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    • 51. 发明授权
    • Reducing gas sensor and a method of producing the same
    • 减少气体传感器及其制造方法
    • US3999947A
    • 1976-12-28
    • US618680
    • 1975-10-01
    • Toshihiro MiharaMasatake AyusawaKeiji MatsumotoKunio SatoYoshio Iida
    • Toshihiro MiharaMasatake AyusawaKeiji MatsumotoKunio SatoYoshio Iida
    • G01N27/12G01N27/00G01N33/00
    • G01N27/12
    • This invention provides a reducing gas sensor which has a gas sensitive element of .gamma.-ferric oxide (.gamma.-Fe.sub.2 O.sub.3), a pair of electrodes and a heater element. The .gamma.-ferric oxide is in the form of a thin film, a plate or a thin surface layer on a sintered plate of .alpha.-ferric oxide. This invention also provides a method of producing the reducing gas sensor, which includes the steps of firing .gamma.-Fe.sub.2 O.sub.3, .gamma.-FeOOH or Fe.sub.3 O.sub.4 powder on a substrate and applying thereto a pair of electrodes and a heater element; or sintering alpha-ferric oxide (.alpha.-Fe.sub.2 O.sub.3) and reducing it to magnetite and oxidizing it at the surface thereof to .gamma.-ferric oxide as a gas sensitive element. The sensitivity (R.sub.A /R.sub.G) of the gas sensitive element of .gamma.-ferric oxide is 10 to 130.degree. at 270.degree. C in an atmosphere containing 0.1 to 1 percent by volume propane gas, and the reducing gas sensor has high sensitivity and stability.
    • 本发明提供一种还原气体传感器,其具有γ-氧化铁(γ-Fe 2 O 3)气体敏感元件,一对电极和加热元件。 γ-氧化铁是在α氧化铁烧结板上的薄膜,板或薄表面层的形式。 本发明还提供一种还原气体传感器的制造方法,其特征在于包括以下步骤:将γ-Fe 2 O 3,γ-FeOOH或Fe 3 O 4粉末烧在基片上,并施加一对电极和加热元件; 或烧结α-氧化铁(α-Fe 2 O 3)并将其还原成磁铁矿并将其在表面氧化成作为气体敏感元件的γ-二氧化铬。 在含有0.1〜1体积%丙烷气体的气氛中,γ-氧化铁气敏元件的灵敏度(RA / RG)在270℃为10〜130℃,还原气体传感器具有高灵敏度和稳定性。