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51. 发明授权

US06593000B2 Chemically adsorbed film and method of manufacturing the same 失效
公开(公告)号：US06593000B2
公开(公告)日：2003-07-15
申请号：US10058220
申请日：2002-01-29
申请人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
发明人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
IPC分类号： B32B904
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , Y10T428/261 , Y10T428/31504 , Y10T428/31663
摘要： A highly dense chemically adsorbed film is formed by repeating the alternate process of adsorption reaction and washing. Adsorption reaction is directed by contacting the substrate surface, which has or is given an alkali metal or a functional group, with a chemical adsorbent, having halosilyl or alkoxysilyl groups at the end of molecules. An unreacted chemical adsorbent is then washed away from the substrate surface. The alternate treatment of adsorption reaction and washing is repeated, thereby covalently bonding a chemically adsorbed film to the substrate surface. As a result, a chemically adsorbed film is formed in which stem molecules are directly or indirectly covalently bonded to the substrate surface via at least one element chosen from the group consisting of Si, Ge, Sn, Ti, Zr, S or C and graft molecules are covalently bonded to at least one element chosen from Si, Ge, Sn, Ti, Zr, S or C via at least one bond chosen from —SiO—, —GeO—, SnO—, —TiO—, ZrO—, —SO2—, —SO— and —C—.

52. 发明授权

US06333074B1 Water repellent coating film, method and apparatus for manufacturing the same, and water repellent coating material composition 失效
标题翻译：防水涂膜，其制造方法和装置以及防水涂料组合物
公开(公告)号：US06333074B1
公开(公告)日：2001-12-25
申请号：US09480252
申请日：2000-01-11
申请人： Kazufumi Ogawa , Yasuo Takebe , Norihisa Mino
发明人： Kazufumi Ogawa , Yasuo Takebe , Norihisa Mino
IPC分类号： B05D300
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , F28F17/005 , F28F2245/02 , Y10T428/2936 , Y10T428/2995 , Y10T428/31663 , Y10T428/31678
摘要： By forming a film that comprises a microcrystalline polymer having at least a fluorocarbon group and has a rough surface on a surface of a base material, super-water-repellency is provided, the dew condensation water of an air conditioner, for example, can be easily removed, and the freezing of the fin of the heat exchanger can be prevented. A fin that is made of aluminium is coated with a solution for forming a coating film, in which CF3(CF2)7—(CH2)2—SiCl3 is diluted with nonaqueous cyclohexamethyl trisiloxane at a concentration of 10 vol. % for preparation, to a thickness of 1 to 10 &mgr;m by a brush, and then the cyclohexamethyl trisiloxane is vaporized in an atmosphere having a relative humidity of about 75% at room temperature. CF3(CF2)7—(CH2)2—SiCl3 that remained on the fin is rapidly hydrolyzed with the moisture in the atmosphere, and the moisture in air and a —SiCl3 group dehydrochlorinated to form a microcrystalline polymer on the fin. As a result, a coating film having a surface roughness in the range of 1 to 40 &mgr;m and a contact angle of about 171° to water can be formed.
摘要翻译：通过形成包含至少具有碳氟化合物基团并且在基材表面上具有粗糙表面的微晶聚合物的膜，提供超疏水性，例如空调的结露水可以是容易地除去，并且可以防止热交换器的翅片的冻结。用铝制成的翅片涂覆有形成涂膜的溶液，其中CF 3（CF 2）7 - （CH 2）2 -SiCl 3用10体积浓度的非水性环己甲基三硅氧烷稀释。制备时，用刷子将其厚度设定为1〜10μm，然后在室温下在相对湿度为约75％的气氛中将环己甲基三硅氧烷蒸发。残留在翅片上的CF 3（CF 2）7 - （CH 2）2 -SiCl 3随着大气中的水分，空气中的水分和-SiCl 3基团脱氯化氢而迅速水解，从而在翅片上形成微晶聚合物。结果，可以形成表面粗糙度为1〜40μm，与水接触角为约171°的涂膜。

53. 发明授权

US5869136A Method of manufacturing a chemically adsorbed multilayer film 失效
标题翻译：制造化学吸附多层膜的方法
公开(公告)号：US5869136A
公开(公告)日：1999-02-09
申请号：US12753
申请日：1993-02-03
申请人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
发明人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
IPC分类号： B05D1/18 , C03C23/00 , B05D1/36
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C03C23/00
摘要： A chemically adsorbed multilayer film is formed through the process of replacing a halogen atom on the surface of a chemically adsorbed film with an alkaline metal or changing the halogen atom to a Grignard group by Grignard reaction. This manufacturing method does not disrupt the molecules of the chemically adsorbed film, is easy to perform, low in cost and is safe. After replacing the halogen (for example, Br) on the surface of the film with an alkaline metal such as Li, a condensation reaction including a dealkalihalide reaction is promoted by contacting the chemically adsorbed film with an adsorbent, such as a chemical adsorbent--containing a halosilane group at one end of a molecule--dissolved in a nonaqueous solvent. A chemically adsorbed multilayer film is then formed by reacting the chemically adsorbed film with chemical absorption composition and with water after removing unreacted adsorbents using a nonaqueous solution.
摘要翻译：通过用碱金属代替化学吸附膜表面上的卤素原子或通过格利雅反应将卤素原子改变成格利雅特基团的方法形成化学吸附的多层膜。该制造方法不会破坏化学吸附膜的分子，容易实施，成本低，安全。用Li等碱性金属取代膜表面的卤素（例如Br）后，通过使化学吸附膜与吸附剂（如含化学吸附剂）接触来促进包括脱卤化物反应的缩合反应分子一端的卤代硅烷基溶解在非水溶剂中。然后通过使用非水溶液除去未反应的吸附剂，使化学吸附膜与化学吸收组合物和水反应形成化学吸附的多层膜。

54. 发明授权

US5455360A 1-pyrrolyl silicon compounds, chemically adsorbed ultrathin film formed therefrom and method of manufacturing the same 失效
标题翻译： 1-吡咯基硅化合物，由其形成的化学吸附的超薄膜及其制造方法
公开(公告)号：US5455360A
公开(公告)日：1995-10-03
申请号：US107886
申请日：1993-08-18
申请人： Norihisa Mino , Kazufumi Ogawa , Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Katsuya Takemura
发明人： Norihisa Mino , Kazufumi Ogawa , Toshinobu Ishihara , Mikio Endo , Tohru Kubota , Katsuya Takemura
IPC分类号： C08G77/26 , B05D1/18 , C07F7/12 , C07F7/18 , C08G77/28 , C08J5/18 , C09K3/16 , H01B1/12 , C07F7/10 , C07D207/323
CPC分类号： B82Y30/00 , B05D1/185 , B82Y10/00 , B82Y40/00 , C07F7/12 , C07F7/182 , C07F7/1836 , C07F7/1868
摘要： Disclosed are a conductive pyrrole derivative monomolecular film covalently bonded to a substrate surface and method of manufacturing the same, and a monomer used for forming the conductive pyrrole derivative monomolecular film and method of manufacturing the same. The invention relates to a monomolecular ultrathin film comprising 1-pyrrolyl groups and silicon groups. The monomer used for forming the film is provided by reacting .omega.-(1-pyrrolyl)-1-alkene compound to a monosilane derivative compound, in which three out of four hydrogen atoms of monosilane are replaced with halogen or alkoxy groups, in the presence of a transition metal catalyst. A substrate is dipped and held in a nonaqueous solution of the above-noted monomer, thus chemically bonding a monomolecular film to a substrate surface. Furthermore, a polypyrrole derivative ultrathin film is formed by the electrolytic or catalytic polymerization of the monomolecular film.
摘要翻译：公开了共价键合到基材表面的导电吡咯衍生物单分子膜及其制备方法，以及用于形成导电吡咯衍生物单分子膜的单体及其制造方法。本发明涉及包含1-吡咯基和硅基团的单分子超薄膜。用于形成膜的单体是通过使ω-（1-吡咯基）-1-烯烃化合物与甲硅烷衍生物化合物反应而得到的，其中甲硅烷的四个氢原子中的三个被卤素或烷氧基取代，的过渡金属催化剂。将基材浸渍并保持在上述单体的非水溶液中，从而将单分子膜化学键合到基材表面。此外，通过单分子膜的电解或催化聚合形成聚吡咯衍生物超薄膜。

55. 发明授权

US5424098A Method of manufacturing organic films using organic compound and metallic compound 失效
标题翻译：使用有机化合物和金属化合物制造有机膜的方法
公开(公告)号：US5424098A
公开(公告)日：1995-06-13
申请号：US123102
申请日：1993-09-20
申请人： Kazuhiro Nishiyama , Norihisa Mino , Kazufumi Ogawa
发明人： Kazuhiro Nishiyama , Norihisa Mino , Kazufumi Ogawa
IPC分类号： B05D1/18 , B05D7/24 , B32B9/00 , C03C17/28 , C08J7/06
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00
摘要： A method of manufacturing an organic film comprises dipping and holding a substrate having an active hydrogen atom on its surface in a metallic compound having an electrophilic property or solution of the metallic compound and washing the substrate with a nonaqueous solvent, thereby manufacturing a metallic monomolecular film on the substrate surface, or dipping and holding a substrate having an organic monomolecular film in organic compound or acid anhydride of organic compound or solution dissolving the organic solution, thereby, manufacturing an organic monomolecular film on a metallic compound monomolecular film. According to the method of manufacturing an organic film above mentioned, unlike the Langmuir-Blodgett technique, a complicated operation is not required and contamination of impurity to inside of film is avoided. As a result, a film having a complicated structure can be manufactured on a substrate simply.
摘要翻译：制造有机膜的方法包括在具有亲电性或金属化合物溶液的金属化合物的表面上浸渍并保持具有活性氢原子的基材，并用非水溶剂洗涤基板，由此制造金属单分子膜在有机化合物或有机化合物的酸酐或溶解有机溶液的溶液中浸渍并保持具有有机单分子膜的基材，从而在金属化合物单分子膜上制造有机单分子膜。根据上述制造有机膜的方法，与Langmuir-Blodgett技术不同，不需要复杂的操作，并且避免了杂质向膜内部的污染。结果，可以简单地在基板上制造具有复杂结构的膜。

56. 发明授权

US5324548A Method for making optical recording mediums 失效
标题翻译：制造光记录介质的方法
公开(公告)号：US5324548A
公开(公告)日：1994-06-28
申请号：US968874
申请日：1992-10-30
申请人： Kazufumi Ogawa , Hideharu Tamura , Norihisa Mino
发明人： Kazufumi Ogawa , Hideharu Tamura , Norihisa Mino
IPC分类号： G11B7/26 , B05D1/18 , B41M5/26 , G03C1/73 , G11B7/24 , G11B7/244 , G11B7/245 , B05D3/06
CPC分类号： B82Y30/00 , B05D1/185 , B82Y10/00 , B82Y40/00 , G11B7/245
摘要： A method for making an optical recording medium having an optically responsive polydiacetylene monomolecular film or monomolecular built-up film is provided. In the method, a substrate having a hydrophilic surface is immersed in a solution, in organic solvent, of a substance containing a diacetylene group and an --Si--Cl group to form a monomolecular film of the substance on the substrate by chemical adsorption. The diacetylene groups are polymerized by energy beam irradiation to obtain the optically responsive polydiacetylene film. This medium is usable as a write-once or rewriteable medium.
摘要翻译：提供了一种制备具有光学响应的聚二乙炔单分子膜或单分子组合膜的光学记录介质的方法。在该方法中，将具有亲水性表面的基材浸渍在含有二乙炔基和-Si-Cl基的物质的有机溶剂的溶液中，通过化学吸附在基板上形成物质的单分子膜。通过能量束照射使乙炔基聚合，得到光学响应性聚二乙炔膜。该介质可用作一次写入或可重写介质。

57. 发明授权

US06410152B1 Chemically adsorbed film and method of manufacturing the same 有权
公开(公告)号：US06410152B1
公开(公告)日：2002-06-25
申请号：US09892530
申请日：2001-06-28
申请人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
发明人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
IPC分类号： B32B904
摘要： A highly dense chemically adsorbed film is formed by repeating the alternate process of adsorption reaction and washing. Adsorption reaction is directed by contacting the substrate surface, which has or is given an alkali metal or a functional group, with a chemical adsorbent, having halosilyl or alkoxysilyl groups at the end of molecules. An unreacted chemical adsorbent is then washed away from the substrate surface. The alternate treatment of adsorption reaction and washing is repeated, thereby covalently bonding a chemically adsorbed film to the substrate surface. As a result, a chemically adsorbed film is formed in which stem molecules are directly or indirectly covalently bonded to the substrate surface via at least one element chosen from the group consisting of Si, Ge, Sn, Ti, Zr, S or C and graft molecules are covalently bonded to at least one element chosen from Si, Ge, Sn, Ti, Zr, S or C via at least one bond chosen from —SiO—, —GeO—, SnO—, —TiO—, ZrO—, —SO2—, —SO— and —C—.

58. 发明授权

US6099958A Lubricating film comprising a covalently bonded, chemically adsorbed film and a physically adsorbed organic compound formed thereon 失效
标题翻译：包含共价键合的化学吸附膜和在其上形成的物理吸附的有机化合物的润滑膜
公开(公告)号：US6099958A
公开(公告)日：2000-08-08
申请号：US970293
申请日：1997-11-14
申请人： Norihisa Mino , Kazufumi Ogawa
发明人： Norihisa Mino , Kazufumi Ogawa
IPC分类号： B05D7/24 , B05D1/18 , B32B9/00 , C10M107/50 , C10M107/54 , C10M177/00 , C10N30/06 , C10N40/02 , C10N40/18 , C10N50/08 , C10N70/00 , G11B5/725 , G11B5/84 , B32B7/04
CPC分类号： B82Y30/00 , B05D1/185 , B82Y40/00 , C10M107/50 , C10M107/54 , C10M177/00 , G11B5/725 , G11B5/8408 , C10M2207/125 , C10M2207/129 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2215/08 , C10M2215/082 , C10M2215/28 , C10M2219/082 , C10M2227/04 , C10M2227/08 , C10M2227/083 , C10M2229/051 , C10N2240/00 , C10N2240/02 , C10N2240/20 , C10N2240/201 , C10N2240/202 , C10N2240/203 , C10N2240/204 , C10N2240/205 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66 , Y10T428/261
摘要： A chemically adsorbed film comprising carbon-chain organic molecules is formed on a substrate surface via covalent bonds, and organic compounds comprising carbon chains are physically adsorbed to the surface of the chemically adsorbed film, thus providing a lubricating film which is thin and durable against friction, and with good anti-abrasion and sliding properties. The thickness of the lubricating film is at the nanometer level. More specifically, a lubricating film is made by forming a chemically adsorbed film on a substrate surface after dipping and holding the substrate in a nonaqueous solution dissolving chemical admolecules, and by coating a chloroform solution of a long-chain hydrocarbon-based fatty acid ester compound on the surface of the chemically adsorbed film.
摘要翻译：通过共价键在基板表面上形成包含碳链有机分子的化学吸附膜，并且将包含碳链的有机化合物物理吸附到化学吸附膜的表面，从而提供薄而耐摩擦的润滑膜，具有良好的抗磨损和滑动性能。润滑膜的厚度为纳米级。更具体地说，润滑膜是通过在将基材浸渍在溶解化学分子的非水溶液中并在基材表面上形成化学吸附膜，并且通过涂布长链烃基脂肪酸酯化合物的氯仿溶液在化学吸附膜的表面上。

59. 发明授权

US5681442A Method of producing an organic device 失效
标题翻译：生产有机装置的方法
公开(公告)号：US5681442A
公开(公告)日：1997-10-28
申请号：US565636
申请日：1995-11-29
申请人： Kazufumi Ogawa , Norihisa Mino
发明人： Kazufumi Ogawa , Norihisa Mino
IPC分类号： H01L51/05 , C08F38/00 , H01L21/368 , H01L51/00 , H01L51/30 , C25D9/02
CPC分类号： H01L51/0075 , H01L51/0094 , H01L51/0545 , H01L51/0036 , H01L51/0062 , Y10S428/901 , Y10T428/24917
摘要： A process for producing an organic device includes forming a first electrode and a second electrode on a substrate having an insulating film formed on a surface thereof, etching out the insulating film with the first electrode and the second electrode being used as masks, forming a monomolecular or built-up monomolecular film containing electrolytically polymerizable unsaturated groups directly or indirectly on the surface of the substrate by a chemical absorption method or the Langmuir-Blodgett method. The process further includes a procedure of spreading a surfactant containing the electrolytically polymerizable unsaturated groups on the surface of a water bath to form a monomolecular film, transferring at least one layer of the monomolecular film into the surface of the substrate, and chemically bonding molecules of the surfactant to form at least one layer of the monomolecular film of the surfactant containing electroconductive conjugated groups, applying a voltage between the first electrode and the second electrode to polymerize the electrolytically polymerizable unsaturated groups, and deriving a third electrode from the substrate such that the substrate acts as the third electrode.
摘要翻译：一种制造有机器件的方法包括：在其表面上形成有绝缘膜的基板上形成第一电极和第二电极，用第一电极和第二电极作为掩模蚀刻绝缘膜，形成单分子或通过化学吸收法或Langmuir-Blodgett法直接或间接地在基材表面上含有电解聚合性不饱和基团的单分子膜。该方法还包括将含有电解可聚合不饱和基团的表面活性剂扩散到水浴表面以形成单分子膜，将至少一层单分子膜转移到基材表面的方法，以及化学键合所述表面活性剂形成至少一层含有导电共轭基团的表面活性剂的单分子膜，在所述第一电极和所述第二电极之间施加电压以聚合所述电解聚合的不饱和基团，并从所述基板导出第三电极，衬底作为第三电极。

60. 发明授权

US5552236A Organic magnetic film and method of manufacturing the same 失效
标题翻译：有机磁性膜及其制造方法
公开(公告)号：US5552236A
公开(公告)日：1996-09-03
申请号：US25662
申请日：1993-03-03
申请人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
发明人： Tadashi Ohtake , Norihisa Mino , Kazufumi Ogawa
IPC分类号： B05D1/18 , G11B5/62 , H01F1/42 , H01F10/00 , G11B5/66 , B05D5/12 , C09J5/02
CPC分类号： B82Y30/00 , B05D1/185 , B82Y10/00 , B82Y40/00 , G11B5/62 , H01F1/42 , H01F10/005 , H01F1/0009 , Y10S428/90
摘要： According to the invention, the surface of a substrate possessing an active hydrogen group is contacted with a chemical adsorbent containing a radical generation precursor group or metal ion capturing group within a molecule--also possessing a reactive functional group such as halosilyl or alkoxy silyl at its end--to form a chemical adsorption film by removing the unreacted chemical adsorbent, radicals are then generated and magnetism is expressed on the chemical adsorption film.
摘要翻译：根据本发明，具有活性氢基团的基材的表面在分子内与含有自由基产生前体基团或金属离子捕获基团的化学吸附剂接触，并且在其分子中也具有反应性官能团如卤代甲硅烷基或烷氧基甲硅烷基通过除去未反应的化学吸附剂形成化学吸附膜，然后产生自由基，并在化学吸附膜上表现磁性。

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