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51. 发明授权

US07388018B2 4-Piridinylmethylsulphonamide derivatives as fungicidal plant protein agents 失效
标题翻译： 4-吡啶基甲基磺酰胺衍生物作为杀真菌植物蛋白剂
公开(公告)号：US07388018B2
公开(公告)日：2008-06-17
申请号：US10570893
申请日：2004-09-10
申请人： Wassilios Grammenos , Carsten Blettner , Bernd Müller , Markus Gewehr , Jordi Tormo i Blasco , Thomas Grote , Joachim Rheinheimer , Peter Schäfer , Frank Schieweck , Anja Schwögler , Oliver Wagner , Norbert Götz , Siegfried Strathmann , Ulrich Schöfl , Maria Scherer , Reinhard Stierl
发明人： Wassilios Grammenos , Carsten Blettner , Bernd Müller , Markus Gewehr , Jordi Tormo i Blasco , Thomas Grote , Joachim Rheinheimer , Peter Schäfer , Frank Schieweck , Anja Schwögler , Oliver Wagner , Norbert Götz , Siegfried Strathmann , Ulrich Schöfl , Maria Scherer , Reinhard Stierl
IPC分类号： A61K31/541 , A61K31/496 , C07D417/02 , C07D403/02
CPC分类号： C04B35/632 , C07D213/42 , C07D215/12 , C07D401/12 , C07D409/12
摘要： Sulfonamides of the formula I where the substituents are as follows: R1 is hydrogen, alkyl, alkoxy, alkenyl or alkynyl; and R2, R3, R4, R5 are hydrogen, halogen, alkyl, alkoxy or halomethyl; R2 and R3 together may also form a phenyl, cyclopentyl or cyclohexyl ring, it being possible for these rings to carry two groups R2, and R3, R2, R3, are hydrogen, halogen, alkyl, alkoxy or halomethyl; in case a), if R2, R3, R4 and R5 are hydrogen: X is phenyl substituted by a group —C(R6)═NOR7, where R6 is alkyl and R7 is alkyl, benzyl, alkenyl, haloalkyl, haloalkenyl, alkynyl or haloalkynyl; and in case b), if at least one of the groups R2, R3, R4 and R5 is not hydrogen: X is phenyl, naphthyl or a five- or six-membered saturated, or partially unsaturated or aromatic heterocycle which is attached via a carbon atom and contains one to four heteroatoms from the group consisting of O, N and S, where X may be substituted according to the description; Processes for preparing these compounds, compositions comprising them and their use for controlling phytopathogenic harmful fungi.
摘要翻译：式I的磺酰胺，其中取代基如下：R 1是氢，烷基，烷氧基，烯基或炔基; R 2，R 3，R 4，R 5是氢，卤素，烷基，烷氧基或卤代甲基 ; R 2和R 3一起也可以形成苯基，环戊基或环己基环，这些环可以携带两个基团R 2， R 3，R 2，R 3，R 3，R 3，R 3，R 3，R 3，R 3，R 3，R 3，在a）情况下，如果R 2，R 3，R 4和R 5是氢：X是由基团-C（R 6） - NOR 7取代的苯基，其中R 6为烷基，R 7为H 烷基，苄基，烯基，卤代烷基，卤代烯基，炔基或卤代炔基; 并且在情况b）中，如果R 2，R 3，R 4和R 5中的至少一个， SUP>不是氢：X是苯基，萘基或五或六元饱和或部分不饱和或芳族杂环，其通过碳原子连接并含有一至四个由O，N和S组成的组的杂原子，其中X可以根据描述被替代; 制备这些化合物的方法，包含它们的组合物及其用于控制植物病原性有害真菌的用途。

52. 发明申请

US20060264446A1 6-Halogeno-[1,2,4]triazolo[1,5-a]pyrimidines for combating animal pests 有权
标题翻译： 6-卤代 - [1,2,4]三唑并[1,5-a]嘧啶，用于对抗动物害虫
公开(公告)号：US20060264446A1
公开(公告)日：2006-11-23
申请号：US10570854
申请日：2004-09-10
申请人： Ernst Baumann , Thomas Grote , Frank Schieweck , Wolfgang Deyn , Norbert Götz , Michael Hofmann , Markus Kordes , Michael Puhl , Michael Rack , Thomas Schmidt , Toni Bucci , Henry Cotter , Deborah Culbertson , Hassan Oloumi-Sadeghi
发明人： Ernst Baumann , Thomas Grote , Frank Schieweck , Wolfgang Deyn , Norbert Götz , Michael Hofmann , Markus Kordes , Michael Puhl , Michael Rack , Thomas Schmidt , Toni Bucci , Henry Cotter , Deborah Culbertson , Hassan Oloumi-Sadeghi
IPC分类号： A01N43/90
CPC分类号： C07D487/04 , A01N43/90
摘要： The present invention relates to a method of combating animal pests which comprises contacting the animal pests, their habit, breeding ground, food supply, plant, seed, soil, area, material or environment in which the animal pests are growing or may grow, or the materials, plants, seeds, soils, surfaces or spaces to be protected from animal attack or infestation with a pesticidally effective amount of at least one 6-halogeno[1,2,4]triazolo[1,5-a]-pyrimidine of the general formula (I), wherein X, R1, R2, R3 and R4 are as defined in claim 1 and/or the agriculturally useful salts thereof.
摘要翻译：本发明涉及一种对抗动物害虫的方法，其包括使动物害虫，其习惯，繁殖地，食物供应，植物，种子，土壤，面积，材料或动物害虫生长或可能生长的环境接触;或要防止动物攻击或侵染的材料，植物，种子，土壤，表面或空间，用杀虫有效量的至少一种6-卤代[1,2,4]三唑并[1,5-a] - 嘧啶通式（I）其中X，R 1，R 2，R 3和R 4均为如权利要求1所定义，和/或其农业上有用的盐。

53. 发明授权

US06888003B2 Method for producing 7-(pyrazole-3-yl) benzoxazoles 失效
标题翻译： 7-（吡唑-3-基）苯并恶唑的制备方法
公开(公告)号：US06888003B2
公开(公告)日：2005-05-03
申请号：US10221206
申请日：2001-03-15
申请人： Cyrill Zagar , Robert Reinhard , Michael Puhl , Thorsten Volk , Norbert Götz , Gerhard Hamprecht , Olaf Menke , Ingo Sagasser
发明人： Cyrill Zagar , Robert Reinhard , Michael Puhl , Thorsten Volk , Norbert Götz , Gerhard Hamprecht , Olaf Menke , Ingo Sagasser
IPC分类号： C07D231/12 , A01N43/56 , A01N43/76 , C07B61/00 , C07D231/16 , C07D231/18 , C07D413/04 , C07D413/14 , C07D498/00
CPC分类号： C07D413/04 , A01N43/56
摘要： A process for preparing 7-(pyrazol-3-yl)benzoxazoles of the formula I in which the variables R1-R6 are as defined in claim 1, which process is characterized in that a 2-halo-3-(pyrazol-3-yl)anilide of the formula II, in which X is bromine or iodine is reacted with a base in the presence of a transition metal compound of subgroup VIIa, VIIIa or Ib of the Periodic Table of the Elements, is disclosed.
摘要翻译：制备其中变量R 1〜6的定义的式I的7-（吡唑-3-基）苯并恶唑的方法如权利要求1所定义，该方法其特征在于式Ⅱ的2-卤代-3-（吡唑-3-基）酰苯胺，其中X是溴或碘，在Ⅶa族，Ⅷa族或Ⅷa族过渡金属化合物存在下与碱反应公开了元素周期表的Ib。

54. 发明授权

US06696607B2 Use of phenethyl acrylamides, novel phenethyl acrylamides, method for the production thereof and agents containing the same 失效
标题翻译：使用苯乙基丙烯酰胺，新型苯乙基丙烯酰胺，其制备方法和含有它们的试剂
公开(公告)号：US06696607B2
公开(公告)日：2004-02-24
申请号：US10297287
申请日：2002-12-04
申请人： Wassilios Grammenos , Hubert Sauter , Oliver Cullmann , Markus Gewehr , Bernd Müller , Jordi Tormo i Blasco , Norbert Götz , Thorsten Volk , Gisela Lorenz , Eberhard Ammermann , Reinhard Stierl , Siegfried Strathmann
发明人： Wassilios Grammenos , Hubert Sauter , Oliver Cullmann , Markus Gewehr , Bernd Müller , Jordi Tormo i Blasco , Norbert Götz , Thorsten Volk , Gisela Lorenz , Eberhard Ammermann , Reinhard Stierl , Siegfried Strathmann
IPC分类号： C07C23309
CPC分类号： A01N37/36 , A01N37/18 , A01N37/38 , C07C231/02 , C07C233/22
摘要： Use of phenethylacrylamides of the formula I: in which the substituents have the following meanings: X is halogen, alkyl, haloalkyl, alkoxy, haloalkoxy and —O—C(Ra,Rb)—C≡C—R6; Ra,Rb and Rc have the meanings given in the description; m,n independently of one another are 1 to 4, it being possible for the radicals X or Y to be different if m or n is greater than 1; Y is halogen, nitro, cyano, alkyl, CF3, alkoxy and phenyl; R1,R2 independently of one another are hydrogen, halogen, alkyl, alkoxy, haloalkoxy and CF3; R3,R4,R5,R6 independently of one another are hydrogen, halogen, alkyl, alkoxy, or R3 and R4 together form a cyclopropyl ring, it being possible for the C—R5— and C—R6 bonds can be in the E- or Z-position relative to each other; for controlling phytopathogenic fungal pests, novel phenethylacrylamides, their preparation, and compositions comprising them.
摘要翻译：使用式I的苯乙基丙烯酰胺：其中取代基具有以下含义：X是卤素，烷基，卤代烷基，烷氧基，卤代烷氧基和-OC（R a，R b）-C = CR 6; R a，R b和R c具有说明书中给出的含义; m，n彼此独立地为1至4，如果m或n可以使基团X或Y不同大于1; Y是卤素，硝基，氰基，烷基，CF 3，烷氧基和苯基; R 1，R 2彼此独立地是氢，卤素，烷基，烷氧基，卤代烷氧基和CF 3; R 3 R 4，R 5，R 6彼此独立地是氢，卤素，烷基，烷氧基或R 3和R 4一起形成环丙基环，其中CR <5> - 和CR 6键可以相对于彼此位于E-或Z-位;用于控制植物病原性真菌害虫，新型苯乙基丙烯酰胺，它们的制备和包含它们的组合物。

55. 发明授权

US06600071B2 Method for producing 1-substituted 5-hydroxpyrazoles 失效
标题翻译： 1-取代的5-羟基吡唑的制备方法
公开(公告)号：US06600071B2
公开(公告)日：2003-07-29
申请号：US10228373
申请日：2002-08-27
申请人： Norbert Götz , Roland Götz , Michael Rack
发明人： Norbert Götz , Roland Götz , Michael Rack
IPC分类号： C07C24330
CPC分类号： C07C243/30 , C07D231/20
摘要： A process for preparing compounds of the formula I in which R1 is hydrogen, an aliphatic group having 1-8 carbon atoms, Cl-C6-alkoxycarbonyl, Cl-C6-alkylthiocarbonyl or a cyclic ring system having 3-14 ring atoms, and R2 is hydrogen, an aliphatic group having 1-8 carbon atoms, or R1 and R2 together with the carbon atom to which they are bound form a cyclic or bicyclic ring system having 3-14 ring atoms, comprises the preparation of compounds of the formula II in which R3 and R4 are readily detachable groups and R1 and R2 are as defined above, as starting materials or intermediates and the cyclization of these under suitable reaction conditions to give compounds of the formula I. The intermediates of the formula II are novel.
摘要翻译：制备式Iin的化合物的方法，其中R1是氢，具有1-8个碳原子的脂族基团，C1-C6-烷氧基羰基，C1-C6-烷硫基羰基或具有3-14个环原子的环状体系，R2是氢，具有1-8个碳原子的脂族基团，或者R1和R2与它们所连接的碳原子一起形成具有3-14个环原子的环状或双环体系，包括制备式II化合物，其中式 R3和R4是容易拆分的基团，R1和R2如上所定义，作为原料或中间体，并在合适的反应条件下环化，得到式I化合物。式II的中间体是新的。

56. 发明授权

US06417388B1 Method for producing alkenyl-substituted bis(oxime ether) derivatives 失效
标题翻译：烯基取代的双（肟醚）衍生物的制备方法
公开(公告)号：US06417388B1
公开(公告)日：2002-07-09
申请号：US09831412
申请日：2001-05-09
申请人： Wassilios Grammenos , Hubert Sauter , Andreas Gypser , Herbert Bayer , Norbert Götz , Roland Götz
发明人： Wassilios Grammenos , Hubert Sauter , Andreas Gypser , Herbert Bayer , Norbert Götz , Roland Götz
IPC分类号： C07C22900
CPC分类号： C07C249/12 , C07C251/60
摘要： The process for preparing alkenyl-substituted bis(oxime ether) derivatives of the formula I where: R1 is unsubstituted C1-C4-alkyl or C2-C4-alkenyl-, C2-C4-alkynyl- or phenyl-substituted methyl; R2, R4 independently of one another are hydrogen or methyl; R3, R5 independently of one another are hydrogen or C1-C4-alkyl, trifluoromethyl or phenyl and X is —C(═CHCH3)—COOCH3, —C(═CHOCH3)—COOCH3, —C(═NOCH3)—COOCH3, —C(═NOCH3)—CONHCH3 or —N(OCH3)—COOCH3, and intermediates which are obtainable by this process are described. Alkenyl-substituted bis(oxime ether) derivatives of the formula I are described in the literature as interesting crop protection agents.
摘要翻译：制备式I的烯基取代的双（肟醚）衍生物的方法，其中：R1是未取代的C1-C4-烷基或C2-C4-烯基 - ，C2-C4-炔基或苯基取代的甲基; R2，R4独立地其中R 3，R 5彼此独立地是氢或C 1 -C 4烷基，三氟甲基或苯基，X是-C（= CHCH 3）-COOCH 3，-C（= CHOCH 3）-COOCH 3，-C（ = NOCH 3）-COOCH 3，-C（= NOCH 3）-CONHCH 3或-N（OCH 3）-COOCH 3，并且可以通过该方法获得的中间体。式I的烯基取代的双（肟醚）衍生物在文献中描述为有趣的作物保护剂。

57. 发明授权

US06329530B1 Method for the production of 1-substituted 5-hydroxypyrazoles 失效
标题翻译： 1-取代的5-羟基吡唑的制备方法
公开(公告)号：US06329530B1
公开(公告)日：2001-12-11
申请号：US09830948
申请日：2001-05-03
申请人： Volker Maywald , Adrian Steinmetz , Michael Rack , Norbert Götz , Roland Götz , Jochem Henkelmann , Heike Becker , Juan Jose Aiscar Bayeto
发明人： Volker Maywald , Adrian Steinmetz , Michael Rack , Norbert Götz , Roland Götz , Jochem Henkelmann , Heike Becker , Juan Jose Aiscar Bayeto
IPC分类号： C07D23120
CPC分类号： C07D231/20
摘要： The invention relates to a method for the production of 1-substituted 5-hydroxypyrazoles of formula (I) wherein R1 is C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkinyl, C3-C6-cycloalkyl or C1-C4-alkoxy, whereby these groups can be substituted by halogen, C1-C4-alkoxy, phenoxy, C1-C6-alkoxycarbonyl, C1-C6-alkylthiocarbonyl or a cyclic ring system with 3-14 ring atoms, by reacting a) an alkylvinylether of general formula (III) wherein R2 is C1-C6-alkyl or C3-C6-cycloalkyl, with phosgene (IVa), “diphosgene” (IVb) or “triphosgene” (IVc) to form acid chlorides of formula (V), b) transforming said acid chlorides by eliminating hydrogen chloride into the corresponding 3-alkoxyacrylic acid chloride of formula (VI) and c) reacting said acid chloride with hydrazines of formula (VII) wherein R1 has the above cited meaning, to form 5-hydroxypyrazoles of formula (I).
摘要翻译：本发明涉及制备式（I）的1-取代的5-羟基吡唑的方法，其中R1是C1-C6-烷基，C2-C6-烯基，C2-C6-炔基，C3-C6-环烷基或C1- C4烷氧基，其中这些基团可以被卤素，C 1 -C 4 - 烷氧基，苯氧基，C 1 -C 6 - 烷氧基羰基，C 1 -C 6烷硫基羰基或具有3-14个环原子的环状体系取代，通过使a）烷基乙烯基醚（IVa），“二光气”（IVb）或“三光气”（IVc））中形成式（V）的酰氯的通式（III）的化合物，其中R2为C1-C6-烷基或C3-C6- b）通过将氯化氢除去相应的式（VI）的3-烷氧基丙烯酰氯，并且c）使所述酰氯与式（Ⅶ）的肼反应，其中R 1具有上述含义，形成5-羟基吡唑的式（I）化合物。

58. 发明授权

US08232421B2 Bifunctional phenyl ISO (THIO) cyanates, processes and intermediates for their preparation 有权
标题翻译：双官能苯基ISO（THIO）氰酸酯，其制备方法和中间体
公开(公告)号：US08232421B2
公开(公告)日：2012-07-31
申请号：US12886986
申请日：2010-09-21
申请人： Gerhard Hamprecht , Michael Puhl , Bernd Wolf , Norbert Götz , Michael Keil , Robert Reinhard , Ingo Sagasser , Werner Seitz
发明人： Gerhard Hamprecht , Michael Puhl , Bernd Wolf , Norbert Götz , Michael Keil , Robert Reinhard , Ingo Sagasser , Werner Seitz
IPC分类号： C07C263/10 , C07C249/14 , C07C331/28 , C07C265/12 , C07D249/12
CPC分类号： C07D213/76 , C07C303/34 , C07C307/06 , C07C331/28 , C07C2601/14 , C07D207/20 , C07D211/18 , C07D211/70 , C07D295/26 , C07D307/52 , C07D319/06 , C07D333/20
摘要： A process for preparing phenyl iso(thio)cyanates of the formula I in which a compound of the formula II or its HCl adduct is reacted with a phosgenating agent where W is oxygen or sulfur and Ar and A are as defined in claim 1 is described. Moreover, the invention relates to the use of the phenyl iso(thio)cyanates for preparing crop protection agents.
摘要翻译：描述式I的苯基异（硫代）氰酸酯的方法，其中将式II化合物或其HCl加合物与W是氧或硫的光气反应剂和Ar和A如权利要求1中所定义的相同。此外，本发明涉及苯基异（硫代）氰酸酯用于制备作物保护剂的用途。

59. 发明授权

US07687632B2 Process for the preparation of pyridine derivatives 有权
标题翻译：吡啶衍生物的制备方法
公开(公告)号：US07687632B2
公开(公告)日：2010-03-30
申请号：US10584354
申请日：2004-12-22
申请人： Joachim Gebhardt , Norbert Götz , Hagen Jaedicke , Guido Mayer , Michael Rack
发明人： Joachim Gebhardt , Norbert Götz , Hagen Jaedicke , Guido Mayer , Michael Rack
IPC分类号： C07D211/72 , C07F9/02
CPC分类号： C07C323/60 , C07D213/64 , C07D213/71 , C07F9/4006
摘要： Process for the preparation of substituted pyridine derivatives of formula (I) comprising reaction of a α-β-unsaturated carbonyl compound of formula (II) R3—C(O)—C(R1)═C(R2)-G with a Wittig reagent or Horner-Wadsworth-Emmons reagent in the presence of a base and optionally subsequent cyclization.
摘要翻译：制备式（I）的取代的吡啶衍生物的方法，包括式（II）的R 3 -C（O）-C（R 1）= C（R 2）-G的α-和bgr-不饱和羰基化合物与 Wittig试剂或Horner-Wadsworth-Emmons试剂在碱的存在下和任选地随后的环化。

60. 发明授权

US07608742B2 Diarylphenoxy aluminum compounds 有权
标题翻译：二芳基苯氧基铝化合物
公开(公告)号：US07608742B2
公开(公告)日：2009-10-27
申请号：US11817468
申请日：2006-03-03
申请人： Marko Friedrich , Klaus Ebel , Norbert Götz , Wolfgang Krause , Christian Zahm
发明人： Marko Friedrich , Klaus Ebel , Norbert Götz , Wolfgang Krause , Christian Zahm
IPC分类号： C07C35/08 , C07F5/06
CPC分类号： C07F5/069
摘要： The present invention relates to diarylphenoxyaluminum compounds which are obtainable by reacting a bis(diarylphenol) ligand of the formula (I) with an alkylaluminum compound and/or a complex aluminum hydride. The invention moreover relates to the use of such diarylphenoxyaluminum compounds as catalysts.Moreover, the invention relates to a method of producing isopulegol by cyclization of citronellal in the presence of diarylphenoxyaluminum compounds as catalysts.The invention also relates to a method of producing menthol by cyclization of citronellal in the presence of diarylphenoxyaluminum compounds as catalysts and subsequent hydrogenation.
摘要翻译：本发明涉及通过使式（I）的双（二芳基苯酚）配体与烷基铝化合物和/或络合氢化铝反应得到的二芳基苯氧基铝化合物。本发明还涉及这种二芳基苯氧基铝化合物作为催化剂的用途。此外，本发明涉及通过在二芳基苯氧基铝化合物作为催化剂的存在下环绕香茅醛来生产异ule醇的方法。本发明还涉及在二芳基苯氧基铝化合物作为催化剂和随后的氢化存在下，通过香茅醛环化生产薄荷醇的方法。

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