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    • 60. 发明授权
    • Fluorinated heterocycles and their use in liquid-crystal mixtures
    • US07026021B2
    • 2006-04-11
    • US10903937
    • 2004-07-30
    • Rainer WingenBarbara HornungWolfgang Schmidt
    • Rainer WingenBarbara HornungWolfgang Schmidt
    • C09K19/34C09K19/32C07D307/77C07D307/93C07C23/08
    • C07D307/93C09K2019/3408Y10T428/10
    • Compounds of the general formula (I) where: R1, R2 are each independently a) H b) -M1-A1-R5 c) a straight-chain or branched alkyl radical having from 1 to 16 carbon atoms or a straight-chain or branched alkenyl radical having from 2 to 16 carbon atoms, where c1) one or more nonadjacent and nonterminal CH2 groups may be replaced by —O—, —C(═O)O—, —O—C(═O)—, —O—C(═O)—O—, —C(═O)— or —Si(CH3)2—, and/or c2) one CH2 group may be replaced by —C≡C—, cyclopropane-1,2-diyl, cyclobutane-1,3-diyl, cyclohexane-1,4-diyl or phenylene-1,4-diyl, and/or c3) one or more hydrogen atoms may be replaced by F and/or Cl, p, q are each independently 0 or 1 G1-G2 is —CH2CH—, —CH═C—, —CH2CH2CH— or —CH═CH—CH— M1 is —CO—O—, —O—CO—, —CH2—O—, —O—CH2—, —CF2—O—, —O—CF2—, —CH═CH—, —CF═CF—, —C≡C—, —CH2—CH2—CO—O—, —O—CO—CH2—CH2—, —CH2—CH2—, —CF2—CF2—, —(CH2)4—, —OC(═O)CF═CF— or a single bond, A1 is 1,4-phenylene where one or two hydrogen atoms may be replaced by F, Cl, CN and/or OCF3, or up to three hydrogen atoms may be replaced by fluorine, 1,4-cyclohexylene where one or two hydrogen atoms may be replaced by CH3 and/or F, 1-cyclohexene-1,4-diyl, where one hydrogen atom may be replaced by CH3 or F, or 1,3-dioxane-2,5-diyl, R5 has the same possible definitions as R1 and R2, with the exception of -M1-A1-R5 with the provisos that: a) at least one of p, q is 1, b) R1 and R2 must not at the same time be H. are used in liquid-crystal mixtures.