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    • 66. 发明专利
    • PRODUCTION OF POLYMER EMULSION
    • JPH08113602A
    • 1996-05-07
    • JP25111194
    • 1994-10-18
    • NIPPON NYUKAZAI CO LTD
    • OU CHIYUUKENTOMITA HIROYUKIISHII TAKASHI
    • C08F2/26
    • PURPOSE: To produce a polymer emulsion having low-foaming properties and excellent polymerization stability by using a specified anionic surfactant in emulsion-polymerizing an unsaturated monomer. CONSTITUTION: An anionic surfactant represented by the formula (wherein R1 is H or methyl; R2 is a 1-4C alkyl; A is a 2-4C alkylenel; (l) is 1-3; (m) is 1-100; M is a monovalent or bivalent cation; and (n) is 1 or 2) is used in emulsion-polymerizing an unsaturated monomer. The compound represented by the formula can be obtained by effecting the addition reaction of a starting material which is a styrenized alkylphenol derivative obtained by reacting a phenol compound having 1-4C substituents with styrene or methylstyrene according to the usual method in the presence of a catalyst such as caustic soda or caustic potash with an alkylene oxide and reacting the adduct with a sulfating agent to form a sulfuric ester. When the degree of sulfation is 60% or above, the desired result can be attained.