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51. 发明申请

US20080027193A1 ISOTACTIC-ATACTIC POLYPROPYLENE AND METHODS OF MAKING SAME 失效
标题翻译：同位素聚丙烯及其制备方法
公开(公告)号：US20080027193A1
公开(公告)日：2008-01-31
申请号：US11461059
申请日：2006-07-31
申请人： Vladimir Marin , Abbas Razavi
发明人： Vladimir Marin , Abbas Razavi
IPC分类号： C08F4/44
CPC分类号： C08F10/06 , C08F10/00 , C08F110/06 , C08F210/06 , Y10S526/901 , Y10S526/941 , Y10S526/943 , C08F4/65927 , C08F2500/15 , C08F2500/01 , C08F2500/11 , C08F2500/18 , C08F210/16
摘要： A method of producing a polymer comprising contacting in a reaction zone under conditions suitable for polymerization of an alpha-olefin monomer with a metallocene catalyst having at least three asymmetric centers, and recovering an alpha-olefin polymer from the reaction zone. A method of polymerizing propylene comprising contacting in a reaction zone propylene, a cocatalyst, and a metallocene catalyst having the formula including stereoisomers: and recovering polypropylene from the reaction zone. A polypropylene composition having a tensile modulus from 40,000 psi to 300,000 psi, a tensile strength at yield from 2,000 psi to 6,000 psi, a tensile strength at break from 1,000 psi to 3,500 psi, a tensile strength from 1,000 psi to 5,000 Kpsi, an elongation at yield of greater than or equal to 10%, and an elongation at break from 50% to 500%.
摘要翻译：一种制备聚合物的方法，包括在适于使α-烯烃单体与具有至少三个不对称中心的茂金属催化剂聚合的条件下在反应区中接触，并从反应区回收α-烯烃聚合物。包括使丙烯，助催化剂和具有下式的茂金属催化剂的反应区域中包含立体异构体的方法：从反应区回收聚丙烯。拉伸模量为40,000psi至300,000psi的聚丙烯组合物，产率为2000psi至6,000psi的拉伸强度，1,000psi至3500psi的断裂拉伸强度，1000psi至5,000Kpsi的拉伸强度，伸长率产率大于或等于10％，断裂伸长率为50％至500％。

52. 发明授权

US07309748B2 Group III bridged ionic metallocene based on cyclopentadienyl-fluorenyl ligands 失效
标题翻译：基于环戊二烯基 - 芴基配体的III族桥连离子茂金属
公开(公告)号：US07309748B2
公开(公告)日：2007-12-18
申请号：US10543670
申请日：2004-01-23
申请人： Jean-Francois Carpentier , Evgueni Kirillov , Abbas Razavi
发明人： Jean-Francois Carpentier , Evgueni Kirillov , Abbas Razavi
IPC分类号： C08F4/6192 , C08F10/00
CPC分类号： C08F10/00 , C07F17/00 , C08F20/12 , C08F36/04 , Y10S526/943 , C08F4/52
摘要： The present invention discloses a metallocene catalyst component of the formula (I) [(Flu-R″-Cp)2M]−[Li(ether)4]+, wherein Cp is a cyclopentadienyl, substituted or unsubstituted, Flu is a fluorenyl, substituted or unsubstitutted, M is a metal Group III of the Periodic Table, and R″ is a structural bridge between Cp and Flu imparting stereorigidity to the component. It further discloses a process for preparing said metallocene catalyst component and its use in controlled polymerisation.
摘要翻译：本发明公开了式（I）的茂金属催化剂组分[（Flu-R“ - Cp）2 M] - [Li（醚）其中Cp是环戊二烯基，取代或未取代的，Flu是芴基，取代或未取代的，M是周期表的金属III族，R“是 Cp和Flu之间的结构桥梁赋予组件立体刚度。它进一步公开了一种制备所述茂金属催化剂组分的方法及其在受控聚合中的用途。

53. 发明申请

US20070255023A1 Process for copolymer production using fluorinated transition metal catalysts 审中-公开
标题翻译：使用氟化过渡金属催化剂制备共聚物的方法
公开(公告)号：US20070255023A1
公开(公告)日：2007-11-01
申请号：US11540181
申请日：2006-09-29
申请人： Abbas Razavi , Vladimir P. Marin , Margarito Lopez
发明人： Abbas Razavi , Vladimir P. Marin , Margarito Lopez
IPC分类号： C08F4/44
CPC分类号： B01J21/12 , B01J37/26 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F2400/02 , C08F2/00 , C08F4/025 , C08F2500/20 , C08F2500/03 , C08F2500/12 , C08F210/14 , C08F2500/04 , C08F210/16
摘要： Copolymers and methods of forming copolymers are described herein. The methods generally include providing a transition metal compound represented by the formula [L]mM[A]n, wherein L is a bulky ligand including bis-indenyl, A is a leaving group, M is a transition metal and m and n are such that the total ligand valency corresponds to the transition metal valency and providing a support material having a bonding sequence selected from Si—O—Al—F, F—Si—O—Al, F—Si—O—Al—F and combinations thereof. The methods further include contacting the transition metal compound with the support material to form an active supported catalyst system, wherein the contact of the transition metal compound with the support material occurs in proximity to contact with monomer and contacting the active supported catalyst system with a plurality of monomers to form an olefin copolymer.
摘要翻译：共聚物和形成共聚物的方法在本文中描述。所述方法通常包括提供由式[L] M M [A] n N表示的过渡金属化合物，其中L是包含双茚基的体积大的配体，A是离去基团，M是过渡金属，m和n使得总配体价态对应于过渡金属价态，并提供具有选自Si-O-Al-F，F-Si-O -Al，F-Si-O-Al-F及其组合。所述方法还包括使过渡金属化合物与载体材料接触以形成活性负载催化剂体系，其中过渡金属化合物与载体材料的接触在与单体接触附近发生并与活性负载的催化剂体系接触多个的单体以形成烯烃共聚物。

54. 发明申请

US20070255021A1 Fluorinated Transition Metal Catalysts and Formation Thereof 审中-公开
标题翻译：氟化过渡金属催化剂及其形成
公开(公告)号：US20070255021A1
公开(公告)日：2007-11-01
申请号：US11740478
申请日：2007-04-26
申请人： Vladimir Marin , Margarito Lopez , Abbas Razavi , Tim Coffy
发明人： Vladimir Marin , Margarito Lopez , Abbas Razavi , Tim Coffy
IPC分类号： C08F4/44 , B01J31/00
CPC分类号： B01J21/12 , B01J37/26 , C08F10/00 , C08F10/06 , C08F110/06 , C08F210/06 , C08F2400/02 , C08F2/00 , C08F4/025 , C08F2500/20 , C08F2500/03 , C08F2500/12 , C08F210/14 , C08F2500/04 , C08F210/16
摘要： Supported catalyst systems, methods of forming the supported catalyst systems and polymerization processes including the supported catalyst systems are described herein. The methods generally include providing an inorganic support composition, wherein the inorganic support composition comprises aluminum, fluorine and silica and contacting the inorganic support composition with a transition metal compound to form a supported catalyst system, wherein the transition metal compound is represented by the formula [L]mM[A]n; wherein L is a bulky ligand, A is a leaving group, M is a transition metal and m and n are such that a total ligand valency corresponds to the transition metal valency. The methods further include contacting the inorganic support composition, the transition metal compound, the supported catalyst system or combinations thereof with at least one compound represented by the formula XRn, wherein X is selected from Group 12 to 13 metals, lanthanide series metals or combinations thereof and each R is independently selected from alkyls, alkoxys, aryls, aryloxys, halogens, hydrides, Group 1 or 2 metals, organic nitrogen compounds, organic phosphorous compounds and combinations thereof and n is from 2 to 5.
摘要翻译：本文描述了负载型催化剂体系，形成负载型催化剂体系的方法和包括负载型催化剂体系的聚合方法。所述方法通常包括提供无机载体组合物，其中无机载体组合物包含铝，氟和二氧化硅，并使无机载体组合物与过渡金属化合物接触以形成负载型催化剂体系，其中过渡金属化合物由式[ M] [A] n < 其中L是大体积配体，A是离去基团，M是过渡金属，m和n使总配体的化合价对应于过渡金属的价态。所述方法还包括使无机载体组合物，过渡金属化合物，负载型催化剂体系或其组合与至少一种由式XR n n表示的化合物接触，其中X选自第12至13族金属，镧系金属或其组合，每个R独立地选自烷基，烷氧基，芳基，芳氧基，卤素，氢化物，第1或2族金属，有机氮化合物，有机磷化合物及其组合，n为2至5 。

55. 发明申请

US20070043184A1 Bidentate catalyst for olefin polymerization, methods of forming such and products therefrom 失效
标题翻译：用于烯烃聚合的二齿催化剂，其形成方法及其产物
公开(公告)号：US20070043184A1
公开(公告)日：2007-02-22
申请号：US11206895
申请日：2005-08-18
申请人： Abbas Razavi , Vladimir Marin , Margarito Lopez
发明人： Abbas Razavi , Vladimir Marin , Margarito Lopez
IPC分类号： C08F4/44 , B01J31/00 , C08F110/06
CPC分类号： C08F10/00 , B01J31/1825 , B01J2231/122 , B01J2531/46 , B01J2531/48 , B01J2531/49 , C08F4/65912 , C08F4/65916 , C08F110/02 , C08F110/06 , C08F4/64048 , C08F4/659 , C08F2500/04 , C08F2500/15
摘要： Bidentate catalyst systems and the methods or forming such are described herein. The catalyst systems generally are compounds having the general formula: where R, R1, R2 and R3 are optional and independently selected from hydrogen, C1 to C20 alkyl groups or C6 to C20 aryl groups, A′ and A″ are independently selected from coordination groups, M is a Group 4 or 5 transition metal, X is selected from halogens, alkyl groups, aromatic groups or combinations thereof and n is less than 4.
摘要翻译：双齿催化剂体系和方法或形成方法在本文中描述。催化剂体系通常是具有以下通式的化合物：其中R 1，R 2，R 2和R 3是任选的，并且独立地选自氢，C 1至C 20烷基或C 6至C 20芳基，A'和A' 独立地选自配位基团，M为4或5族过渡金属，X选自卤素，烷基，芳基或其组合，n小于4。

56. 发明申请

US20070010640A1 Oligomerisation catalyst based upon an octanuclear nickel cluster 审中-公开
标题翻译：基于八核镍簇的低聚催化剂
公开(公告)号：US20070010640A1
公开(公告)日：2007-01-11
申请号：US10547953
申请日：2004-03-02
申请人： Abbas Razavi , Olivier Lavastre , Caroline Hillairet
发明人： Abbas Razavi , Olivier Lavastre , Caroline Hillairet
IPC分类号： B01J31/00 , C08F4/80 , C08F4/02
CPC分类号： B01J31/143 , B01J31/2208 , B01J31/2404 , B01J2231/12 , B01J2231/20 , B01J2531/0211 , B01J2531/847 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07C2531/30 , C08F110/02 , C08F110/06 , C08F110/08 , C07C11/02 , C08F2500/02
摘要： The present invention discloses a catalyst component based upon a Nib cluster made of two sheets each containing four nickel atoms and that is the reaction product of: a) a first component of the general formula (I) b) a second component based on complex, of the general formula (II) wherein in the first component, the benzene ring can be substituted in positions 3 and/or position and/or position 5 and/or position 6, wherein R and R′ are the same or different and can be selected from a phenyl, substituted or unsubstituted or a cycloalkyl or an alkyl having from 1 to 20 carbon atoms, wherein Q is a cation, and wherein, in the second component, R″ is selected from a halogen or an acetate and wherein the two arrows mean that there are two vacant sites. It also discloses a catalyst system and a process for the oligomerisation of olefins.
摘要翻译：本发明公开了一种催化剂组分，该催化剂组分基于由两个片材组成的每个包含四个镍原子的Nib簇，它是以下物质的反应产物：a）通式（I）的第一组分b）基于络合物的第二组分，通式（II）其中在第一组分中苯环可以在3位和/或位置和/或位置5和/或位置6上被取代，其中R和R'相同或不同并且可以是选自苯基，取代或未取代的或环烷基或具有1至20个碳原子的烷基，其中Q是阳离子，并且其中在第二组分中，R“选自卤素或乙酸酯，并且其中两个箭头意味着有两个空位。它还公开了一种催化剂体系和烯烃低聚方法。

57. 发明授权

US07081506B2 Ethylene polymerization employing bis-imino pyridinyl transition metal catalyst components 失效
标题翻译：使用双亚氨基吡啶基过渡金属催化剂组分的乙烯聚合
公开(公告)号：US07081506B2
公开(公告)日：2006-07-25
申请号：US10691809
申请日：2003-10-23
申请人： Abbas Razavi , Vladimir Marin , Margarito Lopez
发明人： Abbas Razavi , Vladimir Marin , Margarito Lopez
IPC分类号： C08F4/44 , B01J31/38
CPC分类号： C08F10/00 , C08F110/02 , C08F210/16 , C08F2410/04 , C08F2500/04 , C08F210/14 , C08F4/60089 , C08F4/7042
摘要： Ethylene polymerization processes employing bis-imino pyridinyl transition metal components which exhibit C2, C2v or Cs symmetry. Catalyst components of the same or different symmetries may be employed to control polymerization characteristics and characteristics of the resulting polymer products such as polymer yield and polymer molecular weight. The transition metal catalyst component is characterized by the formula: wherein M is a Group 4–11 transition metal, n is an integer within the range of 1–3, Q is a halogen or a C1–C2 alkyl group, and PY is a pyridinyl group which is coordinated with M through the nitrogen atom of the pyridinyl group. Further, with respect to formula (I), A is a methyl group, a phenyl group, or a substituted phenyl group and B1 and B2 are the same or different aromatic groups depending on the symmetry of the catalyst component. The catalyst component and an activating co-catalyst component are contacted with ethylene in a polymerization reaction zone which is free of hydrogen or contains hydrogen in an amount which is less than 5 mole % of the ethylene under polymerization conditions to produce a polymer product which can be a ethylene homopolymer or a copolymer of ethylene and C3+ alpha olefin, specifically an ethylene-propylene copolymer.
摘要翻译：使用显示C2，C2v或Cs对称性的双亚氨基吡啶基过渡金属组分的乙烯聚合方法。可以使用相同或不同对称性的催化剂组分来控制所得聚合物产物的聚合特性和特性，例如聚合物产率和聚合物分子量。过渡金属催化剂组分的特征在于下式：其中M是4-11族过渡金属，n是1〜3的整数，Q是卤素或C 1〜 C 2烷基，PY是通过吡啶基的氮原子与M配位的吡啶基。此外，关于式（I），A是甲基，苯基或取代的苯基，B 1和B 2 2是相同或不同的芳族基团取决于催化剂组分的对称性。催化剂组分和活化助催化剂组分在聚合反应区中与乙烯接触，所述聚合反应区在聚合条件下不含氢或含有小于乙烯5摩尔％的氢，以产生聚合物产物，是乙烯均聚物或乙烯和C 3 +α烯烃的共聚物，特别是乙烯 - 丙烯共聚物。

58. 发明申请

US20060100093A1 Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins 失效
标题翻译：催化剂组分，其制备方法及其作为烯烃聚合中催化剂组分的用途
公开(公告)号：US20060100093A1
公开(公告)日：2006-05-11
申请号：US11299564
申请日：2005-12-12
申请人： Abbas Razavi , Vladimir Marin , Margarito Lopez
发明人： Abbas Razavi , Vladimir Marin , Margarito Lopez
IPC分类号： B01J31/00
CPC分类号： B01J31/1815 , B01J2231/122 , B01J2531/842 , C07F15/025 , C08F10/00 , C08F110/02 , C08F2500/12 , C08F2500/04 , C08F2500/20 , C08F2500/19 , C08F2500/17 , C08F4/60089 , C08F4/7042
摘要： Catalyst compositions having Cs symmetry and processes utilizing Cs symmetric catalyst components for the polymerization of ethylenically unsaturated monomers to produce polymers, including copolymers or homopolymers. Monomers, which are polymerized or copolymerized include ethylene, C3+ alpha olefins and substituted vinyl compounds, such as styrene and vinyl chloride. The catalyst component is characterized by the formula: wherein M is a Group 4-11 transition metal, n is an integer of from 1-3, Q is halogen or a C1-C2 alkyl group, PY is a pyridinyl group, R′ and R″ are each C1-C20 hydrocarbyl group, A1 is a mononuclear aromatic group, and A2 is a polynuclear aromatic group, such as a terphenyl group. The catalyst component is used with an activating co-catalyst component such as an alumoxane. Also disclosed is a process for the preparation of a pyridinyl-linked bis-amino ligand suitable for use in forming the catalyst component.
摘要翻译：具有Cs对称性的催化剂组合物和利用Cs对称催化剂组分用于烯键式不饱和单体聚合以产生聚合物（包括共聚物或均聚物）的方法。聚合或共聚的单体包括乙烯，C 3 +α烯烃和取代的乙烯基化合物，例如苯乙烯和氯乙烯。催化剂组分的特征在于下式：其中M是4-11族过渡金属，n是1-3的整数，Q是卤素或C 1 -C 2 烷基，PY是吡啶基，R'和R“各自为C 1 -C 20烃基，A 1， SUB>是单核芳族基团，并且A 2是多核芳族基团，例如三联苯基。催化剂组分与活化助催化剂组分如铝氧烷一起使用。还公开了制备适于用于形成催化剂组分的吡啶基连接的双 - 氨基配体的方法。

59. 发明申请

US20050119425A1 Catalyst system comprising a mixture of catalyst components for producing a polyolefin blend 失效
标题翻译：包含用于生产聚烯烃共混物的催化剂组分的混合物的催化剂体系
公开(公告)号：US20050119425A1
公开(公告)日：2005-06-02
申请号：US10491360
申请日：2002-09-26
申请人： Abbas Razavi
发明人： Abbas Razavi
IPC分类号： C08F4/605 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F4/44 , B01J31/00
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F110/06 , C08F4/65904 , C08F2500/16 , C08F2500/15
摘要： Provided is a catalyst system for producing a polyolefin blend, which catalyst system comprises a mixture including the following catalyst components: i) a catalyst component A capable of producing an isotactic olefin polymer, and/or a catalyst component A′ capable of producing a polymer comprising an isotactic polyolefin block; and ii) a catalyst component B capable of producing a syndiotactic polyolefin, and/or a catalyst component B′ capable of producing a polymer comprising a syndiotactic polyolefin block; wherein each of the components in the catalyst system is distinct from the other components in the catalyst system.
摘要翻译：提供了一种用于生产聚烯烃共混物的催化剂体系，该催化剂体系包括包含以下催化剂组分的混合物：i）能够生产全同立构烯烃聚合物的催化剂组分A和/或能够生产聚合物的催化剂组分A' 包括全同立构聚烯烃嵌段; 和ii）能够制备间同立构聚烯烃的催化剂组分B和/或能够制备包含间同立构聚烯烃嵌段的聚合物的催化剂组分B' 其中催化剂体系中的每个组分与催化剂体系中的其它组分不同。

60. 发明授权

US06630546B1 Process for the preparation of a polyolefin 失效
标题翻译：制备聚烯烃的方法
公开(公告)号：US06630546B1
公开(公告)日：2003-10-07
申请号：US10104745
申请日：2002-03-22
申请人： Abbas Razavi , Liliane Peters
发明人： Abbas Razavi , Liliane Peters
IPC分类号： C08F444
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F10/00 , C08F10/02 , C08F110/02 , Y10S526/905 , Y10S526/943 , C08F4/65927 , C08F2500/12 , C08F2500/19 , C08F210/14 , C08F2500/08 , C08F2500/18
摘要： Use of a catalyst system comprising a metallocene catalyst component of general formula R″(CpRm) (Cp′R′n)MQ2 supported on an inert support in the slurry phase production of linear low density polyolefin, wherein Cp is a cyclopentadienyl moiety, Cp′ is a substituted or unsubstituted fluorenyl ring; R″ is a structural bridge imparting stereorigidity to the component; each R is independently hydrogen or hydrocarbyl having 1 to 20 carbon atoms in which 0≦m≦4; each R′ is independently hydrocarbyl having 1 to 20 carbon atoms in which 0≦n≦B; M is a Group IVB transition metal or vanadium; and each Q is hydrocarbyl having 1 to 20 carbon atoms or halogen; the metallocene having a centroid-M-centroid angle in the range 105° to 125°.
摘要翻译：在线性低密度聚烯烃的浆料相中制备包括负载在惰性载体上的通式R“（CpRm）（Cp'R'n）MQ2的茂金属催化剂组分的催化剂体系的用途，其中Cp是环戊二烯基部分， Cp'是取代或未取代的芴基环; R“是赋予组分立体刚性的结构桥; 每个R独立地是氢或具有1至20个碳原子的烃基，其中0≤m≤4; 每个R'独立地为具有1至20个碳原子的烃基，其中0≤n≤B; M是IVB族过渡金属或钒; 并且每个Q是具有1至20个碳原子的烃基或卤素; 茂金属具有在105°至125°范围内的质心M-心形角。

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