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51. 发明授权

US4620945A Mixtures of one or more t-mercapto terpene isomers and .alpha.-terpineol, .beta.-phenylethyl alcohol, 3-methyl-1-phenyl-pentanol-5 and/or butanoyl cyclohexane derivatives, organoleptic uses thereof and process for preparing same 失效
标题翻译：一种或多种t-巯基萜烯异构体和α-萜品醇，β-苯乙醇，3-甲基-1-苯基 - 戊醇-5和/或丁酰基环己烷衍生物的混合物，其感官用途及其制备方法
公开(公告)号：US4620945A
公开(公告)日：1986-11-04
申请号：US644053
申请日：1984-08-24
申请人： Braja D. Mookherjee , Bernard J. Chant , William J. Evers , Richard A. Wilson , Michael J. Zampino , Manfred H. Vock
发明人： Braja D. Mookherjee , Bernard J. Chant , William J. Evers , Richard A. Wilson , Michael J. Zampino , Manfred H. Vock
IPC分类号： C07D331/02 , C11B9/00 , A61K7/46
CPC分类号： C07D331/02 , C11B9/0034
摘要： Described are organoleptic utilities of mixtures of t-mercapto terpene isomers defined according to the generic structure: ##STR1## wherein one of the dashed lines is a carbon-carbon double bond and the other of the dashed lines is a carbon-carbon single bond taken further together with .alpha.-terpineol having the structure: ##STR2## .beta.-phenylethyl alcohol having the structure: ##STR3## 3-methyl-1-phenyl-pentanol-5 having the structure: ##STR4## and/or butanoyl cyclohexane derivatives defined according to the generic structure: ##STR5## wherein one of the dashed lines is a carbon-carbon double bond or two of the dashed lines represent carbon-carbon double bonds but that when two of the dashed lines represent carbon-carbon double bonds, the carbon-carbon double bonds are conjugated.
摘要翻译：描述了根据通用结构定义的t-巯基萜烯异构体混合物的感官效用：其中一条虚线是碳 - 碳双键，另一条虚线是碳 - 碳单键取代进一步与具有以下结构的α-萜品醇结合：具有以下结构的具有以下结构的β-苯乙醇：具有以下结构的3-甲基-1-苯基 - 戊醇-5：具有以下结构的化合物：和/或丁酰基环己烷衍生物涉及通用结构：其中虚线中的一条为碳 - 碳双键，或两条虚线表示碳 - 碳双键，但当虚线中的两条代表碳 - 碳双键时，碳 - 碳双键共轭。

52. 发明授权

US4512902A Process for augmenting or enhancing aroma of consumable material by adding thereto 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]-oct-5-en-2-ol 失效
标题翻译：通过向其中添加可消耗材料的香气的方法，其中加入1,2,3,3,5,6-六甲基 - 双环[2.2.2] - 辛-5-烯-2-醇
公开(公告)号：US4512902A
公开(公告)日：1985-04-23
申请号：US536161
申请日：1983-09-26
申请人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
发明人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
IPC分类号： C07C29/40 , C07C35/31 , C07C45/62 , C07C45/67 , C07C45/69 , C11B9/00 , C11D3/50 , D06M13/20
CPC分类号： C11D3/50 , C07C29/40 , C07C35/31 , C07C45/62 , C07C45/673 , C07C45/69 , C11B9/0046
摘要： Described is 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol as a mixture of isomers and in its isomeric forms having the structures: ##STR1## and the uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles, and colognes.
摘要翻译：描述为1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇作为异构体的混合物，其异构体具有以下结构：和其用于增强或增强香料组合物，香料制品和古龙水的香气。

53. 发明授权

US4471135A 1,2,3,3,5,6-Hexamethyl-bicyclo[2.2.2]-oct-5-en-2-ol, process for producing same, intermediates useful in said process and organoleptic uses of same 失效
标题翻译： 1,2,3,3,5,6-六甲基 - 双环[2.2.2] - 辛-5-烯-2-醇，其制备方法，可用于所述方法的中间体和其相同的感官用途
公开(公告)号：US4471135A
公开(公告)日：1984-09-11
申请号：US535800
申请日：1983-09-26
申请人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
发明人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
IPC分类号： C07C29/40 , C07C35/31 , C07C45/62 , C07C45/67 , C07C45/69 , C11B9/00 , C11D3/50 , C07C67/02 , A61K7/46
CPC分类号： C11D3/50 , C07C29/40 , C07C35/31 , C07C45/62 , C07C45/673 , C07C45/69 , C11B9/0046 , C07C2102/44
摘要： Described is 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol as a mixture of isomers and in its isomeric forms having the structures: ##STR1## and the uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles, and colognes. Also described is a novel process for preparing 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol.
摘要翻译：描述为1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇作为异构体的混合物，其异构体具有以下结构：和其用于增强或增强香料组合物，香料制品和古龙水的香气。还描述了制备1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇的新方法。

54. 发明授权

US4138413A Process for preparing 2-acyl-5-substituted thiatetrahydrofuran-4-ones 失效
标题翻译： 2-酰基-5-取代的四氢呋喃-4-酮的制备方法
公开(公告)号：US4138413A
公开(公告)日：1979-02-06
申请号：US887631
申请日：1978-03-17
申请人： Braja D. Mookherjee , William J. Evers , Alfred E. Goossens
发明人： Braja D. Mookherjee , William J. Evers , Alfred E. Goossens
IPC分类号： A24B15/40 , C07D307/32 , C07D307/64 , C11B9/00
CPC分类号： C07D307/32 , A24B15/406 , C07D307/64 , C11B9/0076
摘要： Described are 2-acyl-5-substituted thiatetrahydrofuran-4-ones having the generic structure: ##STR1## wherein R.sub.1, R.sub.2, R.sub.1 ' and R.sub.2 ' are the same or different and each represents hydrogen or methyl and wherein R.sub.3 represents one of C.sub.1 -C.sub.9 alkyl, benzyl, phenyl, substituted or unsubstituted allyl having the structure: ##STR2## substituted or unsubstituted 3-furyl having the structure: ##STR3## (wherein R.sub.4 and R.sub.8 are the same or different and each represents hydrogen or methyl) hydroxy alkyl, oxoalkyl, hydroxycycloalkyl or oxocycloalkyl having the structure: ##STR4## (wherein R.sub.5 and R.sub.6, taken separately, represent hydrogen or C.sub.1 -C.sub.3 alkyl or R.sub.5 and R.sub.6, taken together, complete a cycloalkyl group and wherein Q is one of the moieties: ##STR5## prepared according to the process of dimerizing one or more alpha, beta-alkane dione(s) to form one or more alpha, beta-alkane dione dimer(s) having the structure: ##STR6## and reacting the said alkane dione dimer(s) in acidic medium and in the presence of a solvent with a mercaptan, having the structure:R.sub.3 SHthe 2-acyl-5-substituted thiatetrahydrofuran-4-ones of our invention have organoleptic properties which make them useful for augmenting or enhancing the aroma or flavor of foodstuffs, tobaccos and the aroma of perfumes and perfumed articles.
摘要翻译：描述了具有以下通用结构的2-酰基-5-取代的硫代四氢呋喃-4-酮：其中R 1，R 2，R 1'和R 2'相同或不同，各自表示氢或甲基，并且其中R 3表示C1 -C9烷基，苄基，苯基，具有以下结构的取代或未取代的烯丙基：具有以下结构的取代或未取代的3-呋喃基：其中R 4和R 8相同或不同，各自表示氢或甲基）羟基烷基，氧代烷基，羟基环烷基或氧代环烷基，其结构为：其中R 5和R 6分别代表氢或C 1 -C 3烷基或R 5和R 6一起形成环烷基，其中Q是部分之一：根据使一种或多种α，β-烷烃二酮二聚形成一种或多种具有以下结构的α，β-烷烃二酮二聚体的方法制备：＆lt; IMAGE＆gt;并使所述烷烃二酸二聚体在酸性介质中并在溶剂存在下进行具有硫醇，具有以下结构：

55. 发明授权

US4584128A Mixture of one or more t-mercapto terpene isomers and .alpha.-terpineol organoleptic uses thereof 失效
标题翻译：一种或多种t-巯基萜烯异构体和α-萜品醇感官用途的混合物
公开(公告)号：US4584128A
公开(公告)日：1986-04-22
申请号：US644117
申请日：1984-08-24
申请人： Braja D. Mookherjee , Bernard J. Chant , William J. Evers , Richard A. Wilson , Michael J. Zampino , Manfred H. Vock
发明人： Braja D. Mookherjee , Bernard J. Chant , William J. Evers , Richard A. Wilson , Michael J. Zampino , Manfred H. Vock
IPC分类号： C07D331/02 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0034 , C07D331/02
摘要： Described are mixtures of t-mercapto terpene isomers defined according to the generic structure: ##STR1## wherein one of the dashed lines is a carbon-carbon double bond and the other of the dashed lines is a carbon-carbon single bond taken further together with .alpha.-terpineol having the structure: ##STR2##
摘要翻译：描述了根据通用结构定义的t-巯基萜烯异构体的混合物：其中一条虚线是碳 - 碳双键，另一条虚线是碳 - 碳单键，进一步与具有以下结构的α-萜品醇：

56. 发明授权

US4549972A 1,2,3,3,5,6-Hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol, process for producing same, intermediates useful in said process and organoleptic uses of same 失效
标题翻译： 1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇，其制备方法，可用于所述方法的中间体和其相同的感官用途
公开(公告)号：US4549972A
公开(公告)日：1985-10-29
申请号：US671406
申请日：1984-11-14
申请人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
发明人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
IPC分类号： C07C29/40 , C07C35/31 , C07C45/62 , C07C45/67 , C07C45/69 , C11B9/00 , C11D3/50 , C07C35/22 , C11D9/44
CPC分类号： C11D3/50 , C07C29/40 , C07C35/31 , C07C45/62 , C07C45/673 , C07C45/69 , C11B9/0046 , C07C2102/44
摘要： Described is 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol as a mixture of isomers and in its isomeric forms having the structures: ##STR1## and the uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles, and colognes. Also described is a novel process for preparing 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol by first reacting the compound having the structure: ##STR2## with the compound having the structure: ##STR3## in order to produce the ketone defined according to the structure: ##STR4## which is hydrogenated to form the compound having the structure: ##STR5## and further hydrogenated to form the ketone having the structure: ##STR6## This ketone is reacted with CH.sub.3 M wherein M represents Li or MgX and wherein X is chloro, bromo or iodo to form the organometallic intermediate defined according to the structures: ##STR7## These compounds are then hydrolyzed with dilute acid to form the organoleptically useful 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol isomers of our invention defined according to the structures: ##STR8##
摘要翻译：描述为1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇作为异构体的混合物，其异构体具有以下结构：和其用于增强或增强香料组合物，香料制品和古龙水的香气。还描述了制备1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇的新方法，首先使具有以下结构的化合物：＆lt; IMAGE＆gt; 具有以下结构的化合物：为了制备根据以下结构定义的酮：将其氢化形成具有以下结构的化合物：进一步氢化以形成具有以下结构的酮：图像>该酮与CH 3 M反应，其中M表示Li或MgX，并且其中X是氯，溴或碘，以形成根据以下结构定义的有机金属中间体：然后将这些化合物用稀酸水解以形成感官有用的本发明的1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇异构体根据以下结构定义：

57. 发明授权

US4532359A 1,2,3,3,5,6-Hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol, process for producing same, intermediates useful in said process and organoleptic uses of same 失效
标题翻译： 1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇，其制备方法，可用于所述方法的中间体和其相同的感官用途
公开(公告)号：US4532359A
公开(公告)日：1985-07-30
申请号：US602570
申请日：1984-04-20
申请人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
发明人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
IPC分类号： C07C29/40 , C07C35/31 , C07C45/62 , C07C45/67 , C07C45/69 , C11B9/00 , C11D3/50 , C07C45/61
CPC分类号： C11D3/50 , C07C29/40 , C07C35/31 , C07C45/62 , C07C45/673 , C07C45/69 , C11B9/0046 , C12C11/02 , C07C2102/44
摘要： Described is a novel process for preparing 1,2,3,3,5,6-hexamethyl- bicyclo [2,2,2.] oct-5-en-2-ol by using 2,6,6-trimethylcyclohexa-2,4-diene-1-one as a starting material.
摘要翻译：描述了一种制备1,2,3,3,5,6-六甲基 - 双环[2,2,2]辛-5-烯-2-醇的新方法，其中使用2,6,6-三甲基环己烷-2 ，4-二烯-1-酮作为起始原料。

58. 发明授权

US4514324A 1,2,3,3,5,6-Hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol, and organoleptic uses of same 失效
标题翻译： 1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇及其感官用途
公开(公告)号：US4514324A
公开(公告)日：1985-04-30
申请号：US602569
申请日：1984-04-20
申请人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
发明人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
IPC分类号： C07C29/40 , C07C35/31 , C07C45/62 , C07C45/67 , C07C45/69 , C11B9/00 , C11D3/50 , A61K7/46
CPC分类号： C11D3/50 , C07C29/40 , C07C35/31 , C07C45/62 , C07C45/673 , C07C45/69 , C11B9/0046 , C07C2102/44
摘要： Described is 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol as a mixture of isomers and in its isomeric forms having the structures: ##STR1## and the uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles, and colognes. Also described is a novel process for preparing 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol by first reacting the compound having the structure: ##STR2## with the compound having the structure: ##STR3## in order to produce the ketone defined according to the structure: ##STR4## which is hydrogenated to form the compound having the structure: ##STR5## and further hydrogenated to form the ketone having the structure: ##STR6## This ketone is reacted with CH.sub.3 M wherein M represents Li or MgX and wherein X is chloro, bromo or iodo to form the organometallic intermediate defined according to the structures: ##STR7## These compounds are then hydrolyzed with dilute acid to form the organoleptically useful 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol isomers of our invention defined according to the structures: ##STR8##
摘要翻译：描述为1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇作为异构体的混合物，其异构体具有以下结构：和其用于增强或增强香料组合物，香料制品和古龙水的香气。还描述了制备1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇的新方法，首先使具有以下结构的化合物：＆lt; IMAGE＆gt; 具有以下结构的化合物：为了制备根据以下结构定义的酮：将其氢化形成具有以下结构的化合物：进一步氢化以形成具有以下结构的酮：图像>该酮与CH 3 M反应，其中M表示Li或MgX，其中X为氯，溴或碘，以形成根据以下结构定义的有机金属中间体：然后将这些化合物用稀酸水解以形成感光有用的本发明的1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇异构体根据以下结构定义：

59. 发明授权

US4434085A Perfume or cologne containing 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]-oct-5-en-2-ol 失效
标题翻译：含有1,2,3,3,5,6-六甲基 - 双环[2.2.2] - 辛-5-烯-2-醇的香水或古龙水
公开(公告)号：US4434085A
公开(公告)日：1984-02-28
申请号：US371930
申请日：1982-04-26
申请人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
发明人： William J. Evers , Braja D. Mookherjee , Anton Van Ouwerkerk , Augustinus G. Van Loveren
IPC分类号： C07C29/40 , C07C35/31 , C07C45/62 , C07C45/67 , C07C45/69 , C11B9/00 , C11D3/50 , C07C35/22
CPC分类号： C11D3/50 , C07C29/40 , C07C35/31 , C07C45/62 , C07C45/673 , C07C45/69 , C11B9/0046 , C07C2102/44
摘要： Described is 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol as a mixture of isomers and in its isomeric forms having the structures: ##STR1## and the uses thereof in augmenting or enhancing the aroma of perfume compositions, perfumed articles, and colognes. Also described is a novel process for preparing 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol by first reacting the compound having the structure: ##STR2## with the compound having the structure: ##STR3## in order to produce the ketone defined according to the structure: ##STR4## which is hydrogenated to form the compound having the structure: ##STR5## and further hydrogenated to form the ketone having the structure: ##STR6## This ketone is reacted with CH.sub.3 M wherein M represents Li or MgX and wherein X is chloro, bromo or iodo to form the organometallic intermediate defined according to the structures: ##STR7## These compounds are then hydrolyzed with dilute acid to form the organoleptically useful 1,2,3,3,5,6-hexamethyl-bicyclo[2.2.2]oct-5-en-2-ol isomers of our invention defined according to the structures: ##STR8##
摘要翻译：描述为1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇作为异构体的混合物，其异构体具有以下结构：和其用于增强或增强香料组合物，香料制品和古龙水的香气。还描述了制备1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇的新方法，首先使具有以下结构的化合物：＆lt; IMAGE＆gt; 具有以下结构的化合物：为了制备根据以下结构定义的酮：将其氢化形成具有以下结构的化合物：进一步氢化以形成具有以下结构的酮：图像>该酮与CH 3 M反应，其中M表示Li或MgX，并且其中X是氯，溴或碘，以形成根据以下结构定义的有机金属中间体：然后将这些化合物用稀酸水解以形成感官有用的本发明的1,2,3,3,5,6-六甲基 - 双环[2.2.2]辛-5-烯-2-醇异构体根据以下结构定义：

60. 发明授权

US4143173A Flavoring with 5-acyl-2-(furfurylthio)dihydro-2,5-dialkyl-3-[2H]furanones 失效
标题翻译：用5-亚氨基-2-（呋喃硫基）二氢-2H-二烷基-3-（2H）呋喃酮
公开(公告)号：US4143173A
公开(公告)日：1979-03-06
申请号：US887632
申请日：1978-03-17
申请人： Braja D. Mookherjee , Donald A. Withycombe , Ira Katz , Alfred E. Goossens , Manfred H. Vock , William J. Evers , Joaquin F. Vinals , Jacob Kiwala
发明人： Braja D. Mookherjee , Donald A. Withycombe , Ira Katz , Alfred E. Goossens , Manfred H. Vock , William J. Evers , Joaquin F. Vinals , Jacob Kiwala
IPC分类号： A24B15/40 , C07D307/32 , C07D307/38 , C07D307/42 , C11B9/00 , A23L1/234
CPC分类号： C07D307/32 , A24B15/406 , C07D307/38 , C07D307/42 , C11B9/0076
摘要： Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma and tobacco flavor and aroma augmenting, modifying, enhancing and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product and tobacco aroma and flavor imparting, augmenting, modifying and enhancing materials of one or more 5-acyl-2-(furfurylthio)dihydro-2,5-dialkyl-3-[2H]furanones having the generic structure: ##STR1## wherein R.sub.1 ', R.sub.2 ', R.sub.3 ' and R.sub.4 ' are each the same or different and each represents hydrogen or methyl produced according to the process of reacting one or more alpha, beta diketones containing from 4 up to 6 carbon atoms and having the generic structure: ##STR2## or one or more dimerization products thereof having the generic structure: ##STR3## wherein R.sub.1 ', R.sub.2 ', R.sub.3 ', R.sub.4 ', R.sub.5 ' and R.sub.6 ' are each the same or different and each represents hydrogen or methyl with furfuryl mercaptan having the structure: ##STR4## Addition of one or more 5-acyl-2-(furfurylthio)dihydro-2,5-dialkyl-3-[2H]furanones or "cis" or "trans" isomers thereof to consumable materials is indicated to produce:(A) In flavoring compositions for foodstuffs, chewing gums, toothpastes and medicinal products and in the foodstuffs, chewing gums, toothpastes and medicinal products per se, coffee, roasted, cocoa-like, caramel-like, licorice and roasted almond aroma and flavor characteritics at levels of greater than or equal to 0.01 parts per million; and(B) In tobacco, flavoring compositions for tobacco, tobacco substitutes and flavoring compositions therefor, wheat, caramel/coffee aroma and taste characteristics prior to and on smoking and nutty/pyrazine-like flavor and aroma characteristics with roasted nut like nuances on smoking.

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