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    • 54. 发明专利
    • METHOD OF CLEANING BY ROTATION OF SUBSTRATE
    • JPH10189412A
    • 1998-07-21
    • JP34473996
    • 1996-12-25
    • TOKYO OHKA KOGYO CO LTD
    • IGUCHI ETSUKOSATO MITSURU
    • H01L21/027H01L21/304
    • PROBLEM TO BE SOLVED: To suppress generation of bubbles and so on in cleaning liquid by reducing a major rotating number in a certain degree and by making an accessing time long until reaching the major rotating number when the cleaning liquid remaining on a substrate having a resist pattern film of developing liquid is cleaned by rotation. SOLUTION: A substrate 2 of a semiconductor wafer and so on is set on a spinner 1 and a lower layer reflection preventing film 3 is formed on the surface of the substrate 2. A resist pattern film 4 which is formed by a chemical amplifying negative resist having a alkaline developing property is formed on the lower reflection preventing film 3 and development is performed by supplying developing liquid 5 on the resist pattern film 4. After completion of the steps cleaning liquid 6 is supplied on the resist pattern film 4, the developing liquid 5 is cleaned and the substrate 2 is also cleaned. In this case an accessing time until reaching a major rotation number of the substrate 2 at a low speed of 2500rpm is set more than one second. Therefore generation of bubbles and so on in the cleaning liquid 6 can be suppressed.
    • 59. 发明专利
    • POSITIVE TYPE PHOTOSENSITIVE RESIN COMPOSITION
    • JPH03158855A
    • 1991-07-08
    • JP29766189
    • 1989-11-17
    • TOKYO OHKA KOGYO CO LTD
    • TOKUTAKE NOBUOSATOU YOSHIYUKISATO KAZUFUMIANDO YASUTOSATO MITSURU
    • G03F7/004G03F7/022H01L21/027
    • PURPOSE:To obtain the positive type photoresist compsn. having an excellent sensitizing effect and extremely good preservable stability, image contrast and heat resistance by compounding alpha, alpha', alpha''-tris(4-hydroxyphenyl)-1, 3, 5-triisopropyl benzene into the compsn. contg. an alkaline-soluble novolak type resin and a quinone diazide group-contg. compd. CONSTITUTION:This compsn. is formed by compounding (c) the alpha, alpha', alpha''-tris(4- hydroxyphenyl)-1, 3, 5-triisopropyl benzene is compounded into the compsn. contg. (a) the alkaline-soluble novolak type resin and (b) the quinone diazide group-contg. compd. The photosensitive component consisting of the quinone diazide group-contg. compd. is preferably the complete esterified matter or partially esterified matter of, for example, polyhydroxybenzophenone, such as 2, 3, 4-trihydroxybenzophenone, and naphthoquinone-1, 2-diazide-5-sulfonic acid. The alpha, alpha', alpha''-tris(4-hydroxyphenyl)-1, 3, 5-triisopropyl benzene has the excellent sensitizing effect and has the effect of accelerating the dissolution of exposed parts at the time of development and conversely to suppress the dissolution of unexposed parts, and therefore, has the solution selectivity with a developing soln. The resist patterns having the excellent image contrast are thus formed.
    • 60. 发明专利
    • Positive resist composition
    • 积极抵抗组成
    • JP2012078864A
    • 2012-04-19
    • JP2011284144
    • 2011-12-26
    • Tokyo Ohka Kogyo Co Ltd東京応化工業株式会社
    • HIRAYAMA HIROSHIHANEDA HIDEOFUJIMURA SATOSHIIWAI TAKESHISATO MITSURUTAKASU RYOICHITACHIKAWA TOSHIKAZUIWASHITA ATSUSHIISHIZUKA KEITAYAMADA TOMOTAKATAKAYAMA JUICHIYOSHIDA MASAAKI
    • G03F7/039G03F7/26C08F8/12C08F220/28G03F7/038G03F7/38H01L21/027
    • PROBLEM TO BE SOLVED: To provide a resist composition which is stable to a solvent used in an immersion lithography process and has excellent sensitivity and a resist pattern profile.SOLUTION: A positive resist composition comprises: a resin component (A) in which alkali solubility is increased by action of acid; an acid generator component (B) which generates the acid by exposure; an organic solvent (C) which dissolves the (A) component and the (B) component; and a nitrogen-containing organic compound (D). The resin component (A) has (a1) a constitutional unit derived from a (meth) acrylic acid ester having an acid-dissociable dissolution inhibiting group, (a2) a constitutional unit derived from the (meth) acrylic acid ester having a lactone unit, and (a4) a constitutional unit derived from the (meth) acrylic acid ester having a polycyclic group, but does not have (a0) (a0-1) a constitutional unit containing an anhydride of dicarboxylic acid and (a0-2) a constitutional unit containing a phenolic hydroxyl group.
    • 要解决的问题:提供一种对浸渍光刻工艺中使用的溶剂稳定的抗蚀剂组合物,并且具有优异的灵敏度和抗蚀剂图案轮廓。 解决方案:正性抗蚀剂组合物包括:通过酸的作用使碱溶解度增加的树脂组分(A) 通过曝光产生酸的酸发生剂组分(B); 溶解(A)成分和(B)成分的有机溶剂(C) 和含氮有机化合物(D)。 树脂成分(A)具有(a1)来自具有酸解离性溶解抑制基的(甲基)丙烯酸酯的结构单元,(a2)来自具有内酯单元的(甲基)丙烯酸酯的结构单元 ,(a4)来自具有多环基的(甲基)丙烯酸酯的结构单元,但不具有(a0)(a0-1)含有二羧酸的酸酐的结构单元和(a0-2)a 含有酚羟基的结构单元。 版权所有(C)2012,JPO&INPIT