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    • 56. 发明授权
    • Fibers and fibrets from blends of polybezimidazoles and aromatic
polyamides, aromatic polyamide-hydrazides or aromatic polyamides
containing heterocyclic linkages
    • 来自聚苯并咪唑和芳族聚酰胺的共混物的纤维和纤维,芳族聚酰胺 - 酰肼或含有杂环键的芳族聚酰胺
    • US5250633A
    • 1993-10-05
    • US647392
    • 1991-01-29
    • Gordon W. CalundannEdward C. CheneveyTai-Shung Chung
    • Gordon W. CalundannEdward C. CheneveyTai-Shung Chung
    • C08L77/00C08L79/02C08L79/04D01D5/40D01F6/90C08L79/06C08L79/08
    • D01F6/905C08L77/00C08L79/02C08L79/04D01D5/40
    • Fibers and fibrets of a novel miscible blend of component polymers comprising from about 5 weight percent to about 95 weight percent of a polybenzimidazole and from about 95 weight percent to about 5 weight percent of an aromatic polyamide, aromatic polyamide-hydrazide or aromatic polyamide containing heterocyclic linkages. Miscibility of the component polymers of the blend is indicated by infrared, X-Ray and Differential Scanning Calorimetry analyses and electron photomicrographs. In fibers or fibrets of a blend mostly comprised of a polybenzimidazole, it is preferred that the aromatic polyamide, aromatic polyamide-hydrazide or aromatic polyamide containing heterocyclic linkages be present in the blend in an amount sufficient to yield a blend with improved tensile properties compared to the polybenzimidazole and more thermally processable than the polybenzimidazole. The fibers or fibrets of the blend have a lower moisture regain than polybenzimidazole fibers or fibrets. In fibers or fibrets of a blend mostly comprised of an aromatic polyamide, aromatic polyamide-hydrazide or aromatic polyamide containing heterocyclic linkages, it is preferred that the polybenzimidazole be present in the blend in an amount sufficient to yield a blend with increased thermal stability and nonflammability compared to the aromatic polyamide, aromatic polyamide-hydrazide or aromatic polyamide containing heterocyclic linkages. The fibers or fibrets may be post-treated with heat or sulfuric acid in order to minimize their shrinkage when they are subsequently subjected to heat and in order to increase their resistance to solvents and acid.
    • 包含约5重量%至约95重量%的聚苯并咪唑和约95重量%至约5重量%的芳族聚酰胺,芳族聚酰胺 - 酰肼或芳族聚酰胺含杂环的组分聚合物的新型可混溶共混物的纤维和纤维 联系。 通过红外,X射线和差示扫描量热法分析和电子显微照片表明共混物的组分聚合物的混溶性。 在主要由聚苯并咪唑组成的共混物的纤维或纤维中,优选芳香族聚酰胺,芳族聚酰胺 - 酰肼或芳族聚酰胺含杂环键以足以产生具有改进的拉伸性能的共混物的量存在于共混物中 聚苯并咪唑,并且比聚苯并咪唑更热可加工。 共混物的纤维或纤维层具有比聚苯并咪唑纤维或纤维的更低的回潮率。 在主要由芳族聚酰胺,芳族聚酰胺 - 酰肼或含有杂环键的芳族聚酰胺组成的共混物的纤维或纤维中,优选聚苯并咪唑以足以产生具有增加的热稳定性和不可燃性的共混物的量存在于共混物中 与芳族聚酰胺,芳族聚酰胺 - 酰肼或含有杂环键的芳族聚酰胺相比。 可以用热或硫酸对纤维或纤维素进行后处理,以便当它们随后经受热量时使其收缩最小化,以增加其对溶剂和酸的耐受性。