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51. 发明授权

US5529963A Process for the regeneration of a deactivated, carbon-covered, fine-grained, heat-resistant catalyst 失效
标题翻译：钝化，碳覆盖，细粒度，耐热催化剂的再生方法
公开(公告)号：US5529963A
公开(公告)日：1996-06-25
申请号：US217865
申请日：1994-03-25
申请人： Dietrich Maschmeyer
发明人： Dietrich Maschmeyer
IPC分类号： B01J23/94 , B01J38/30 , B01J20/34
CPC分类号： B01J23/94 , B01J38/30
摘要： The invention relates to a process for the regeneration of a deactivated, carbon-covered, fine-grained, heat-resistant catalyst, a pumpable suspension of deactivated catalyst being injected into a hot gas stream and the regenerated catalyst then being separated off from the gas stream.
摘要翻译：本发明涉及一种用于再生失活的，覆盖碳的细粒的耐热催化剂的方法，将失活的催化剂的可泵送悬浮液注入热气流中，再生的催化剂然后与气体分离流。

52. 发明授权

US07294741B2 Process for the production of acrylic acid 有权
标题翻译：丙烯酸生产工艺
公开(公告)号：US07294741B2
公开(公告)日：2007-11-13
申请号：US10498852
申请日：2002-12-13
申请人： Gunther Bub , Jurgen Mosler , Dietrich Maschmeyer , Andreas Sabbagh , Roland Fornika , Matthias Peuckert
发明人： Gunther Bub , Jurgen Mosler , Dietrich Maschmeyer , Andreas Sabbagh , Roland Fornika , Matthias Peuckert
IPC分类号： C07C51/16
CPC分类号： C07C51/252 , C07C57/04
摘要： The present invention relates to a process for the production of acrylic acid (AA) comprising the steps wherein: a) a 1st gas mixture comprising propylene, oxygen, an inert gas and steam is subjected to a 1st catalytic oxidation reaction stage thereby converting the propylene in the presence of a catalyst mainly into acrolein being contained in a 2nd gas mixture from said 1st catalytic oxidation reaction, b) said 2nd gas mixture from the 1st catalytic oxidation reaction stage is subjected to a 2nd catalytic oxidation reaction stage thereby converting the acrolein in the presence of a catalyst mainly into AA, being contained in a product gas, c) said product gas is subjected to a quench tower, wherein said AA is recovered as an aqueous solution comprising said AA being contained in the process water, wherein a process vent gas is obtained at the top of said quench tower, wherein, said 1st gas mixture has a steam/propylene ratio of >0.3 and
摘要翻译：本发明涉及一种生产丙烯酸（AA）的方法，包括以下步骤：a）将包含丙烯，氧气，惰性气体和蒸汽的第一气体混合物进行第一催化氧化反应阶段，由此将丙烯在主催化剂存在下，由所述第一催化氧化反应产生的第二气体混合物中含有丙烯醛，b）将来自第一催化氧化反应阶段的所述第二气体混合物进行第二催化氧化反应阶段，由此将丙烯醛转化为催化剂主要以AA形式存在于产物气体中，c）将所述产物气体进行骤冷塔，其中所述AA作为包含所述AA的水溶液被回收，所述水溶液包含在工艺用水中，其中过程在所述骤冷塔的顶部获得排出气体，其中所述第一气体混合物具有> 0.3和<2的蒸汽/丙烯比，并且所述处理水的量为 s或等于从骤冷塔抽出的所述水溶液中的水量。

53. 发明授权

US06881700B2 Dealuminized catalyst carrier, method of production, and method for hydrating C2 or C3 olefins with water 有权
标题翻译：脱色催化剂载体，生产方法，以及用水将C2或C3烯烃水合的方法
公开(公告)号：US06881700B2
公开(公告)日：2005-04-19
申请号：US10634879
申请日：2003-08-06
申请人： Michael Sakuth , Dietrich Maschmeyer , Gregor Lohrengel , Guido Stochniol
发明人： Michael Sakuth , Dietrich Maschmeyer , Gregor Lohrengel , Guido Stochniol
IPC分类号： B01J21/16 , B01J27/16 , B01J37/00 , C07C29/04 , C07C29/08 , C07C31/08 , B01J21/08
CPC分类号： C12C11/02 , B01J21/16 , B01J27/16 , C07C29/08 , C07C31/08 , C07C31/10
摘要： A catalyst support comprising silicates is described. This catalyst support has a lower aluminum content than naturally occurring sheet silicates and can be used in the hydration of C2 and C3 olefins to produce C2 and C3 alcohols. A method for the production of the catalyst support and a process for hydrating C2 and C3 olefins are also described. One advantage of this catalyst support is the reduction in aluminum leaching that occurs when this catalyst is used in the presence of phosphoric acid.
摘要翻译：描述了包含硅酸盐的催化剂载体。该催化剂载体的铝含量比天然存在的片状硅酸盐低，可用于C 2 O 3和C 3 O 3烯烃的水合以产生C 2 SUB和C 3醇。还描述了制备催化剂载体的方法和水合C 2和C 3 O 3烯烃的方法。该催化剂载体的一个优点是当在磷酸存在下使用该催化剂时，铝浸出的减少。

54. 发明授权

US06881699B1 Method for producing a dealuminized catalyst support 有权
标题翻译：脱铝催化剂载体的制造方法
公开(公告)号：US06881699B1
公开(公告)日：2005-04-19
申请号：US09701054
申请日：1999-07-01
申请人： Michael Sakuth , Gregor Lohrengel , Dietrich Maschmeyer , Guido Stochniol
发明人： Michael Sakuth , Gregor Lohrengel , Dietrich Maschmeyer , Guido Stochniol
IPC分类号： B01J21/16 , B01J27/16 , B01J37/00 , C07C29/04 , C07C29/08 , C07C31/08 , B01J27/182
CPC分类号： C12C11/02 , B01J21/16 , B01J27/16 , C07C29/08 , C07C31/08 , C07C31/10
摘要： What is claimed is a dealuminated catalyst carrier, a process for producing a catalyst carrier with reduced aluminum content based on naturally occurring lattice-layer silicates, such as, for example, montmorillonite, as well as a process for the hydration reaction of C2- or C3-olefins in which said catalyst carrier with reduced aluminium content is used. For acid-catalysed hydration reaction the catalyst carrier is impregnated with phosphoric acid. The improvements according to the invention of the hydration reaction compared to conventional processes include the fact that no aluminium is leached out of the carrier in the presence of the phosphoric acid. As a result no more blockage of the succeeding apparatus due to aluminium phosphate is expected.
摘要翻译：所要求的是脱铝催化剂载体，基于天然存在的格子层硅酸盐（例如蒙脱石）制备具有降低的铝含量的催化剂载体的方法，以及C 其中使用具有降低的铝含量的所述催化剂载体的2- 2 - 或C 3 - 烯烃。对于酸催化的水合反应，催化剂载体用磷酸浸渍。根据本发明的水合反应与常规方法相比的改进包括在磷酸存在下不将铝从载体中浸出的事实。因此，预计不会因为磷酸铝而导致后续装置的堵塞。

55. 发明授权

US5660807A Process for the removal of HCN from gas mixtures 失效
标题翻译：从气体混合物中除去HCN的方法
公开(公告)号：US5660807A
公开(公告)日：1997-08-26
申请号：US553588
申请日：1996-05-13
申请人： Wolfgang Forg , Gerhard Ranke , Michael Heisel , Dietrich Maschmeyer , Robert Walter
发明人： Wolfgang Forg , Gerhard Ranke , Michael Heisel , Dietrich Maschmeyer , Robert Walter
IPC分类号： B01D53/86 , B01J23/26 , C01B3/58 , C10K1/34 , B01D53/42
CPC分类号： B01J23/26 , B01D53/8603 , B01D53/8621 , C01B3/58 , C10K1/34 , B01D2257/308 , B01D2257/408 , C01B2203/045 , C01B2203/0465 , C01B2203/0475 , C01B2203/0485
摘要： The invention relates to a process for the removal of HCN from gas mixtures that contain at least HCN and sulfur compounds, especially from gas mixtures that are obtained by partial oxidation of hydrocarbons, by catalytic decomposition of HCN, as well as a catalyst for the decomposition of HCN. According to the invention, the gas mixture is brought into contact with a catalyst which decomposes the HCN by hydrogenation and/or by hydrolysis and COS that is contained in the gas mixture is decomposed at least partially in this catalyst by hydrolysis. Advantageously, a catalyst that is based on titanium oxide and/or zirconium oxide as a vehicle and that contains chromium oxide as an active component is used. Advantageously, the catalyst is reduced during catalyst production or before use with H.sub.2 and/or a reducing gas at temperatures above the operating temperature of catalytic decomposition.
摘要翻译： PCT No.PCT / EP94 / 01646 Sec。 371日期：1996年5月13日 102（e）日期1996年5月13日PCT提交1994年5月20日PCT公布。出版物WO94 / 29004 日期1994年12月22日本发明涉及从气体混合物中除去HCN的方法，所述气体混合物至少含有HCN和硫化合物，特别是通过烃的部分氧化获得的气体混合物，HCN的催化分解以及用于分解HCN的催化剂。根据本发明，使气体混合物与通过氢化和/或水解分解HCN的催化剂接触，并且气体混合物中包含的COS至少部分地通过水解在该催化剂中分解。有利地，使用基于氧化钛和/或氧化锆作为载体并且含有氧化铬作为活性组分的催化剂。有利地，催化剂在催化剂生产期间或在高于催化分解操作温度的温度下用H2和/或还原气体使用之前被还原。

56. 发明授权

US09914681B2 Preparation of high-quality oxo process alcohols from inconstant raw material sources 有权
公开(公告)号：US09914681B2
公开(公告)日：2018-03-13
申请号：US14717183
申请日：2015-05-20
申请人： Frank Geilen , Katrin Marie Dyballa , Dieter Hess , Stephan Peitz , Robert Franke , Dirk Fridag , Dietrich Maschmeyer , Helene Reeker , Guido Stochniol
发明人： Frank Geilen , Katrin Marie Dyballa , Dieter Hess , Stephan Peitz , Robert Franke , Dirk Fridag , Dietrich Maschmeyer , Helene Reeker , Guido Stochniol
IPC分类号： C07C29/14 , C07C45/50 , C07C2/24 , C07C67/08 , C07C69/80 , C08K5/12 , B01J31/18 , C07C29/141
CPC分类号： C07C29/14 , B01J31/185 , B01J31/1885 , C07C2/24 , C07C29/141 , C07C45/50 , C07C67/08 , C07C69/80 , C07C2523/755 , C08K5/12 , C07C11/02 , C07C47/02 , C07C31/125
摘要： The preparation of high-quality oxo process alcohols from inconstant raw material sources is the technically demanding problem which is addressed by a process for continuously preparing an alcohol mixture, in which an input mixture which contains an olefin and has a composition that changes over time is subjected to an oligomerization to obtain an oligomerizate and at least a portion of the olefin oligomers present in the oligomerizate are hydroformylated with carbon monoxide and hydrogen in a hydroformylation in the presence of a homogeneous catalyst system to give aldehydes, at least some of which are converted to the alcohol mixture by subsequent hydrogenation. The process provides a constant plasticizer quality to be produced over a long production period and, optionally, a higher throughput with the same product quality. This is achieved a) by control of the temperature and/or the conversion of the oligomerization as a function of the current composition of the oligomerizate; and b) by control of the composition of the catalyst system and/or of the pressure of the hydroformylation as a function of the current composition of the aldehydes.

57. 发明授权

US08044229B2 Alicyclic polycarboxylic ester mixtures with a high trans proportion and method for the production thereof 失效
标题翻译：具有高反式比例的脂环族多羧酸酯混合物及其制备方法
公开(公告)号：US08044229B2
公开(公告)日：2011-10-25
申请号：US10490028
申请日：2002-09-03
申请人： Dietrich Maschmeyer , Wilfried Bueschken , Michael Grass , Axel Tuchlenski
发明人： Dietrich Maschmeyer , Wilfried Bueschken , Michael Grass , Axel Tuchlenski
IPC分类号： C07C69/74 , C08G63/02
CPC分类号： C07C69/75 , C07C67/303
摘要： The present invention relates to the preparation of alicyclic polycarboxylic esters by ring-hydrogenation of the corresponding aromatic polycarboxylic esters on a catalyst which comprises at least one metal from the triad iron, cobalt, nickel, and at least one metal of the IInd, IIIrd, IVth, Vth, and/or VIth transition group of the Periodic Table.An alicyclic carboxylic ester mixture with a proportion above 10 mol % of the trans isomers.The use of the alicyclic polycarboxylic ester mixtures.Mixtures made from plastics and from alicyclic polycarboxylic ester mixtures.
摘要翻译：本发明涉及通过在催化剂上对相应的芳族多羧酸酯进行环加氢制备脂环族多羧酸酯，所述催化剂包含至少一种来自三联体铁，钴，镍和至少一种IInd，IIIrd， IV，Vth，和/或第六过渡组。一种比例高于10摩尔％的反式异构体的脂环族羧酸酯混合物。使用脂环族多羧酸酯混合物。由塑料和脂环族多羧酸酯混合物制成的混合物。

58. 发明授权

US07354883B2 Catalyst and method for the production of 1-olefins from 2-hydroxylkanes 有权
标题翻译：用于从2-羟基烷烃生产1-烯烃的催化剂和方法
公开(公告)号：US07354883B2
公开(公告)日：2008-04-08
申请号：US10576302
申请日：2004-10-21
申请人： Alfred Kaizik , Dietrich Maschmeyer , Klaus-Diether Wiese , Wilfried Bueschken , Kurt-Alfred Gaudschun
发明人： Alfred Kaizik , Dietrich Maschmeyer , Klaus-Diether Wiese , Wilfried Bueschken , Kurt-Alfred Gaudschun
IPC分类号： B01J23/00 , C07C1/24
CPC分类号： C07C1/24 , B01J21/066 , B01J23/002 , B01J23/02 , B01J23/10 , B01J35/1014 , B01J35/1042 , B01J37/0009 , B01J37/03 , B01J2523/00 , C07C2523/10 , C07C11/02 , B01J2523/12 , B01J2523/36 , B01J2523/48
摘要： The present invention relates to a process for preparing 1-olefins from 2-hydroxyalkanes by catalytic elimination of water under nonisomerizing conditions and to a catalyst which is particularly well-suited for this process and formally comprises yttrium oxide (Y2O3), zirconium dioxide (ZrO2) and an alkali metal oxide and/or alkaline earth metal oxide.
摘要翻译：本发明涉及一种通过在非异构化条件下催化除去水而由2-羟基烷烃制备1-烯烃的方法和特别适用于该方法的催化剂，并且正式地包含氧化钇（Y 2 O 2）（CH 2 O 3），二氧化锆（ZrO 2）和碱金属氧化物和/或碱土金属氧化物。

59. 发明申请

US20050131259A1 Dealuminized catalyst support, method for producing said catalyst support and method for hydrating C2- or C3-olefins with water in the presence of a catalyst consisting of this catalyst support impregnated with acid 审中-公开
标题翻译：脱铝催化剂载体，用于生产所述催化剂载体的方法和用水在含有酸的催化剂载体的催化剂存在下水与C2-或C3-烯烃的方法
公开(公告)号：US20050131259A1
公开(公告)日：2005-06-16
申请号：US10973759
申请日：2004-10-26
申请人： Michael Sakuth , Gregor Lohrengel , Dietrich Maschmeyer , Guido Stochniol
发明人： Michael Sakuth , Gregor Lohrengel , Dietrich Maschmeyer , Guido Stochniol
IPC分类号： B01J21/16 , B01J27/16 , B01J37/00 , C07C29/04 , C07C29/08 , C07C31/08
CPC分类号： C12C11/02 , B01J21/16 , B01J27/16 , C07C29/08 , C07C31/08 , C07C31/10
摘要： What is claimed is a dealuminated catalyst carrier, a process for producing a catalyst carrier with reduced aluminium content based on naturally occurring lattice-layer silicates, such as, for example, montmorillonite, as well as a process for the hydration reaction of C2- or C3-olefins in which said catalyst carrier with reduced aluminium content is used. For acid-catalysed hydration reaction the catalyst carrier is impregnated with phosphoric acid. The improvements according to the invention of the hydration reaction compared to conventional processes include the fact that no aluminium is leached out of the carrier in the presence of the phosphoric acid. As a result no more blockage of the succeeding apparatus due to aluminum phosphate is expected.
摘要翻译：所要求的是脱铝催化剂载体，基于天然存在的格子层硅酸盐（例如蒙脱石）制备具有降低的铝含量的催化剂载体的方法，以及C 其中使用具有降低的铝含量的所述催化剂载体的2- 2 - 或C 3 - 烯烃。对于酸催化的水合反应，催化剂载体用磷酸浸渍。根据本发明的水合反应与常规方法相比的改进包括在磷酸存在下不将铝从载体中浸出的事实。因此，预计不会因为磷酸铝而导致后续装置的堵塞。

60. 发明授权

US08314043B2 Process for the regeneration of a Fischer-Tropsch catalyst 失效
标题翻译：费 - 托催化剂再生方法
公开(公告)号：US08314043B2
公开(公告)日：2012-11-20
申请号：US12515208
申请日：2007-10-30
申请人： Hermanus Gerhardus Jozef Lansink Rotgerink , Claus Rehren , Dietrich Maschmeyer
发明人： Hermanus Gerhardus Jozef Lansink Rotgerink , Claus Rehren , Dietrich Maschmeyer
IPC分类号： B01J38/40
CPC分类号： C10G2/342 , B01J23/94 , B01J38/28 , B01J38/30 , C10G2/332 , C10G2/344 , C10G2300/703
摘要： A process is disclosed for the regeneration of a deactivated wax covered Fischer-Tropsch catalyst, a pumpable suspension of deactivated catalyst being injected into a hot gas stream and the regenerated catalyst then being separated off from the gas stream, optionally further treated by calcination and/or reduction.
摘要翻译：公开了一种用于再生失活的蜡覆盖的费 - 托催化剂的方法，将失活的催化剂的可泵送悬浮液注入热气流中，再生的催化剂然后与气流分离，任选进一步通过煅烧和/ 或减少。

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