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    • 51. 发明授权
    • Color photographic recording material containing a non-diffusible dye
releaser from which a complexible azo dye is released during development
    • 包含非扩散性染料释放剂的彩色照相记录材料,在显影过程中从其中释放可络合的偶氮染料
    • US4461827A
    • 1984-07-24
    • US455319
    • 1983-01-03
    • Peter BergthallerGunther SchenkGerhard Wolfrum
    • Peter BergthallerGunther SchenkGerhard Wolfrum
    • C09B29/01C09B29/36C09B45/14G03C8/10G03C5/54G03C1/40G03C7/00
    • C09B29/36C09B29/0007C09B45/14G03C8/10
    • Metal complexes, particularly copper and nickel complexes, of azo dyes corresponding to formula suitable for use as magenta-colored image dyes for the production of colored images by the dye diffusion transfer process. The dyes are linked (in non-metallized form) to a carrier radical provided with a ballast group as so-called color-providing compounds which are associated with a photosensitive silver halide emulsion layer. During development, the metallizable dyes are released imagewise and, after diffusion into an image-receiving layer, are converted into the corresponding metal complexes. ##STR1## In formula II, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 represent H, F, Cl, Br, --CN, --NO.sub.2, --CF.sub.3, --OCH.sub.3, --SCF.sub.3, alkyl, alkoxy, alkylthio, acylamino, alkyl sulphonyl, aryl sulphonyl, --CO--X or --SO.sub.2 Y; or two adjacent radicals from the group of radicals R.sup.1 to R.sup.4 together represent a fused benzene ring;R.sup.5 represents H, alkyl, alkoxy, aryl, alkoxy carbonyl, carbamoyl or cyano,R.sup.6 and R.sup.7 represent H, halogen, alkyl, --CF.sub.3 or --SO.sub.2 --Y,G represents --OH or a hydrolyzable precursor thereof,X represents --OH, alkoxy or an amino group;Y represents H, --OH, an amino group or a group of the formula --NH--SO.sub.2 --R.sup.8 whereR.sup.8 represents alkyl, aryl or an amino group; andm=0 or 1.
    • 金属络合物,特别是铜和镍络合物,对应于适合用作品红色图像染料的式的偶氮染料,用于通过染料扩散转移方法生产彩色图像。 将染料以非金属化形式连接到具有镇流器基团的载体基团上,所述载体基团与感光卤化银乳剂层相关联的所谓的提供色彩的化合物。 在显影过程中,金属化染料被成像释放,并且在扩散到图像接收层中后,转化成相应的金属络合物。 式II中,R 1,R 2,R 3和R 4表示H,F,Cl,Br,-CN,-NO 2,-CF 3,-OCH 3,-SCF 3,烷基,烷氧基,烷硫基,酰氨基,烷基磺酰基, 芳基磺酰基,-CO-X或-SO 2 Y; 或者R 1〜R 4基团的两个相邻基团一起表示稠合苯环; R5代表H,烷基,烷氧基,芳基,烷氧基羰基,氨基甲酰基或氰基,R6和R7表示H,卤素,烷基,-CF3或-SO2-Y,G表示-OH或其可水解的前体,X表示-OH, 烷氧基或氨基; Y表示H,-OH,氨基或式-NH-SO 2 -R 8的基团,其中R 8表示烷基,芳基或氨基; m = 0或1。
    • 53. 发明授权
    • Azo dyes from a 5-aminopyrazole bearing 1 to 2 sulfated
hydroxyalkoxycarbonyl or N-(hydroxyalkyl) carbamoyl groups on its ring
    • 来自5-氨基吡唑的偶氮染料在其环上带有1至2个硫酸化羟基烷氧基羰基或N-(羟基烷基)氨基甲酰基
    • US4301070A
    • 1981-11-17
    • US100626
    • 1979-12-05
    • Ralph R. GilesMax A. Weaver
    • Ralph R. GilesMax A. Weaver
    • C09B29/00C09B29/36C09B62/51C09B29/036C09B29/09C09B29/32
    • C09B29/0037C09B29/36C09B62/51
    • This invention relates to azo dyes in which the diazotized amino component bears 1 or 2 sulfated hydroxyalkoxycarbonyl or N-(hydroxyalkyl)carbamoyl groups on its ring. These dyes have excellent dyeing properties on polyamide fibers and also impart color to cellulose acetate fibers and wool.The dyes correspond to the formula: ##STR1## wherein when n is 1, R.sup.1 is selected from hydrogen, alkyl, aryl, alkylthio, carbamoyl, alkylcarbamoyl, acyl, cyanoalkyl, and halogen; R is selected from hydrogen, alkyl, aryl, acyl, alkylsulfonyl, arylsulfonyl alkylsulfamoyl, arylsulfamoyl, alkyl substituted with alkoxy, cyano, or halogen, and aryl substituted with alkoxy, halogen, or cyano; X' is O, NH, N(alkyl)--or N(aryl)--; Z is selected from straight- or branched-chain alkylene which may be substituted, for example, with phenyl, halogen, OSO.sub.3 M, alkoxy, aryloxy and the like; M is H, Na, K or NH.sub.4 ; n is 1 or 2; and the coupler C is selected from a variety of couplers including anilines, tetrahydroquinolines, phenols and the like.
    • 本发明涉及偶氮染料,其中重氮化的氨基组分在其环上带有1或2个硫酸化羟基烷氧基羰基或N-(羟烷基)氨基甲酰基。 这些染料在聚酰胺纤维上具有优异的染色性能,并赋予醋酸纤维素纤维和羊毛颜色。 染料对应于下式:其中当n为1时,R 1选自氢,烷基,芳基,烷硫基,氨基甲酰基,烷基氨基甲酰基,酰基,氰基烷基和卤素; R选自氢,烷基,芳基,酰基,烷基磺酰基,芳基磺酰基烷基氨磺酰基,芳基氨磺酰基,被烷氧基,氰基或卤素取代的烷基,以及被烷氧基,卤素或氰基取代的芳基; X'是O,NH,N(烷基) - 或N(芳基) - ; Z选自可以被取代的直链或支链亚烷基,例如苯基,卤素,OSO 3 M,烷氧基,芳氧基等; M是H,Na,K或NH 4; n为1或2; 并且成色剂C选自包括苯胺,四氢喹啉,酚等的各种成色剂。
    • 54. 发明授权
    • Monoazo dyestuffs containing diazo component substituted by disulfimide
and trifluoromethyl groups
    • 含有被二硫代酰亚胺和三氟甲基取代的重氮组分的单偶氮染料
    • US4243584A
    • 1981-01-06
    • US919482
    • 1978-06-27
    • Richard SommerGerhard WolfrumGerhard Buttner
    • Richard SommerGerhard WolfrumGerhard Buttner
    • C09B29/01C09B29/08C09B29/36C09B29/38D06P3/26
    • C09B29/0801C09B29/08C09B29/36
    • Monoazo dyestuffs of the formula ##STR1## wherein R.sub.1 represents an aromatic radical, an aliphatic radical with 1-4 C atoms or a dialkylamino radical, in which the alkyl groups contain 1-C atoms, R.sub.2 represents hydrogen, halogen, alkyl with 1-C atoms, alkoxy with 1-4 C atoms or trifluoromethyl, R.sub.3 represents hydrogen, halogen, alkyl with 1-4 C atoms, alkoxy with 1-4 C atoms or trifluoromethyl and K represents the radical of a coupling component K-H of the formulae (II), (III) and (IV) ##STR2## wherein R.sub.4 represents alkyl with 1-4 C atoms or aryl,R.sub.5 represents hydrogen or unsubstituted alkyl with 1-4 C atoms,R.sub.6 represents hydrogen, nitrile, halogen, alkyl with 1-4 C atoms or alkoxy with 1-4 C atoms,R.sub.7 represents hydrogen, alkyl with 1-4 C atoms, aryl, a carboxylic acid ester group or a carboxylic acid amide group,R.sub.8 represents hydrogen, alkyl, cycloalkyl, aryl or the radical of a heterocyclic compound,R.sub.9 represents hydrogen, halogen, alkyl with 1-4 C atoms, alkoxy with 1-4 C atoms or acylamino,R.sub.10 represents hydrogen, halogen, alkyl with 1-4 C atoms, alkoxy with 1-4 C atoms or aryloxy,R.sub.11 represents hydrogen or alkyl,R.sub.12 represents hydrogen or alkyl and m represents 0 or 1,are suitable for the dyeing of synthetic fibre materials, especially those from polyamides. Level yellow, red and ruby shades are obtained with good dyeing yield and fastness.
    • 其中R 1表示芳族基团,具有1-4个碳原子的脂族基团或二烷基氨基,其中烷基含有1-C原子,R 2表示氢,卤素,具有1- C原子,具有1-4个C原子的烷氧基或三氟甲基,R 3表示氢,卤素,具有1-4个C原子的烷基,具有1-4个C原子的烷氧基或三氟甲基,K表示式(I)的偶合组分KH的基团 II),(III)和(IV)其中R 4表示具有1-4个C原子的烷基或芳基,R 5表示氢或具有1-4个C原子的未取代的烷基,R 6表示氢,腈,卤素,具有1个 -4个C原子或具有1-4个C原子的烷氧基,R7代表氢,具有1-4个C原子的烷基,芳基,羧酸酯基或羧酸酰胺基,R8代表氢,烷基,环烷基,芳基或 杂环化合物的基团,R 9表示氢,卤素,具有1-4个C原子的烷基,具有1-4个C原子的烷氧基或a 氨基,R 10表示氢,卤素,具有1-4个C原子的烷基,具有1-4个C原子的烷氧基或芳氧基,R 11表示氢或烷基,R 12表示氢或烷基,m表示0或1,适于染色 合成纤维材料,特别是聚酰胺。 获得具有良好的染色产率和坚牢度的黄色,红色和红宝石色调。