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    • 52. 发明授权
    • Polyimide
    • 聚酰亚胺
    • US5508377A
    • 1996-04-16
    • US357193
    • 1994-12-13
    • Wataru YamashitaYuichi OkawaShoji TamaiAkihiro Yamaguchi
    • Wataru YamashitaYuichi OkawaShoji TamaiAkihiro Yamaguchi
    • C08G73/10C08L79/08C08G69/26
    • C08G73/1085C08G73/10C08G73/1039C08G73/105C08G73/1053C08G73/1071C08L79/08
    • This invention relates to a novel polyimide or polyimide copolymer having excellent heat resistance and greatly improved processability, and has a novel aromatic diamino compound used for the polyimide, a preparation process thereof, a polyimide-based resin composition comprising the polyimide or polyimide copolymer and a fibrous reinforcement, a process for preparing the resin composition, an injection molded article of the resin composition.The polyimide comprise a requisite structural unit having one or more recurring structural units of the formula: ##STR1## wherein L is an oxygen atom, carbonyl, isopropylidene or hexafluoroisopropylidene, and X is ##STR2## and Ar is a tetravalent radical having 6 to 27 carbon atoms and being selected from the group consisting of a monoaromatic radical, condensed polyaromatic radical and noncondensed polyaromatic radical having aromatic radicals connected to each other with a direct bond or a bridge member.The polyimide or polyimide copolymer is outstanding in melt-flow stability, and has greatly improved processability and excellent heat resistance. Consequently, the polyimide or polyimide copolymer can be applied to structural materials, and electic.cndot.electronic appliances.
    • 本发明涉及耐热性优异且加工性极佳的新型聚酰亚胺或聚酰亚胺共聚物,具有用于聚酰亚胺的新型芳族二氨基化合物及其制备方法,包含聚酰亚胺或聚酰亚胺共聚物的聚酰亚胺系树脂组合物和 纤维增强材料,树脂组合物的制备方法,树脂组合物的注塑制品。 聚酰亚胺包括具有一个或多个下式的重复结构单元的必需结构单元:其中L是氧原子,羰基,异亚丙基或六氟异亚丙基,X是(5)和Ar 是具有6至27个碳原子的四价基团,并且选自具有芳族基团的单芳族基团,缩合多芳族基团和具有直接键合或桥连构件彼此连接的非缩合多芳族基团。 聚酰亚胺或聚酰亚胺共聚物在熔体流动稳定性方面是突出的,并且具有极大的改进的加工性和优异的耐热性。 因此,聚酰亚胺或聚酰亚胺共聚物可以应用于结构材料和电子电器。
    • 56. 发明授权
    • Polyimide
    • 聚酰亚胺
    • US5470943A
    • 1995-11-28
    • US360584
    • 1994-12-21
    • Yoshihiro SakataWataru YamashitaYuichi OkawaShoji TamaiTsutomu IshidaMitsunori MatsuoKeizaburo YamaguchiAkihiro Yamaguchi
    • Yoshihiro SakataWataru YamashitaYuichi OkawaShoji TamaiTsutomu IshidaMitsunori MatsuoKeizaburo YamaguchiAkihiro Yamaguchi
    • C08G73/10C08G77/10C07D213/69C08G69/26
    • C08G73/1039C08G73/1085
    • This invention relates to a novel fluorine-containing polyimide or polyimide copolymer being colorless and having transparency and very low dielectric characteristics, and has a novel aromatic diamino compound used for the polyimide, a preparation process thereof, a polyimide-based resin composition comprising the polyimide or polyimide copolymer and a fibrous reinforcement, a process for preparing the resin composition, an injection molded article of the resin composition.The polyimide comprise a requisite structural unit having one or more recurring structural units of the formula: ##STR1## wherein Ar is a tetravalent radical having 6 to 27 carbon atoms and being selected from the group consisting of a monoaromatic radical, condensed polyaromatic radical and noncondensed polyaromatic radical having aromatic radicals connected to each other with a direct bond or a bridge member, a trifluoromethyl radical is situated at the 3- or the 4-position on a pyridine nucleus, and an imide nitrogen atom is connected at the 3- or the 4-position to an ether bond.The polyimide or polyimide copolymer has excellent heat resistance, outstanding melt-flow stability and greatly improved processability, and also is colorless and has high transparency and very low dielectric coefficient, and can be expected to be used as raw materials for electric.cndot.electronic appliances and optical instruments due to the above characteristics.
    • 本发明涉及一种新颖的含氟聚酰亚胺或聚酰亚胺共聚物,其具有透明性和非常低的介电特性,并且具有用于聚酰亚胺的新型芳族二氨基化合物及其制备方法,该聚酰亚胺系树脂组合物含有聚酰亚胺 或聚酰亚胺共聚物和纤维增强剂,树脂组合物的制备方法,树脂组合物的注塑制品。 聚酰亚胺包含具有一个或多个下式的重复结构单元的必需结构单元:其中Ar是具有6至27个碳原子的四价基团,并且选自单芳族基团,缩合多芳族基团 具有芳族基团的自由基和非缩合多芳族基团彼此直接键合或桥接成员,三氟甲基位于吡啶核上的3-或4-位,酰亚胺氮原子连接在3 - 或4-位到醚键。 聚酰亚胺或聚酰亚胺共聚物具有优异的耐热性,优异的熔体流动稳定性和极好的加工性,并且是无色的,具有高透明度和非常低的介电系数,并且可以预期用作电气电子设备的原料 光学仪器由于上述特点。
    • 60. 发明授权
    • Polyimide composition
    • 聚酰亚胺组合物
    • US5321096A
    • 1994-06-14
    • US35043
    • 1993-03-22
    • Yuichi OkawaNobuhito KogaHideaki OikawaTadashi AsanumaAkihiro Yamaguchi
    • Yuichi OkawaNobuhito KogaHideaki OikawaTadashi AsanumaAkihiro Yamaguchi
    • C08G73/10C08L71/00C08L79/08C08L81/06C08F283/04C08G69/48
    • C08L71/00C08G73/101C08L79/08C08L81/06
    • A thermoplastic resin composition comprise 99.9.about.50 parts by weight of one or more thermoplastic resin selected from the group consisting of aromatic polyimide, aromatic polyetherimide, aromatic polyamideimide, aromatic polyethersulfone and aromatic polyether ketone and 0.1.about.50 parts by weight of one or more liquid crystal type aromatic polyimide having recurring structural units represented by the formula (1): ##STR1## wherein R.sub.1 .about.R.sub.5 is a hydrogen atom, fluorine atom, trifluoromethyl, methyl, ethyl or cyano and may be the same or different, and R is a tetravalent radical having 6.about.27 carbon atoms and being selected from the group consisting of a monoaromatic radical, condensed polyaromatic radical and noncondensed aromatic radical connected each other with a direct bond or a bridge member.The present invention can provide thermoplastic resin compositions which have remarkably good processability and excellent thermal stability in addition to essentially excellent properties of each resin.
    • 热塑性树脂组合物包含99.9重量份的一种或多种选自芳族聚酰亚胺,芳族聚醚酰亚胺,芳族聚酰胺酰亚胺,芳族聚醚砜和芳族聚醚酮的热塑性树脂和0.1重量份的一种或多种液体 具有由式(1)表示的重复结构单元的结晶型芳族聚酰亚胺:(1)n原子,氟原子,三氟甲基,甲基,乙基或氰基,可以相同或不同,R是具有 6个碳原子,并且选自由直链或桥构件相互连接的单芳族基团,缩合多芳族基团和非缩合芳族基团组成的组。 本发明可以提供具有非常好的加工性和优异的热稳定性的热塑性树脂组合物,除了每种树脂的基本上优异的性能。