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51. 发明专利

JPS6328053B2 失效
公开(公告)号：JPS6328053B2
公开(公告)日：1988-06-07
申请号：JP4976180
申请日：1980-04-15
申请人： SUMITOMO CHEMICAL CO
发明人： MINAMII MASAYOSHI
IPC分类号： C07C43/23 , B01J31/00 , B01J31/02 , B01J31/06 , C07C27/00 , C07C29/143 , C07C37/56 , C07C39/08 , C07C39/15 , C07C41/00 , C07C41/26 , C07C43/295 , C07C67/00 , C07C213/00 , C07C215/78

52. 发明专利

JPS5929626A Method for recovering active component in catalyst for preparing phenol 失效
标题翻译：用于回收催化剂中活性成分制备酚的方法
公开(公告)号：JPS5929626A
公开(公告)日：1984-02-16
申请号：JP14059182
申请日：1982-08-12
申请人： Mitsubishi Chem Ind Ltd
发明人： MAKI TAKAO , MASUYAMA TETSUO , YOKOYAMA TOSHIHARU
IPC分类号： C07C37/56 , B01J23/00 , B01J23/72 , B01J38/00 , C07B61/00 , C07C27/00 , C07C37/50 , C07C39/04 , C07C67/00
CPC分类号： Y02P20/52 , Y02P20/584
摘要： PURPOSE: To recover advantageously components in a catalyst containing a specific rare earth compound in decarbonating a benzenemonocarboxylic acid in the liquid phase oxidatively in the presence of the catalyst containing the specific rare earth compound to prepare a phenol, by bringing the reaction product after separating the above-mentioned phenolic compound into contact with water.
CONSTITUTION: In decarbonating a benzenemonocarboxylic acid, a salt, ester or anhydride thereof in the liquid phase in the presence of a catalyst consisting of a copper compound, a manganese compound and a rare earth compound to prepare a phenol, the resultant reaction product after separating the above-mentioned phenolic compound is (A) dissolved in a water-insoluble organic solvent capable of dissolving tarry components, e.g. toluene, and then brought into contact with a small amount of water to precipitate and recover the above-mentioned components in the catalyst, preferably the rare earth compound, as a hydrate, or (B) brought into contact with a large amount of water without using the organic solvent to extract the components other than the tar into the aqueous layer. The tarry components are separated and removed from the reaction product by either one of the above-mentioned methods to recover advantageously the components in the catalyst, preferably the expensive rare earth compound.
COPYRIGHT: (C)1984,JPO&Japio
摘要翻译：目的：在含有特定的稀土类化合物的催化剂中，在含有特定稀土类化合物的催化剂存在下，在液相中氧化苯甲酸中的组分，有利地回收组分，制备苯酚，通过使分离后的反应产物上述酚类化合物与水接触。构成：在由铜化合物，锰化合物和稀土化合物组成的催化剂存在下，在液相中将苯三羧酸，其盐，酯或酸酐脱碳以制备苯酚，分离后得到的反应产物上述酚类化合物是（A）溶于能溶解焦油成分的水不溶性有机溶剂中，甲苯，然后与少量的水接触以沉淀并回收催化剂中的上述组分，优选稀土化合物作为水合物，或（B）与大量的水接触而没有使用有机溶剂将除焦油之外的组分萃取到水层中。通过上述任一种方法将焦油组分从反应产物中分离并除去，以有利地回收催化剂中的组分，优选昂贵的稀土化合物。

53. 发明专利

JPS5843933A PREPARATION OF P-CRESOL 失效
公开(公告)号：JPS5843933A
公开(公告)日：1983-03-14
申请号：JP14137881
申请日：1981-09-08
申请人： MITSUBISHI GAS CHEMICAL CO
发明人： SUZUKI TAKASHI , HASHIMOTO SHIYOUICHIROU , ORISAKU MASAMI , NAKANO RIAKO
IPC分类号： C07C27/00 , C07C37/56 , C07C39/07 , C07C67/00
摘要： PURPOSE:To obtain the titled compound useful as plastic raw materials, etc. from raw materials at a generally stabilized reaction rate, by specifying the moisture concentration in formic acid solvent and reaction temperature in oxidizing p-tolualdehyde with a peroxide in the formic acid solvent. CONSTITUTION:p-Tolualdehyde of formulaIis oxidized with a peroxide, e.g. performic acid of formula II or hydrogen peroxide of formula III, in formic acid solvent with 3-15wt% moisture concentration based on the formic acid, at 50-150 deg.C to give p-cresol of formula IV useful as industrial raw materials or intermediates for medicines, agricultural chemicals, etc. industrially and advantageously. The p-tolualdehyde may contain the o- or m-isomer, and preferably synthesized by the oxidation of p-xylene or carbonylating reaction of toluene. In this case, the p-cresol having the retained purity of the raw material isomer is obtained.

54. 发明专利

JPS5625126A PREPARATION OF PHENOLS 失效
公开(公告)号：JPS5625126A
公开(公告)日：1981-03-10
申请号：JP10003479
申请日：1979-08-06
申请人： MITSUBISHI CHEM IND
发明人： KAGEYAMA YOUICHI , MASUYAMA TETSUO , YOKOYAMA TOSHIHARU
IPC分类号： C07C37/56 , B01J27/00 , B01J27/02 , C07B61/00 , C07C27/00 , C07C67/00
摘要： PURPOSE:To obtain phenols in high yield, inhibiting the formation of by-products, by the gas-phase oxidation of aromatic carboxylic acids with molecular oxygen in the presence of a highlt active, long-life catalyst containing, Cu, Cr, Ba, Te and oxygen atom. CONSTITUTION:A phenol is obtained by the gas-phase oxidation of an aromatic carboxylic acid (e.g. benzoic acid, methyl benzoic acid, etc.) with molecular oxygen, using a catalyst containing Cu, Cr, Ba, Te and oxygen atom as essential components. The atomic ratio of Cu, Cr, Ba and Te and Te in the catalyst is 1: (5-0.5):(2-0.1):(1-0.01), and these components should be homogeneously mixed and integrated. The activity of the catalyst can be increased by calcination with O2-containing gas at 400-600 deg.C for 1-24hr after the preparation. EFFECT:The above catalyst has an excellent heat-resistance and reduction-resistance and gives only a small amount of carbon deposition.

55. 发明专利

JP2017101020A 高純度フェノール化合物の製造方法审中-公开
公开(公告)号：JP2017101020A
公开(公告)日：2017-06-08
申请号：JP2016223028
申请日：2016-11-16
申请人：宇部興産株式会社
发明人：木村恵輔 , 大森潔 , 改田鈴枝 , 西村浩輔
IPC分类号： C07C37/70 , C07C39/14 , C07D317/54 , C07D317/64 , C07C37/56
摘要：【課題】高純度フェノール化合物の製造方法。【解決手段】芳香族メチルアルコール式(1)と過酸化物を反応させる芳香族アルデヒド式(2)を製造する工程1、酸触媒存在下で式(2)を過酸化物と反応させるフェノール式(3)を製造する工程2、並びに式(3)を精製する高純度フェノールの製造方法。【選択図】なし

56. 发明专利

JP5778755B2 ヒドロキノンの製造方法有权
标题翻译：用于生产氢醌法
公开(公告)号：JP5778755B2
公开(公告)日：2015-09-16
申请号：JP2013504147
申请日：2011-03-17
申请人：メルクパテントゲゼルシャフトミットベシュレンクテルハフツング , Merck Patent Gesellschaft mit beschraenkter Haftung
发明人：カダム,シャフラジュ,ハナマントゥラオ , パクニカール,シャシクマール
IPC分类号： C07C39/08 , C07C37/56
CPC分类号： C07C37/01 , C07C37/56 , C07C45/69 , C07C47/565

57. 发明专利

JP2014098019A METHOD FOR PRODUCING β-SANTALOL AND DERIVATIVE THEREOF 有权
标题翻译：生产方法及其衍生物及其衍生物
公开(公告)号：JP2014098019A
公开(公告)日：2014-05-29
申请号：JP2014020303
申请日：2014-02-05
申请人： Firmenich Sa , フイルメニツヒソシエテアノニムFirmenich Sa
发明人： FEHR CHARLES , MAGALI VUAGNOUX
IPC分类号： C07C33/05 , C07B61/00 , C07C29/00 , C07C37/20 , C07C37/56 , C07C45/67 , C07C47/225 , C07F7/08
CPC分类号： C07C33/14 , C07B2200/07 , C07C29/147 , C07C29/38 , C07C45/30 , C07C45/512 , C07C45/62 , C07C45/68 , C07C45/74 , C07C45/75 , C07C67/00 , C07C67/283 , C07C67/343 , C07C2602/42 , C07C47/225 , C07C49/433 , C07C49/653 , C07C69/007 , C07C69/608 , C07C69/145
摘要： PROBLEM TO BE SOLVED: To provide a more industrial method for producing β-santalol and a derivative thereof.SOLUTION: There is provided a method for producing a compound (I) which is a direct precursor of β-santalol, the method comprising the steps of: a) obtaining a compound of the formula (I-a) (wherein, Rrepresents a Si(R)or a (R)COH group (Rand Reach independently represents a Cgroup or a phenyl group) by reacting 2-R-3-methylene-bicyclo[2.2.1]heptane (wherein, R has the same meaning as the case of the compound (I)) with a compound of the formula: R-C≡CCHO [wherein, Rrepresents a Si(R)group or a (R)COH group (Rand Reach independently represents a Cgroup or a phenyl group] in the presence of Al, B or Sn derivative Lewis acid as a catalyst ("en" reaction); and b) obtaining the compound (I) by treating the resulting compound (I-a) with a proper base or a fluorine salt.
摘要翻译：要解决的问题：提供一种更加工业化的生产方法 - 檀香醇及其衍生物。方法：提供一种生产化合物（I）的方法，该化合物（I）是 - 檀香醇的直接前体，该方法包括步骤：a）获得式（Ia）化合物（其中，R 2表示Si（R）或（R）COH基团（Rand Reach独立地表示C基或苯基），通过使2-R-3 - 亚甲基 - 双环[2.2.1]庚烷（其中，R与化合物（I）的情况具有相同的含义）与下式的化合物：RC≡CCHO[其中R表示Si（R）基团或在Al，B或Sn衍生物路易斯酸作为催化剂（“en”反应））存在下，COH基团（Rand Reach独立地表示C基或苯基）; b）通过处理所得化合物（Ia）具有适当的碱或氟盐。

58. 发明专利

JP3221447B2 失效
公开(公告)号：JP3221447B2
公开(公告)日：2001-10-22
申请号：JP40826890
申请日：1990-12-27
IPC分类号： B01J23/78 , C07B61/00 , C07C37/56 , C07C39/04

59. 发明专利

JP2969960B2 失效
公开(公告)号：JP2969960B2
公开(公告)日：1999-11-02
申请号：JP40827090
申请日：1990-12-27
申请人： NIPPON KOKAN KK
发明人： MIKI ATSUSHI , SHIKADA TSUTOMU , TACHIBANA YAKUDO
IPC分类号： B01J23/74 , B01J23/78 , B01J23/86 , C07B61/00 , C07C37/50 , C07C37/56 , C07C39/04

60. 发明专利

JP2697441B2 失效
公开(公告)号：JP2697441B2
公开(公告)日：1998-01-14
申请号：JP34292991
申请日：1991-12-25
IPC分类号： B01J23/75 , B01J23/74 , B01J23/78 , C07B61/00 , C07C37/56 , C07C39/04

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