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    • 52. 发明授权
    • Zirconia alloy cylinders and sleeves for imaging and lithographic
printing methods
    • 氧化锆合金圆筒和袖子用于成像和平版印刷方法
    • US5855173A
    • 1999-01-05
    • US844348
    • 1997-04-18
    • Dilip K. ChatterjeeSyamal K. GhoshBarbara L. Nussel
    • Dilip K. ChatterjeeSyamal K. GhoshBarbara L. Nussel
    • G03F7/09B41C1/10B41M5/26B41N1/00B41N1/08G03F7/00
    • B41C1/1041B41N1/006
    • Rotary lithographic printing members are prepared from a non-porous zirconia ceramic that is an alloy of ZrO.sub.2 and a second oxide chosen from MgO, CaO, Y.sub.2 O.sub.3, Sc.sub.2 O.sub.3, a rare earth oxide or a combination of any of these. These printing members can be rotary printing cylinders having a zirconia alloy ceramic printing surface. Such cylinders can be composed of zirconia alloy ceramic throughout, or have a ceramic sleeve or shell mounted around a non-ceramic core. In use, the surface of the zirconia alloy ceramic printing member is imagewise exposed to infrared radiation which transforms it from a hydrophilic to an oleophilic state or from an oleophilic to a hydrophilic state, thereby creating a lithographic printing surface which is hydrophilic in non-image areas and is oleophilic and thus capable of accepting printing ink in image areas. These printing members are directly laser-imageable as well as image erasable.
    • 旋转平版印刷构件由不含氧化锆的陶瓷制成,其为ZrO 2和选自MgO,CaO,Y 2 O 3,Sc 2 O 3,稀土氧化物或其任何组合的第二氧化物的合金。 这些印刷部件可以是具有氧化锆合金陶瓷印刷表面的旋转印刷滚筒。 这种圆柱体可以由整个氧化锆合金陶瓷组成,或者具有安装在非陶瓷芯周围的陶瓷套筒或壳体。 在使用中,氧化锆合金陶瓷印刷部件的表面被成像地暴露于红外辐射,其将其从亲水性转变为亲油性状态或从亲油性转变为亲水状态,由此产生在非图像中亲水的平版印刷表面 并且是亲油的,因此能够在图像区域中接受印刷油墨。 这些印刷部件直接可激光成像,图像可擦除。
    • 53. 发明授权
    • Laser ablation imaging of zirconia-alumina composite ceramic printing
member
    • 氧化锆 - 氧化铝复合陶瓷印刷部件的激光烧蚀成像
    • US5836249A
    • 1998-11-17
    • US848332
    • 1997-05-01
    • Dilip K. ChatterjeeSyamal K. Ghosh
    • Dilip K. ChatterjeeSyamal K. Ghosh
    • B41C1/10B41N1/00
    • B41N1/006B41C1/1033B41C1/1041Y10S430/146
    • Reusable lithographic printing members are prepared from a ceramic that is a composite of a zirconia alloy and .alpha.-alumina. In use, a printing surface of the zirconia-alumina composite ceramic is imagewise exposed to electromagnetic radiation such as from a laser under controlled conditions to provide ablation of the zirconia alloy in the exposed areas. Those areas are transformed from a hydrophilic to an oleophilic state or from an oleophilic to a hydrophilic state, thereby creating a lithographic printing surface that is hydrophilic in non-image areas and is oleophilic and thus capable of accepting printing ink in image areas. Such inked areas can then be used to transfer an image to a suitable substrate in lithographic printing. The printing members are directly laser-imageable as well as image erasable, and can include printing plates, printing cylinders, printing tapes and printing sleeves.
    • 可再利用的平版印刷构件由氧化锆合金和α-氧化铝的复合材料制成。 在使用中,氧化锆 - 氧化铝复合陶瓷的印刷表面在受控条件下成像暴露于诸如激光的电磁辐射,以在暴露的区域中提供氧化锆合金的烧蚀。 这些区域从亲水性状态转变为亲油性状态或从亲油性状态转变为亲水状态,从而产生在非图像区域中亲水的亲和性并且因此能够接受图像区域中的印刷油墨的平版印刷表面。 然后可以使用这样的油墨区域在平版印刷中将图像转印到合适的基底上。 印刷部件直接可激光成像,图像可擦除,可包括印版,印刷滚筒,印刷胶带和印刷套筒。
    • 58. 发明授权
    • Method of making core shell structured articles based on alumina
ceramics having spinel surfaces
    • 基于具有尖晶石表面的氧化铝陶瓷制造芯壳结构制品的方法
    • US5683481A
    • 1997-11-04
    • US700256
    • 1996-08-20
    • Dilip K. ChatterjeeSyamal K. GhoshGregory S. Jarrold
    • Dilip K. ChatterjeeSyamal K. GhoshGregory S. Jarrold
    • C04B35/10C04B35/119C04B35/64C04B41/50C04B41/87C03B19/01C03B19/09C04B33/34C04B33/36
    • C04B41/009C04B35/119C04B35/64C04B41/5046C04B41/87C04B2111/0025
    • An alumina ceramic article and a method for preparing the article. The method comprises the steps of: (1) Compacting a mixture of a first concentration of particulate aluminum oxide sufficient to prevent retention of the zirconium oxide alloy particles in the shell in a predominantly tetragonal crystal structure and a second concentration of particulate zirconium oxide alloy. The zirconium oxide alloy is zirconium oxide and a secondary oxide selected from the group consisting of MgO, CaO, Y.sub.2 O.sub.3, Sc.sub.2 O.sub.3, CeO.sub.2, and rare earth oxides having a concentration of secondary oxide generally of about 0.5 to about 5 mole percent Y.sub.2 O.sub.3, from about 0.1 to about 1 mole percent MgO, from about 0.5 to about 15 mole percent CeO.sub.2, from about 0.5 to about 7.0 mole percent Sc.sub.2 O.sub.3, or from about 0.5 to about 5 mole percent CaO, relative to the total of the zirconium oxide alloy. The compacting results in the formation of a blank.(2) Providing contact between the blank and a dopant oxide. (3) Sintering the blank in contact with the dopant oxide wherein said first concentration is from 50-75 weight percent of the total of the first and second concentrations.
    • 一种氧化铝陶瓷制品及其制备方法。 该方法包括以下步骤:(1)将第一浓度的微粒氧化铝的混合物压实成足以防止氧化锆合金颗粒以主要为四方晶体结构和第二浓度的颗粒状氧化锆合金在壳中的保留。 氧化锆合金是氧化锆和选自MgO,CaO,Y 2 O 3,Sc 2 O 3,CeO 2的二次氧化物和二氧化硫浓度通常为约0.5〜约5摩尔%Y 2 O 3的稀土氧化物,从约 0.1至约1摩尔%的MgO,约0.5至约15摩尔%的CeO 2,约0.5至约7.0摩尔%的Sc 2 O 3,或约0.5至约5摩尔%的CaO,相对于氧化锆合金的总量。 压实导致形成空白。 (2)提供坯料与掺杂剂氧化物之间的接触。 (3)烧结坯料与掺杂剂氧化物接触,其中所述第一浓度为第一和第二浓度总量的50-75重量%。