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51. 发明公开

EP1897911A4 WATER-DISPERSIBLE POLYOLEFIN RESIN COMPOSITION 有权
标题翻译：水可分散的聚烯烃树脂
公开(公告)号：EP1897911A4
公开(公告)日：2009-07-22
申请号：EP06729698
申请日：2006-03-22
申请人： IDEMITSU KOSAN CO
发明人： KANAMARU MASAMI , MINAMI YUTAKA
IPC分类号： C08L23/20
CPC分类号： C08L23/10 , C08L23/20 , C08L33/08 , C08L2666/04
摘要： Provided is a water dispersible polyolefin resin composition which is capable of forming a coating film having a smooth solidified surface when applied onto a substrate and which has excellent storage stability. The water dispersible polyolefin resin composition contains (C) a surfactant, (D) a water-soluble polymeric compound and (E) a water-insoluble organic solvent in amounts of 0.01 to 1.00 part by mass, 0.01 to 1.00 part by mass and 2 to 200 parts by mass, respectively, per 100 parts by mass of a combination of 5 to 70 % by mass of (A) a poly(1-butene) resin having (i) a mesopentad fraction [mmmm] of 20 to 80 mole % and (ii) a weight average molecular weight (Mw) measured by gel permeation chromatography (GPC) of 10,000 to 1,000,000 or 5 to 70 % by mass of (A') polypropylene resin having (i) a mesopentad fraction [mmmm] of 20 to 60 mole % and (ii) an intrinsic viscosity [·] measured at 135°C in tetralin of 0.1 to 15 dl/g with 95 to 30 % by mass of (B) water.

52. 发明公开

EP1477498A4 PROCESS FOR PRODUCING MODIFIED BUTENE-1 POLYMER AND MODIFIED BUTENE-1 POLYMER OBTAINED BY THE PROCESS 有权
标题翻译：用于生产改性丁烯-1聚合物然后起身丁烯-1聚合物
公开(公告)号：EP1477498A4
公开(公告)日：2006-12-13
申请号：EP03705328
申请日：2003-02-19
申请人： IDEMITSU KOSAN CO
发明人： KANAMARU MASAMI , MINAMI YUTAKA , ABURATANI RYO , TATSUMI TOMIO
IPC分类号： C08F8/00 , C08F8/46 , C08F255/00 , C08F255/10 , C08F257/02 , C08L23/20 , C08L51/00 , C08L51/06 , C09J123/20 , C09J151/00 , C09J151/06 , C09J123/30
CPC分类号： C09J151/003 , C08F255/00 , C08F255/10 , C08F257/02 , C08L23/20 , C08L51/003 , C08L51/06 , C08L2666/02 , C08L2666/24 , C09J123/20 , C09J151/06 , Y10S526/943 , C08F222/06 , C08F220/06 , C08F212/08
摘要： The present invention relates to a process for producing a buten-1-based polymer satisfying the following requirements (a), (b) and (c): (a) a crystalline resin having a melting point (Tm -D) of 0 to 100 DEG C, the melting point being defined as a top of a peak observed on a highest-temperature side in a melting endothermic curve obtained by a differential scanning calorimeter (DSC) when a sample is held in a nitrogen atmosphere at -10 DEG C for 5 min and then heated at a temperature rise rate of 10 DEG C/min; (b) a stereoregularity index represented by (mmmm)/(mmrr + rmmr) of 20 or less; and (c) a weight-average molecular weight (Mw) of 10,000 to 1,000,000 and a ratio (Mw/Mn) of weight-average molecular weight to number-average molecular weight of 4.0 or less; a modified buten-1-based polymer produced by modifying the buten-1-based polymer with a radical polymerization initiator and an organic acid; and an adhesive composition containing the modified buten-1-based polymer. The modified buten-1-based polymer of the present invention is capable of imparting a high adhesiveness, a high strength and a good softness to polyolefins, and providing sealants having a high adhesiveness, or polyolefins having an improved compatibility to inorganic fillers, etc., in particular, is useful as resins for hot-melt adhesives.

53. 发明公开

EP1498432A4 PROCESS FOR PRODUCING HIGHLY FLOWABLE PROPYLENE POLYMER AND HIGHLY FLOWABLE PROPYLENE POLYMER 有权
标题翻译：用于产生良好的流动性丙烯聚合物和GOOD FLOWABLE丙烯聚合物
公开(公告)号：EP1498432A4
公开(公告)日：2006-10-04
申请号：EP03725615
申请日：2003-04-21
申请人： IDEMITSU KOSAN CO
发明人： MINAMI YUTAKA , KANAMARU MASAMI , FUJIOKA TOYOZO , MINE TOSHIHIRO
IPC分类号： C08F4/645 , C08F4/659 , C08F10/06 , C08F110/06 , C08F210/06 , C08L23/10 , C09J123/10
CPC分类号： C08L23/10 , C08F4/65908 , C08F4/65912 , C08F10/06 , C08F110/06 , C08F210/06 , C08L2205/02 , C08L2666/02 , C09J123/10 , C08F4/65927 , C08L2666/06 , C08F2500/15 , C08F2500/17 , C08F2500/03 , C08F2500/20 , C08F210/08 , C08F210/14
摘要： A propylene polymer can be produced which has evenness of composition and regulated stereoregularity and is highly flowable and highly flexible. Also provided is propylene-based modifier giving a molding which is soft, reduced in tackiness, and excellent in compatibility with polyolefin resins. Furthermore, provided is a hot-melt adhesive composition. It is excellent in heat resistance and flowability at high temperature and in adhesion to lowly polar substance. It is usable for sanitary materials, packing, bookbinding, fibers, woodworking, electric materials, canmaking, building, bagmaking, etc.

54. 发明公开

EP1561762A4 PROCESS FOR PRODUCING PROPYLENE/ETHYLENE BLOCK COPOLYMER AND PROPYLENE/ETHYLENE BLOCK COPOLYMER 审中-公开
标题翻译：方法制备丙烯/乙烯嵌段共聚物和丙烯/乙烯嵌段共聚物
公开(公告)号：EP1561762A4
公开(公告)日：2006-03-15
申请号：EP03811115
申请日：2003-11-11
申请人： IDEMITSU KOSAN CO
发明人： KANAMARU MASAMI , FUNABASHI HIDEO
IPC分类号： C08F4/656 , C08F4/659 , C08F4/6592 , C08F10/00 , C08F210/06 , C08F297/08
CPC分类号： C08F297/08 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/00 , C08F210/06 , C08F297/083 , Y10S526/941 , Y10S526/943 , C08F210/16 , C08F2500/17 , C08F2500/24 , C08F2500/11 , C08F4/65904
摘要： A process for producing a propylene/ethylene block copolymer with a satisfactory morphology, which comprises using a catalyst system comprising (1) a metallocene catalyst giving a highly crystalline polypropylene, (2) a metallocene catalyst giving a lowly crystalline polypropylene, (3) a porous support, and (4) an aluminoxane or a compound capable of forming an ionic complex upon reaction with either of the metallocene catalysts, and optionally containing (5) an organoaluminum compound; and a propylene/ethylene block copolymer obtained by the process. The copolymer is highly transparent and has a low modulus.

55. 发明公开

EP1498434A4 PROCESS FOR PRODUCTION OF MODIFIED PROPYLENE POLYMERS AND MODIFIED PROPYLENE POLYMERS PRODUCED BY THE PROCESS 有权
标题翻译：用于生产改性丙烯聚合物并生产改性丙烯聚合物
公开(公告)号：EP1498434A4
公开(公告)日：2005-08-10
申请号：EP03746459
申请日：2003-04-11
申请人： IDEMITSU KOSAN CO
发明人： KANAMARU MASAMI , MINAMI YUTAKA , ABURATANI RYO , TATSUMI TOMIO , FUJIMURA TAKENORI
IPC分类号： C08F8/00 , C08F255/02 , C09J123/10 , C09J123/12 , C08F8/46 , C09J123/26 , C09J151/06
CPC分类号： C09J123/12 , C08L2023/42 , C08L2666/02 , C09J123/10
摘要： The present invention relates to a method for producing a modified propylene-based polymer containing modifying a propylene-based polymer by a radical initiator and an organic acid, a modified propylene-based polymer obtained by the method, and an adhesive composition containing the modified propylene-based polymer. The propylene-based polymer is a propylene homopolymer satisfying the conditions of (a) mmmm = 20 to 60 mol%, (b) Ärrrr/(1-mmmm)Ü 2.5 mol%, (d) mmxrr/(mr) C-NMR measurement is 55 to 90 mol%. The modified propylene-based polymer of the invention can make a polyolefin, etc. more adhesive, stronger, or flexible, to be useful for a high-adhesive sealant or an polyolefin with increased compatibility to an inorganic filler, etc., particularly as a resin for a hot-melt adhesive.

56. 发明专利

JP2011246559A Catalyst composition and process for producing olefinic polymer using the catalyst composition 有权
标题翻译：催化剂组合物和使用催化剂组合物生产烯烃聚合物的方法
公开(公告)号：JP2011246559A
公开(公告)日：2011-12-08
申请号：JP2010119784
申请日：2010-05-25
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： YABUGAMI MINORU , KANAMARU MASAMI , FUJIMURA TAKETSUNE , MINAMI YUTAKA
IPC分类号： C08F4/6592
CPC分类号： C08F4/65922 , C08F4/65908 , C08F4/6592 , C08F10/00 , C08F110/06 , C08F110/14 , C08F2410/01 , C08F4/65912 , C08F4/65927 , C08F4/6494 , C08F4/6495
摘要： PROBLEM TO BE SOLVED: To provide a catalyst composition which uses a transition metal compound etc., and can be made a high concentration, and to provide a method for producing an olefinic polymer using the catalyst composition.SOLUTION: The specific catalyst composition is obtained by bringing (A) the transition metal compound into contact with (B) a solid boron compound forming an ion pair with the component (A), (C) an organometallic compound and (D) a compound represented by general formula (XIV) and/or general formula (XV) in a hydrocarbon solvent.
摘要翻译：待解决的问题：提供使用过渡金属化合物等的催化剂组合物，并且可以制成高浓度，并提供使用该催化剂组合物制备烯烃聚合物的方法。解决方案：通过使（A）过渡金属化合物与（B）与组分（A），（C）有机金属化合物和（D）形成离子对的固体硼化合物接触来获得特定的催化剂组合物）在烃溶剂中由通式（XIV）和/或通式（XV）表示的化合物。版权所有（C）2012，JPO＆INPIT

57. 发明专利

JP2011144293A METHOD FOR PRODUCING POLY-α-OLEFIN 有权
标题翻译：生产聚α-烯烃的方法
公开(公告)号：JP2011144293A
公开(公告)日：2011-07-28
申请号：JP2010007388
申请日：2010-01-15
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： KANAMARU MASAMI , FUJIMURA TAKETSUNE
IPC分类号： C08F10/00 , C08F2/00 , C08F4/6592
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a poly-α-olefin exhibiting high activity.
SOLUTION: The method for producing a polyolefin is provided, comprising conducting a polymerization reaction under the reaction conditions meeting the requirements (a) to (d) described below, using a catalyst prepared by mutually contacting (A) a transition metal compound, (B) a boron compound forming an ion pair with the component (A), and (C) an organoaluminum compound. The requirements (a) to (d) are as follows: (a) 200≤c/a≤4,500, wherein a is the molar amount of the component (A) and c is the molar amount of the component (C); (b) when using a gaseous monomer, the amounts of carbonyl sulfide, carbon dioxide and carbon monoxide contained in the gaseous monomer are 20 mass ppb or less, 0.1 mol.ppm or less, and 0.1 mol.ppm or less, respectively; (c) when using a liquid monomer, the amounts of a monomer oxide(s) and moisture contained in the liquid monomer are 100 mass ppm or less and 10 mass ppm or less, respectively; and (d) when using a solvent, the amount of moisture contained in the solvent is 10 mass ppm or less.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：待解决的问题：提供一种表现出高活性的聚-α-烯烃的制备方法。解决方案：提供聚烯烃的制造方法，包括使用通过使（A）过渡金属化合物（A）相互接触而制备的催化剂，在满足下述要求（a）〜（d）的反应条件下进行聚合反应，（B）与组分（A）形成离子对的硼化合物和（C）有机铝化合物。（a）至（d）的要求如下：（a）200≤c/a≤4,500，其中a是组分（A）的摩尔量，c是组分（C）的摩尔量; （b）当使用气态单体时，气态单体中所含的羰基硫化物，二氧化碳和一氧化碳的量分别为20质量ppm以下，0.1摩尔ppm以下，0.1摩尔ppm以下。（c）当使用液体单体时，液体单体中所含的单体氧化物和水分的量分别为100质量ppm以下且10质量ppm以下。和（d）当使用溶剂时，溶剂中含有的水分量为10质量ppm以下。版权所有（C）2011，JPO＆INPIT

58. 发明专利

JP2010001367A Reactive hot-melt adhesive composition 有权
标题翻译：反应性热熔胶组合物
公开(公告)号：JP2010001367A
公开(公告)日：2010-01-07
申请号：JP2008160650
申请日：2008-06-19
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： KANAMARU MASAMI , MINAMI YUTAKA , YASUYOSHI MATSUNORI
IPC分类号： C09J123/10 , C09J11/08 , C09J123/30 , C09J175/04
摘要： PROBLEM TO BE SOLVED: To provide a reactive hot-melt adhesive composition which has strength sufficient for practical use in every aspect of initial adhesivity and of adhesivity after curing reaction, and which is inexpensive. SOLUTION: The reactive hot-melt adhesive composition contains a propylene-based polymer, a polyol, and a polyisocyanate compound, the propylene-based polymer satisfying the following (a)-(c): (a) [mmmm]=20-80 mol%, (b) a molecular weight distribution of (Mw/Mn)≤4.0, and (c) 0.5 mass% or less of an acetone-soluble portion. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种反应性热熔粘合剂组合物，其具有足够实用的初始粘合性的各个方面的强度和固化反应后的粘合性，并且成本低廉。反应性热熔粘合剂组合物含有丙烯类聚合物，多元醇和多异氰酸酯化合物，满足以下（a） - （c）的丙烯类聚合物：（a）[mmmm] = 20-80摩尔％，（b）（Mw / Mn）≤4.0的分子量分布和（c）丙酮可溶部分的0.5质量％以下。版权所有（C）2010，JPO＆INPIT

59. 发明专利

JP2008202024A α-OLEFIN POLYMER AND METHOD FOR PRODUCING THE SAME 有权
标题翻译： α-烯烃聚合物及其生产方法
公开(公告)号：JP2008202024A
公开(公告)日：2008-09-04
申请号：JP2007266928
申请日：2007-10-12
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： KANAMARU MASAMI , MINAMI YUTAKA , TAKEBE TOMOAKI
IPC分类号： C08F10/14 , C08F4/654
摘要： PROBLEM TO BE SOLVED: To provide a high molecular weight α-olefin polymer having specific properties prepared by using a 12-30C α-olefin as a raw material, and to provide a method for efficiently producing the same.
SOLUTION: The α-olefin polymer is a polymer of one or more 8-30C α-olefins and satisfies the following (1) and (2): (1) the weight-average molecular weight (Mw) in terms of polystyrene measured by the gel permeation chromatography (GPC) is 1,000,000 or more, and (2) the molecular weight distribution (Mw/Mn) determined from the weight-average molecular weight (Mw) and the number average molecular weight (Mn) in terms of polystyrene measured by the gel permeation chromatography (GPC) is 3-20. The method for producing an α-olefin polymer comprises polymerizing a 12-30C α-olefin at 40°C or below in the presence of a catalyst comprising a solid catalyst component containing a magnesium compound and a titanium compound.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供一种通过使用12-30℃α-烯烃作为原料制备的具有特定性能的高分子量α-烯烃聚合物，并提供一种有效地制备该聚合物的方法。解决方案：α-烯烃聚合物是一种或多种8-30℃α-烯烃的聚合物，满足以下（1）和（2）：（1）以重量平均分子量（Mw）计通过凝胶渗透色谱法（GPC）测定的聚苯乙烯为1,000,000以上，（2）由重均分子量（Mw）和数均分子量（Mn）确定的分子量分布（Mw / Mn）通过凝胶渗透色谱法（GPC）测定的聚苯乙烯为3-20。 α-烯烃聚合物的制造方法包括在包含含有镁化合物和钛化合物的固体催化剂成分的催化剂存在下，在40℃以下聚合12-30℃的α-烯烃。版权所有（C）2008，JPO＆INPIT

60. 发明专利

JP2007009002A Water-dispersible polyolefin resin composition 有权
标题翻译：水不溶性聚烯烃树脂组合物
公开(公告)号：JP2007009002A
公开(公告)日：2007-01-18
申请号：JP2005189463
申请日：2005-06-29
申请人： Idemitsu Kosan Co Ltd , 出光興産株式会社
发明人： KANAMARU MASAMI , MINAMI YUTAKA
IPC分类号： C08L23/20 , C08L101/14
CPC分类号： C08L23/10 , C08L23/20 , C08L33/08 , C08L2666/04
摘要： PROBLEM TO BE SOLVED: To provide a water-dispersible polyolefin resin composition which forms a smooth coating film with a solidified surface when applied to a substrate and is excellent in storage stability. SOLUTION: The water-dispersible polyolefin resin composition comprises 100 pts.mass of a combination of (A) 5-70 mass% of a poly(1-butene) resin having (i) a meso pentad fraction [mmmm] of 20-80 mol% and (ii) a weight average molecular weight (Mw) measured by GPC of 10,000-1,000,000 or (A') 5-70 mass% of a polypropylene resin having (i) a meso pentad fraction [mmmm] of 20-60 mol% and (ii) a limiting viscosity [η] measured at 135°C in tetralin of 0.1-15 dl/g with (B) 95-30 mass% of water; (C) 0.01-1.00 pts.mass of a surfactant; (D) 0.01-1.00 pts.mass of a water-soluble polymer compound; and (E) 2-200 pts.mass of a water-insoluble organic solvent. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种水分散性聚烯烃树脂组合物，其在施加到基材上时形成具有固化表面的光滑涂膜，并且具有优异的储存稳定性。解决方案：水分散性聚烯烃树脂组合物包含（A）5-70质量％的聚（1-丁烯）树脂的组合的100重量份，其具有（i）内消旋五单元组分[mmmm] 20-80摩尔％和（ii）通过GPC测量的10,000-1,000,000的重均分子量（Mw）或（A'）5-70质量％的聚丙烯树脂，其具有（i）内消旋五单元组分[mmmm] 20-60摩尔％，（ⅱ）在135℃下在（1S）95-30质量％的水中，在1,2,3,4-四氢化萘中测定的特性粘度[η]为0.1-15dl / g。（C）0.01-1.00磅表面活性剂; （D）0.01〜1.00份水溶性高分子化合物; 和（E）2-200重量份的水不溶性有机溶剂。版权所有（C）2007，JPO＆INPIT

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