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    • 52. 发明授权
    • Alkaline storage battery
    • 碱性蓄电池
    • US5346781A
    • 1994-09-13
    • US646012
    • 1991-01-28
    • Kohji YuasaMunehisa IkomaHiroshi KawanoOsamu TakahashiIsao Matsumoto
    • Kohji YuasaMunehisa IkomaHiroshi KawanoOsamu TakahashiIsao Matsumoto
    • H01M4/24H01M4/38H01M4/80H01M10/24
    • H01M4/242H01M4/383H01M4/808
    • Disclosed is an alkaline storage battery, in which the negative electrode is constituted by a hydrogen absorbing alloy capable of absorbing/desorbing hydrogen electrochemically, and a hydrophobic material is provided in the space between the surface of the negative electrode and the separator while a hydrophilic material is provided in the inside of the negative electrode, thereby properly secure both wetting property and surface hydrophobic property of the negative electrode against the alkaline electrolytic solution. Accordingly, a hydrogen gas generated in charging the battery can be absorbed by a vapor phase reaction in the hydrophobic portion in the surface of the negative electrode which is exposed to the vapor phase and can be absorbed electrochemically in the portion of the negative electrode which is wetted by the electrolytic solution, so that the inner pressure of the battery can be reduced to thereby make it possible to perform quick charging.
    • 公开了一种碱性蓄电池,其中负极由能够电化学吸收/解吸氢的吸氢合金构成,并且在负极表面和隔板之间的空间中设置疏水材料,同时亲水材料 设置在负极的内部,从而适当地确保负极的润湿性和表面疏水性相对于碱性电解液。 因此,在电池充电中产生的氢气可以通过暴露于气相的负极表面中的疏水部分中的气相反应吸收,并且可以在负极的部分电化学吸收 被电解液润湿,从而可以降低电池的内部压力,从而可以进行快速充电。
    • 53. 发明授权
    • Alkaline storage battery
    • 碱性蓄电池
    • US5250369A
    • 1993-10-05
    • US952146
    • 1992-09-28
    • Kohji YuasaMunehisa IkomaHiroshi KawanoOsamu TakahashiIsao Matsumoto
    • Kohji YuasaMunehisa IkomaHiroshi KawanoOsamu TakahashiIsao Matsumoto
    • H01M4/24H01M4/38H01M4/80H01M10/52
    • H01M4/383H01M4/242H01M4/808
    • Disclosed is an alkaline storage battery, in which the negative electrode is constituted by a hydrogen absorbing alloy capable of absorbing/desorbing hydrogen electrochemically, and a hydrophobic material is provided in the space between the surface of the negative electrode and the separator while a hydrophilic material is provided in the inside of the negative electrode, thereby properly secure both wetting property and surface hydrophobic property of the negative electrode against the alkaline electrolytic solution. Accordingly, a hydrogen gas generated in charging the battery can be absorbed by a vapor phase reaction in the hydrophobic portion in the surface of the negative electrode which is exposed to the vapor phase and can be absorbed electrochemically in the Portion of the negative electrode which is wetted by the electrolytic solution, so that the inner pressure of the battery can be reduced to thereby make it possible to perform quick charging.
    • 公开了一种碱性蓄电池,其中负极由能够电化学吸收/解吸氢的吸氢合金构成,并且在负极表面和隔板之间的空间中设置疏水材料,同时亲水材料 设置在负极的内部,从而适当地确保负极的润湿性和表面疏水性相对于碱性电解液。 因此,在电池充电中产生的氢气可以通过在暴露于气相的负极表面的疏水部分中的气相反应吸收,并且可以在负极的部分中被电化学吸收 被电解液润湿,从而可以降低电池的内部压力,从而可以进行快速充电。
    • 60. 发明授权
    • Hydrogen storage alloy electrode
    • 储氢合金电极
    • US06207323B1
    • 2001-03-27
    • US09263756
    • 1999-03-05
    • Seiji YamaguchiShinichi YuasaMunehisa Ikoma
    • Seiji YamaguchiShinichi YuasaMunehisa Ikoma
    • H01M458
    • H01M4/383Y10S420/90
    • Disclosed is a hydrogen storage alloy electrode for use in alkaline storage batteries that can reduce internal resistance of the battery and can give an excellent output characteristic and a long cycle life to the battery. The electrode comprises an AB5-type hydrogen storage alloy powder, a yttrium compound and a compound of a light rare earth element. The total content of the yttrium compound and the compound of a light rare earth element is in a range of 0.5 to 2.0 parts by weight per 100 parts by weight of hydrogen storage alloy powder. Preferable ratios of the yttrium compound and the compound of a light rare earth element selected from La, Ce, Pr and Nd are, respectively, 60 wt % or more and 7 wt % or less in the total amount of the yttrium compound and the compound of the light rare earth element.
    • 公开了一种用于碱性蓄电池的储氢合金电极,其可以降低电池的内部电阻,并且可以给电池提供优异的输出特性和长的循环寿命。 电极包括AB5型储氢合金粉末,钇化合物和轻稀土元素的化合物。 钇化合物和轻稀土元素的化合物的总含量相对于100重量份的储氢合金粉末为0.5〜2.0重量份。 钇化合物和选自La,Ce,Pr和Nd的轻稀土元素的化合物的比例分别为钇化合物和化合物的总量的60重量%以上且7重量%以下 的轻稀土元素。