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    • 58. 发明申请
    • METHODS OF CONTROLLING INSECTS
    • 控制方法
    • WO2014029709A1
    • 2014-02-27
    • PCT/EP2013/067186
    • 2013-08-16
    • SYNGENTA PARTICIPATIONS AG
    • EL QACEMI, MyriemCASSAYRE, Jérôme Yves
    • A01N43/80A01P7/04
    • A01N43/80C07D261/04G06Q30/018
    • The present invention relates to methods, preferably for controlling and/or preventing infestation of boll weevil in cotton, comprising applying to a crop of cotton plants, the locus thereof, or propagation material thereof, a compound of formula (I), wherein -B 1 -B 2 -B 3 - is -C=N-O-, -C=N-CH 2 -, -C=CH-O- or -N-CH 2 -CH 2 -; L is a direct bond or methylene; A 1 and A 2 are C-H, or one of A 1 and A 2 is C-H and the other is N; X 1 is group X R 1 is C 1 -C 4 alkyl, C 1 C 4 aloalkyl or C 3 -C 6 cycloalkyl; R 2 is chlorodifluoromethyl or trifluoromethyl; each R 3 is independently bromo, chloro, fluoro or trifluoromethyl; R 4 is hydrogen, halogen, methyl, halomethyl or cyano; R 5 is hydrogen; or R 4 and R 5 together form a bridging 1,3-butadiene group; p is 2 or 3.
    • 本发明涉及优选用于控制和/或预防棉花中的棉铃象鼻虫感染的方法,其包括将棉花植物作物的基因座或其繁殖材料施用于式(I)化合物,其中-B1 -B2-B3 - 是-C = NO - , - C = N-CH2-,-C = CH-O-或-N-CH2-CH2-; L是直接键或亚甲基; A1和A2是C-H,A1和A2之一是C-H,另一个是N; X1是基团XR1是C1-C4烷基,C1C4烷基或C3-C6环烷基; R2是氯二氟甲基或三氟甲基; 每个R 3独立地是溴,氯,氟或三氟甲基; R4是氢,卤素,甲基,卤代甲基或氰基; R5是氢; 或R4和R5一起形成桥连1,3-丁二烯基团; p是2或3。
    • 59. 发明申请
    • METHODS OF CONTROLLING INSECTS
    • 控制方法
    • WO2014029706A2
    • 2014-02-27
    • PCT/EP2013/067182
    • 2013-08-16
    • SYNGENTA PARTICIPATIONS AG
    • EL QACEMI, MyriemCASSAYRE, Jérôme Yves
    • A01N43/36A01N43/653A01N43/80A01P7/04
    • A01N43/80A01N43/36A01N43/653C07D207/08C07D207/20C07D261/04C07D403/10C07D413/10
    • The present invention provides a method comprising applying to a crop of cotton plants, the locus thereof, or propagation material thereof, a compound of formula (I) wherein -B 1 -B 2 -B 3 -is -C=N-O-, -C=N-CH 2 -, or -N-CH 2 -CH 2 -;R 1 is trifluoromethyl, difluoromethyl or chlorodifluoromethyl; R 2 is group X formula (X) X 2 is C-X 6 or nitrogen; X 1 , X 3 and X 6 are independently hydrogen, halogen or trihalomethyl, wherein at least one of X 1 , X 3 and X 6 is not hydrogen; A is selected from A1 to A (A5) B is C-R 6 , CH or nitrogen;1Y2 and Y3 are independently CH or nitrogen; wherein no more than two of Y 1 , Y 2 and Y 3 are nitrogen and wherein Y 2 and Y 3 are not both nitrogen; R is hydrogen, halogen, cyano, nitro, NH 2 , C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 3 -C 5 cycloalkyl, C 3 -C 5 halocycloalkyl, C 1 -C 2 alkoxy, or C 1 -C 2 haloalkoxy;provided that when A is A3 or A4 R 5 is not hydrogen; R 6 when present together with R 5 forms a -CH=CH-CH=CH-bridge; R 7 is C 1 -C 4 alkyl; ) R 8 is C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 alkoxy(C 1 -C 4 )alkyl, C 1 -C 4 alkylthio(C 1 -C 4 )alkyl, C 1 -C 4 alkylsulfinyl(C 1 -C 4 )alkyl, C 1 -C 4 alkylsulfonyl(C 1 -C 4 ) alkyl, C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkyl(C 1 -C 4 )alkyl-, or tetrahydrofuranyl;R 9 is C 1 -C 4 alkyl, C 1 -C 4 haloalkyl, C 1 -C 4 alkyl-O-CH 2 -, C-C4 haloalkyl-O-CH 2 -,C 3 -C 6 cycloalkyl, C 3 -C 6 cycloalkyl-CH 2 -, C 1 -C 4 alkyl-S-CH 2 -, C 1 -C 4 alkyl-S(O)-CH 2 -,or C 1 -C 4 alkyl-S(O 2 )-CH 2 ; each Z is independently halogen, C 1 -C 12 alkyl or C 1 -C 12 alkyl substituted by one to five R 12 , nitro, C 1 -C 12 alkoxy or C 1 -C 12 alkoxy substituted by one to five R 12 cyano, C 1 -C 12 alkylsulfinyl, C 1 -C 12 alkylsulfonyl,C 1 -C 12 haloalkylsulfinyl, C 1 -C 12 haloalkylsulfonyl, hydroxyl or thiol;each R 12 is halogen, cyano, nitro, hydroxy, C 1 -C 8 alkoxy-, C 1 -C 8 haloalkoxy-, mercapto, C 1 -C 8 alkylthio-, or C 1 -C 8 haloalkylthio; and k is 0, 1,2 or 3. The methods are preferably for the control of Anthonomus grandis.
    • 本发明提供了一种方法,其包括将棉花植物的基因座或其繁殖材料施用于其中-B1-B2-B3-为-C = NO-,-C = N的式(I)化合物 -CH 2 - 或-N-CH 2 -CH 2 - ; R 1是三氟甲基,二氟甲基或氯二氟甲基; R2是基团X式(X)X2是C-X6或氮; X 1,X 3和X 6独立地为氢,卤素或三卤代甲基,其中X 1,X 3和X 6中的至少一个不是氢; A选自A1至A(A5)B为C-R6,CH或氮; 1Y2和Y3独立地为CH或氮; 其中Y1,Y2和Y3中不超过两个是氮,并且其中Y2和Y3不都是氮; R是氢,卤素,氰基,硝基,NH 2,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 3 -C 5环烷基,C 3 -C 5卤代环烷基,C 1 -C 2烷氧基或C 1 -C 2卤代烷氧基;条件是当A为A3或A4 R5 不是氢; 当与R 5一起存在时,R6形成-CH = CH-CH = CH-桥; R7是C1-C4烷基; )R 8是C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4烷氧基(C 1 -C 4)烷基,C 1 -C 4烷硫基(C 1 -C 4)烷基,C 1 -C 4烷基亚磺酰基(C 1 -C 4)烷基,C 1 -C 4烷基磺酰基 (C 1 -C 4)烷基,C 3 -C 6环烷基,C 3 -C 6环烷基(C 1 -C 4)烷基或四氢呋喃基; R 9为C 1 -C 4烷基,C 1 -C 4卤代烷基,C 1 -C 4烷基-O-CH 2 - ,C-C 4 卤代烷基-O-CH 2 - ,C 3 -C 6环烷基,C 3 -C 6环烷基-CH 2 - ,C 1 -C 4烷基-S-CH 2 - ,C 1 -C 4烷基-S(O)-CH 2 - 或C 1 -C 4烷基-S (O2)-CH 2; 每个Z独立地为卤素,被一至五个R 12,硝基,C 1 -C 12烷氧基或被一至五个R 12氰基,C 1 -C 12烷基亚磺酰基,C 1 -C 12烷基磺酰基,C 1 -C 12烷氧基取代的C 1 -C 12烷氧基取代的C 1 -C 12烷基或C 1 -C 12烷基, C 12卤代烷基亚磺酰基,C 1 -C 12卤代烷基磺酰基,羟基或硫醇;每个R 12是卤素,氰基,硝基,羟基,C 1 -C 8烷氧基 - ,C 1 -C 8卤代烷氧基 - ,巯基,C 1 -C 8烷硫基 - 或C 1 -C 8卤代烷硫基; 并且k是0,1,2或3.这些方法优选用于控制Anthonomus grandis。