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    • 51. 发明授权
    • Process for production of chlorinated polyvinyl chloride resin
    • 氯化聚氯乙烯树脂生产工艺
    • US06197895B1
    • 2001-03-06
    • US09120382
    • 1998-07-21
    • Takeyuki SuzukiHiroaki ShiotaMinoru Isshiki
    • Takeyuki SuzukiHiroaki ShiotaMinoru Isshiki
    • C08F822
    • C08F8/22C08F14/06
    • In producing chlorinated polyvinyl chloride resin having chlorination degree of 60-73% by weight, wherein polyvinyl chloride resin is suspended in an aqueous medium and chlorine gas is blown into said suspension under beam of a mercury lamp in the temperature range of 40-90° C., an organic peroxide compound having a 10 hour half-life in the range of 40-90° C. is added into the reaction vessel in the ratio of 0.01-1 parts to 100 parts of the polyvinyl chloride resin by weight before the chlorination reaction is started. By this method, the time for chlorination reaction can be shortened without sacrificing the initial coloring and the heat stability, whereby chlorinated polyvinyl chloride can be produced with significantly improved productivity.
    • 在生产氯化度为60-73重量%的氯化聚氯乙烯树脂中,其中聚氯乙烯树脂悬浮在水性介质中,氯气在水银灯的波束下在40-90℃的温度范围内吹入所述悬浮液 将在40-90℃范围内的10小时半衰期为10小时的有机过氧化物以比例为0.01-1份至100份的聚氯乙烯树脂的比例加入反应容器中 开始氯化反应。 通过该方法,可以缩短氯化反应的时间,而不会牺牲初始着色和热稳定性,由此可以以显着提高的生产率生产氯化聚氯乙烯。