5 to 9.9 wt.% of barnaclecide, based on the total weight of the dry mass of the composition, preferably 1 to 6 wt.%, most preferably 1.5 to 4 wt.%.

63. 发明公开

EP0751067A1 Machine de remplissage automatique de sacs à valve 失效
标题翻译： Automatische Ventilsack-Füllmaschine
公开(公告)号：EP0751067A1
公开(公告)日：1997-01-02
申请号：EP96110585.5
申请日：1996-07-01
申请人： SIGMA COATINGS B.V.
发明人： Weck, Hans Herman Marinus Coenraad
IPC分类号： B65B1/00 , B65B3/17 , B65B43/26
CPC分类号： B65B3/17
摘要： L'invention concerne une machine de remplissage automatique de sacs à valve en matière plastique avec des liquides.
La machine comprend essentiellement des moyens de soutien 2 sur lesquels reposent les sacs 1 dans le lieu de stockage, des moyens d'enlèvement 4 pour tirer un par un vers le bas les sacs 1 entre les moyens de support 2, ces moyens 4 comprenant un ou plusieurs moyens 4' fermement attachés à un support 5 qui peut bouger verticalement et placés au milieu des moyens de support 2, et d'autres moyens d'enlèvement 4'' attachés au support 5 de manière mobile, de part et d'autre sur ses côtés, de manière à suivre la déformation des sacs 1 lorsqu'ils sont tirés un par un vers le bas par les moyens d'enlèvement 4, des moyens 8 et 11 pour aligner les sacs 1 dans une position précise, des moyens d'enlèvement 13 pour agripper les sacs 1 un par un par le fond du côté de la valve, des moyens de pression 16 pour faire perdre aux sacs 1 la mémoire de leur forme pliée, des moyens d'ouverture 15 afin d'ouvrir la valve 20 et de la maintenir ouverte, des moyens de remplissage 21 pour remplir les sacs 1 par la valve 20, des moyens (22, 23, 24, 25) définissant un volume parallélipédique comportant les ouvertures permanentes ou temporaires appropriées pour reprendre les sacs pleins et les délivrer dans une orientation constante en vue des opérations d'emballage et des moyens pour transporter les sacs 1 entre les manipulations successives.
摘要翻译：用于自动填充折叠塑料袋（1）的机器，具有液体散装产品，具有用于保持堆叠和折叠的袋（1）的支撑件（2）。行进机构来回移动，在支撑件（5）处具有一个或多个夹具（4'），该支撑件可垂直移动以便在袋支撑件（2）水平定位。支撑架上的其他单元（4“）在侧面移动，以便在来回移动时扭曲袋子（1）。袋子（1）被精确地定位，并且握住袋子（1）以及把手通过阀门的底部，并施加压力以去除袋子材料中的任何折叠的记忆，阀被打开并保持打开，用于将液体送入袋中，填充的袋体积由永久或临时的每个袋子中的通气量不变，系统在处理阶段之间运送袋子，袋子（1）是低密度聚乙烯，支撑板上的流化聚合物的表面涂层或气垫帮助袋子动作。

64. 发明授权

EP2287261B1 Method of Preparing an Aqueous Oligomeric or Polymeric Compound 有权
公开(公告)号：EP2287261B1
公开(公告)日：2020-09-02
申请号：EP10181971.2
申请日：2006-01-25
申请人： SIGMA COATINGS B.V.
发明人： Plehiers, Mark , Van Loon, Sander
IPC分类号： C09D183/08 , C08L83/08 , C09D4/00 , C09D5/08

65. 发明授权

EP1427736B1 PROCESS FOR THE PREPARATION OF ORGANOSILYLATED CARBOXYLATE MONOMERS, AND THEIR USE IN ANTIFOULING COATINGS 有权
标题翻译：用于生产ORGANOSILYLKARBOXYLATMONOMEREN，以及它们作为防污列车
公开(公告)号：EP1427736B1
公开(公告)日：2006-11-15
申请号：EP02777159.1
申请日：2002-09-19
申请人： SIGMA COATINGS B.V.
发明人： PLEHIERS, Mark , VOS, Marcel , GILLARD, Michel
IPC分类号： C07F7/18 , C09D5/16 , C08F4/42
CPC分类号： C07F7/1896
摘要： Process for the preparation of organosilylated carboxylate monomers comprising the step of reacting an acyloxysilane with an unsaturated carboxylic acid, the monomers and their use as comonomer unit in the binder of antifouling coating compositions.

66. 发明公开

EP1423443A1 BINDERS WITH LOW CONTENT IN HYDROLYSABLE MONOMER SUITABLE FOR SELF-POLISHING ANTIFOULING PAINTS 审中-公开
标题翻译：有适合于自抛光END防污涂料含量低水解的单体粘结剂
公开(公告)号：EP1423443A1
公开(公告)日：2004-06-02
申请号：EP02769979.2
申请日：2002-08-22
申请人： SIGMA COATINGS B.V.
发明人： GILLARD, Michel , VOS, Marcel
IPC分类号： C08F220/12 , C09D5/16
CPC分类号： C08F220/12
摘要： Film-forming polymer prepared by polymerisation of: 5 - from more than 0 up to 4 mol% of at least one ethylenically unsaturated monomer unit A selected from the carboxylic acid and sulfonic acid derivatives that can yield an acid function upon hydrolysis in water; 10 - from 5 to 45 mol% of at least one monomer unit B selected from the group consisting of the N-vinyl lactam monomers of general formula CH2=CH-N-CO-R'J , the N-vinyl amides of general formula CH2=CH-NR-CO-15 R', the monomers of general formula CH2=CR''-C00-R''N-CO-R'I, the monomers of general formula CH2=CR''C00-R''-NR'''-CO-R', 2-pyrrolidone-l-isoprenyl ketone, and mixtures thereof, wherein - R is H or selected from the group consisting 20 of alkyl, - R' is a n-alkylidene radical having 2 to 8 carbon atoms, - R' is selected from the group consisting of alkyl, cycloalkyl, aryl, alkylaryl and arylalkyl 25 radicals having a maximum of 18 carbon atoms, - R'' is H or CH3, - R'' is a n-alkylidene radical having from 1 to 8 carbon atoms, - R''' is H or R' 30 and the balance of the monomer units being monomer units C selected from the group consisting of the esters of ethylenically unsaturated carboxylic acids with C1-C18 alcohols, styrene, alpha-methyl styrene, vinyl toluenes, and mixtures thereof.

67. 发明公开

EP1389214A1 PROCESS FOR THE PREPARATION OF TRIALKYLSILYLATED CARBOXYLATE MONOMERS, THE OBTAINED TRIALKYLSILYLATED CARBOXYLATE MONOMERS AND THEIR USE IN ANTI-FOULING COATINGS 审中-公开
标题翻译：用于生产TRIALKYLSILYLIERTEN羧酸酯单体，将如此获得的TRIALKYLSILYLIERTEN羧酸酯单体和它们在防污涂料
公开(公告)号：EP1389214A1
公开(公告)日：2004-02-18
申请号：EP02743061.0
申请日：2002-05-17
申请人： SIGMA COATINGS B.V.
发明人： PLEHIERS, Mark , GILLARD, Michel
IPC分类号： C07F7/08 , C07F7/18 , C09D5/16 , C08F4/42
CPC分类号： C07F7/188 , C07F7/0834
摘要： The invention relates to a process for the preparation of trialkylsilylated carboxylate monomers of general formula (I), which process comprises the step of reacting a hexaalkyldisilylsulfate of the formula (IV), with an unsaturated carboxylic compound of formula (III), and the obtained compounds. The invention further relates to a process for the preparation of a hexaalkyldisilylsulfate of the formula (IV) by treating a hexaalkyldisiloxane of formula (II), with fuming sulfuric acid, and the obtained compounds. The invention further relates to the use of said compound (I) in the preparation of a hydrolysable polymer.

68. 发明公开

EP1314716A1 Amine phenolic compounds and their use as hardener and/or accelerators in epoxy coatings 审中-公开
标题翻译：胺取代的苯酚衍生物和它们作为在环氧树脂涂料的固化剂或促进剂的使用
公开(公告)号：EP1314716A1
公开(公告)日：2003-05-28
申请号：EP01204522.5
申请日：2001-11-23
申请人： SIGMA COATINGS B.V.
发明人： Mill, Sibel , Gerritsen, Roy , De Vries, Gerard
IPC分类号： C07C215/48 , C07C215/52 , C07C229/36 , C08G59/62
CPC分类号： C07C215/52 , C07C229/36 , C08G59/623 , C09D163/00
摘要： The invention relates to new having the formula HO-C 6 H 5-n -(XN(Y 1 N(R 1 )R 2 )Y 2 N(R 3 )R 4 ) n wherein n is an integer chosen from 1 to 3; X, Y 1 , Y 2 represent each independently a bivalent radical and R 1 , R 2 , R 3 and R 4 represent each independently a hydrogen, alkyl or aminoalkyl in which at least one of R 1 , R 2 , R 3 ,R 4 or Y 1 N(R 1 )R 2 represent hydrogen. A method for the preparation of the new compounds is described, which comprises reacting an aminophenolic compound with a suitable reagent and reducing the intermediate.
摘要翻译：本发明涉及新的具有式HO-C6H5-N（XN（Y <1> N（R <1>）R <2>）Y <2> N（R <3>）R <4>）N worin n是从1到3的整数; X，Y <1>，Y <2>分别独立地表示二价基团且R <1>，R <2>，R <3>和R <4>表示，其中至少各自独立地为氢，烷基或氨基烷基 R的一<1>，R <2>，R <3>，R <4>或Y <1> N（R <1>）R氢<2>表示。描述了一种新化合物的制备方法，该方法包括使对氨基酚与合适的试剂化合物和减少了中间。

69. 发明公开

EP1288234A1 Binders with low content in hydrolysable monomer suitable for selfpolishing antifouling paints 审中-公开
标题翻译：粘合剂具有可水解的单体的含量低，适用于自抛光防污涂料
公开(公告)号：EP1288234A1
公开(公告)日：2003-03-05
申请号：EP01203208.2
申请日：2001-08-27
申请人： SIGMA COATINGS B.V.
发明人： Gillard, Michel , Vos, Marcel
IPC分类号： C08F220/12 , C09D5/16
CPC分类号： C08F220/12
摘要： Film-forming polymer prepared by polymerisation of:

from more than 0 up to 4 mol% of at least one ethylenically unsaturated monomer unit A selected from the carboxylic acid and sulfonic acid derivatives that can yield an acid function upon hydrolysis in water;
from 5 to 45 mol% of at least one monomer unit B selected from the group consisting of the N-vinyl lactam monomers of general formula CH2=CH- N-CO-R' | , the N-vinyl amides of general formula CH2=CH-NR-CO-R", the monomers of general formula CH2=CR"'-COO-R""- N-CO-R' |, the monomers of general formula CH2=CR"'-COO-R""-NR""'-CO-R", 2-pyrrolidone-1-isoprenyl ketone, and mixtures thereof, wherein

R is H or selected from the group consisting of alkyl,
R' is a n-alkylidene radical having 2 to 8 carbon atoms,
R" is selected from the group consisting of alkyl, cycloalkyl, aryl, alkylaryl and arylalkyl radicals having a maximum of 18 carbon atoms,
R"' is H or CH3,
R"" is a n-alkylidene radical having from 1 to 8 carbon atoms,
R""' is H or R",
and
the balance of the monomer units being monomer units C selected from the group consisting of the esters of ethylenically unsaturated carboxylic acids with C1-C18 alcohols, styrene, alpha-methyl styrene, vinyl toluenes, and mixtures thereof.
摘要翻译：通过聚合制备的成膜聚合物：从大于0到4摩尔％由羧酸和磺酸衍生物中的至少一种烯属不饱和单体单元A的那样可以在水中后的水解酸功能得到; 为5〜45摩尔％的选自通式CH 2 = CH-N-CO-R的N-乙烯基内酰胺单体的选择了”至少一种单体单元B的，通式CH 2 = CH的N-乙烯基酰胺 - NR-CO-R “的通式CH 2 = CR单体” ' - COO-R “” - N的-CO-R'，通式CH 2 = CR的单体 ““ - COO-R”“ - NR “”“-CO-R”，2-吡咯烷酮-1-异戊二烯酮，以及它们的混合物，worin R是H或选自选自烷基中选择，R”是正亚烷基具有2-8个碳原子， R“是选自烷基，环烷基，芳基，烷基芳基的选择和芳烷基具有最多18个碳原子，R的自由基”“是H或CH 3，R‘’是正亚烷基具有1至8个碳原子，R“”“为H或R”，和单体单元是单体单元C的选自烯属不饱和羧酸与C1-C18醇，苯乙烯，α-甲基苯乙烯，乙烯基酯的选择的平衡甲苯和它们的混合物。

70. 发明公开

EP1151047A1 PIGMENT CONCENTRATE 审中-公开
标题翻译： PIGMENTKONZENTRATE
公开(公告)号：EP1151047A1
公开(公告)日：2001-11-07
申请号：EP00904941.2
申请日：2000-01-21
申请人： SIGMA COATINGS B.V.
发明人： COUPERUS, Anja , GROENMAN, Tjerk , CARLIER, Stéphane
IPC分类号： C09D167/00 , C09B67/20 , C09D5/03 , C08J3/22
CPC分类号： C08J3/226 , C08J2467/00 , C09B67/0063 , C09D5/035 , C09D17/001 , C09D167/00 , C08L67/02 , C08L2666/70
摘要： Method for preparing a pigment concentrate which is suitable, in particular, for the preparation of a powder coating. The pigment concentrate is prepared by pigment particles being comminuted in the presence of an aqueous binder essentially consisting of a polyester having a glass transition temperature of at least 60 °C and an acid value of at least 60, to form a stable paste or suspension, the said paste or suspension formed being subjected to a drying treatment, and the pigment concentrate being collected. The binder used is preferably free of cosolvent, while expediently it is a resin having an acid value of at least 70. Preferably, no dispersant is used. By using a pigment concentrate formed according to the present method, a powder coating can be formed which no longer has a tinting strength reserve.
摘要翻译：制备颜料浓缩物的方法，其特别适用于制备粉末涂料。颜料浓缩物是通过将颜料颗粒在基本上由玻璃化转变温度至少为60℃，酸值至少为60的聚酯组成的水性粘合剂存在下粉碎来制备的，以形成稳定的糊剂或悬浮液，所形成的糊状物或悬浮液进行干燥处理，并收集颜料浓缩物。所使用的粘合剂优选不含共溶剂，有利的是其酸值至少为70℃的树脂。优选不使用分散剂。通过使用根据本方法形成的颜料浓缩物，可以形成不再具有着色强度储备的粉末涂料。

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