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    • 52. 发明授权
    • Interfacial viscosification of aqueous acid systems utilizing sulfonated
ionomers
    • 使用磺化离聚物的含水酸性体系的界面粘度
    • US4426473A
    • 1984-01-17
    • US374198
    • 1982-05-03
    • Dennis G. PeifferRobert D. LundbergThad O. Walker
    • Dennis G. PeifferRobert D. LundbergThad O. Walker
    • B01J13/00C08J3/07C08K5/05C08K5/15
    • C08J3/07B01J13/0052C08J2357/06
    • The present invention relates to a process for the gelation (i.e. thickening) of an aqueous acid solution which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 100 cps; dissolving a neutralized sulfonated polymer in the solvent system to form a solution, a concentration of the neutralized sulfonated polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; and admixing or contacting said solution with about 5 to about 500 volume percent of the aqueous acid solution, the aqueous acid solution being immiscible with the organic liquid and the polar cosolvent and neutralized sulfonated polymer transferring from the organic liquid to the aqueous acid phase, thereby causing the aqueous acid phase to thicken (i.e. interfacial viscosification).
    • 本发明涉及一种酸性水溶液凝胶化(即增稠)的方法,其包括形成有机液体或油和极性助溶剂的溶剂体系的步骤,极性助溶剂小于约15重量% 溶剂系统,溶剂体系的粘度小于约100cps; 将中和的磺化聚合物溶解在溶剂体系中以形成溶液,溶液中中和的磺化聚合物的浓度为约0.01至约0.5重量%,溶液的粘度小于约200cps; 并将所述溶液与约5至约500体积%的酸水溶液混合或接触,酸性水溶液与有机液体和极性助溶剂不混溶,并将中和的磺化聚合物从有机液体转移到含水酸相,由此 导致含水酸相增稠(即界面粘稠化)。
    • 53. 发明授权
    • Drilling fluids based on a mixture of a sulfonated thermoplastic polymer
and a sulfonated elastomeric polymer
    • 基于磺化热塑性聚合物和磺化弹性体聚合物的混合物的钻井液体
    • US4425461A
    • 1984-01-10
    • US416936
    • 1982-09-13
    • S. Richard TurnerRobert D. LundbergWarren A. ThalerThad O. WalkerDennis G. Peiffer
    • S. Richard TurnerRobert D. LundbergWarren A. ThalerThad O. WalkerDennis G. Peiffer
    • C09K8/36C08K3/24C08L25/08C09K7/02
    • C09K8/36
    • The present invention relates to mixtures of sulfonated thermoplastic polymers and sulfonated elastomeric polymers which function as viscosification agents when added to oil-based drilling muds which are the fluids used to maintain pressure, cool drill bits, and lift cuttings from the holes in the drilling operation for oil and gas wells. The sulfonated thermoplastic and elastomeric polymers both have about 5 to about 200 meq. of sulfonate groups per 100 grams of the sulfonated thermoplastic or elastomeric polymers, wherein the sulfonated groups are neutralized with a metallic cation or an amine or ammonium counterion. A polar cosolvent can optionally be added to the mixture of oil drilling mud and sulfonated thermoplastic and elastomeric polymers, wherein the polar cosolvent increases the solubility of the sulfonated thermoplastic and elastomeric polymer in the oil drilling mud by decreasing the strong ionic interactions between the sulfonate groups of the sulfonated polymers.
    • 本发明涉及磺化热塑性聚合物和磺化弹性体聚合物的混合物,其在添加到油基钻井泥浆中时起粘稠剂的作用,油基钻井泥浆是用于在钻井操作中从孔中保持压力的液体,冷钻头和提升切屑 用于油气井。 磺化的热塑性和弹性体聚合物都具有约5至约200meq。 每100克磺化热塑性或弹性聚合物的磺酸盐基团,其中磺化基团被金属阳离子或胺或铵的抗衡离子中和。 可以任选地将极性助溶剂加入到油钻泥浆和磺化热塑性弹性体聚合物的混合物中,其中极性助溶剂通过降低磺酸盐基团之间的强离子相互作用而增加磺化热塑性弹性体聚合物在石油钻井泥浆中的溶解度 的磺化聚合物。