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51. 发明授权

US06294274B1 Oxide thin film 有权
标题翻译：氧化物薄膜
公开(公告)号：US06294274B1
公开(公告)日：2001-09-25
申请号：US09350914
申请日：1999-07-12
申请人： Hiroshi Kawazoe , Hideo Hosono , Atsushi Kudo , Hiroshi Yanagi
发明人： Hiroshi Kawazoe , Hideo Hosono , Atsushi Kudo , Hiroshi Yanagi
IPC分类号： C01G302
CPC分类号： H01L33/26 , C03C17/23 , C03C2217/228 , C03C2217/23 , C23C14/087 , H01L51/5012 , Y10T428/26
摘要： An object of the invention is to provide an oxide thin film which exhibits a widegap or transparency and p-type conductivity although it has heretofore been very difficult to form. The oxide thin film formed on a substrate contains copper oxide and strontium oxide as a main component and exhibits p-type conductivity at a bandgap of at least 2 eV.
摘要翻译：本发明的目的是提供尽管迄今为止非常难以形成的具有宽带或透明性和p型导电性的氧化物薄膜。形成在基板上的氧化物薄膜含有氧化铜和氧化锶作为主要成分，并且在至少2eV的带隙处表现出p型导电性。

52. 发明授权

US09048380B2 Thermoelectric conversion material and production method for thermoelectric conversion material 有权
标题翻译：热电转换材料及热电转换材料的制造方法
公开(公告)号：US09048380B2
公开(公告)日：2015-06-02
申请号：US11667753
申请日：2005-11-15
申请人： Hideo Hosono , Masahiro Hirano , Hiromichi Ohta , Kunihito Koumoto
发明人： Hideo Hosono , Masahiro Hirano , Hiromichi Ohta , Kunihito Koumoto
IPC分类号： H01L35/00 , H01L35/22 , H01L35/34
CPC分类号： H01L35/22 , H01L35/34
摘要： A thermoelectric conversion material having a novel composition is provided. The thermoelectric conversion material comprises a first dielectric material layer, a second dielectric material layer, and an electron localization layer that is present between the first dielectric material layer and the second dielectric material layer and that has a thickness of 1 nm.
摘要翻译：提供具有新型组成的热电转换材料。热电转换材料包括第一电介质材料层，第二电介质材料层和存在于第一电介质材料层和第二电介质材料层之间且厚度为1nm的电子定位层。

53. 发明申请

US20050279279A1 Hydrogen-containing electrically conductive organic compound 有权
标题翻译：含氢导电有机化合物
公开(公告)号：US20050279279A1
公开(公告)日：2005-12-22
申请号：US10511715
申请日：2003-04-18
申请人： Hideo Hosono , Masahiro Hirano , Katsuro Hayashi
发明人： Hideo Hosono , Masahiro Hirano , Katsuro Hayashi
IPC分类号： C01B3/00 , C01F7/16 , H01B1/08 , C30B21/02 , C30B7/00 , C30B9/00 , C30B11/00 , C30B28/06
CPC分类号： H01B1/08 , C01B3/00 , C01F7/164 , C01F7/166 , C01P2006/40 , C04B35/44 , C04B2235/3208 , C04B2235/3213 , C04B2235/44 , C04B2235/6565 , C04B2235/658 , C04B2235/6582 , C04B2235/96 , C30B7/00 , C30B7/005 , Y02E60/324
摘要： Disclosed is a 12CaO.7Al2O3 compound, a 12SrO.7Al2O3 compound, or a mixed crystal compound of 12CaO.7Al2O3 and 12SrO.7Al2O3, which contains a negative hydrogen ion (H−, H2−, H2− at a concentration of 1×1018 cm−3 or more. A negative hydrogen ion comprising a primary component of a hydride ion is incorporated into C12A7 (12CaO.7Al2O3), so that a function of being converted from an insulative material to an electrically conductive material in a sustained manner by means of irradiation with light can be exhibited even in the normal atmosphere at a room temperature. The present invention also provides a solid electrolyte capable of conducting a negative hydrogen ion, and means for releasing a hydride ion from the inside of a solid into a gaseous phase using an electric field.
摘要翻译：公开了一种12CaO·0.7Al 2 O 3 N 3化合物，12SrO·7H 2 O 3 O 3化合物，或 12CaO.7Al 2 O 3 3和12SrO 7 Al 2 O 3 3 N 3的混合晶体化合物，其含有负的浓度为1×10 18的氢离子（H 2 - ，H 2 - ，H 2 - ）包含氢离子的主要成分的负极性氢离子被并入到C12A7（12Ca0.7Al2O3）中， <！ - SIPO - >，即使在室温的正常气氛中也可以显示通过照射光从持续的方式将绝缘材料转换成导电材料的功能，本发明还提供能够导入负氢离子的固体电解质，以及使用电场将氢离子从固体内部释放到气相中的装置。

54. 发明授权

US07465433B2 Method for preparing electroconductive mayenite type compound 有权
标题翻译：导电钙铝石型化合物的制备方法
公开(公告)号：US07465433B2
公开(公告)日：2008-12-16
申请号：US11503244
申请日：2006-08-14
申请人： Hideo Hosono , Katsuro Hayashi , Masashi Miyakawa , Masahiro Hirano , Sungwng Kim , Setsuro Ito , Satoru Narushima
发明人： Hideo Hosono , Katsuro Hayashi , Masashi Miyakawa , Masahiro Hirano , Sungwng Kim , Setsuro Ito , Satoru Narushima
IPC分类号： C01F7/00 , C01F11/02
CPC分类号： C04B35/653 , C01F7/164 , C01P2006/40 , C04B35/44 , C04B2235/3205 , C04B2235/3208 , C04B2235/3213 , C04B2235/96
摘要： To provide a method for preparing a mayenite type compound having electroconductivity imparted.A method for preparing an electroconductive mayenite type compound, which comprises melting a raw material containing Al and at least one element selected from the group consisting of Ca and Sr, holding the melt in a low oxygen partial pressure atmosphere having an oxygen partial pressure of not higher than 10 Pa, followed by cooling or annealing in a low oxygen partial pressure atmosphere or in atmospheric air for solidification, thereby to replace oxygen present in cages by electrons in a high concentration.
摘要翻译：提供制备具有导电性的钙铝石型化合物的方法。一种制备导电性钙铝石型化合物的方法，其包括熔融含有Al的原料和选自Ca和Sr中的至少一种元素，将熔体保持在氧分压不为低的氧分压气氛中高于10Pa，然后在低氧分压气氛或大气中进行冷却或退火以固化，从而以高浓度的电子代替笼中存在的电子。

55. 发明申请

US20080210285A1 Thermoelectric Conversion Material And Production Method For Thermoelectric Conversion Material 有权
标题翻译：热电转换材料及热电转换材料的制造方法
公开(公告)号：US20080210285A1
公开(公告)日：2008-09-04
申请号：US11667753
申请日：2005-11-15
申请人： Hideo Hosono , Masahiro Hirano , Hiromichi Ohta , Kunihito Koumoto
发明人： Hideo Hosono , Masahiro Hirano , Hiromichi Ohta , Kunihito Koumoto
IPC分类号： H01L35/02 , H01L35/34 , H01L21/365
CPC分类号： H01L35/22 , H01L35/34
摘要： A thermoelectric conversion material having a novel composition is provided. The thermoelectric conversion material comprises a first dielectric material layer, a second dielectric material layer, and an electron localization layer that is present between the first dielectric material layer and the second dielectric material layer and that has a thickness of 1 nm.
摘要翻译：提供具有新型组成的热电转换材料。热电转换材料包括第一电介质材料层，第二电介质材料层和存在于第一电介质材料层和第二电介质材料层之间且厚度为1nm的电子定位层。

56. 发明申请

US20080095688A1 METHOD FOR PREPARING ELECTROCONDUCTIVE MAYENITE TYPE COMPOUND 有权
标题翻译：制备电极型MAYENITE型化合物的方法
公开(公告)号：US20080095688A1
公开(公告)日：2008-04-24
申请号：US11948147
申请日：2007-11-30
申请人： Hideo Hosono , Katsuro Hayashi , Sung Kim , Masahiro Hirano , Satoru Narushima , Setsuro Ito
发明人： Hideo Hosono , Katsuro Hayashi , Sung Kim , Masahiro Hirano , Satoru Narushima , Setsuro Ito
IPC分类号： C01F17/00 , C01F11/02 , C01F7/00
CPC分类号： C01F7/164 , C01F7/166 , C01P2002/50 , C01P2002/84 , C01P2006/40 , C01P2006/60 , H01B1/08
摘要： Provided is a method for preparing an electroconductive mayenite type compound with good properties readily and stably at low cost without need for expensive facilities, a reaction at high temperature and for a long period of time, or complicated control of reaction. A method for preparing an electroconductive mayenite type compound comprises a step of subjecting a precursor to heat treatment, wherein the precursor contains Ca and/or Sr, and Al, a molar ratio of (a total of CaO and SrO:Al2O3) is from (12.6:6.4) to (11.7:7.3) as calculated as oxides, a total content of CaO, SrO and Al2O3 in the precursor is at least 50 mol %, and the precursor is a vitreous or crystalline material; and the method comprises a step of mixing the precursor with a reducing agent and performing the heat treatment of holding the mixture at 600-1,415° C. in an inert gas or vacuum atmosphere with an oxygen partial pressure of at most 10 Pa.
摘要翻译：本发明提供一种低成本地容易且稳定地制备具有良好性能的导电性钙铝石型化合物的方法，而不需要昂贵的设备，高温反应和长时间的反应或复杂的反应控制。制备导电性钙铝石型化合物的方法包括以下步骤：将前体进行热处理，其中前体含有Ca和/或Sr，和Al，（CaO和SrO：Al 2的总和的摩尔比（12.6:4.4）至（11.7:7.3）按氧化物计算，CaO，SrO和Al 2 O 2的总含量前体中的3 <3>至少为50摩尔％，前体是玻璃状或结晶的材料; 该方法包括将前体与还原剂混合并在氧分压至多10Pa的惰性气体或真空气氛中进行600-1,415℃保持混合物的热处理的步骤。

57. 发明申请

US20080089826A1 METHOD FOR PREPARING ELECTROCONDUCTIVE MAYENITE TYPE COMPOUND 有权
标题翻译：制备电极型MAYENITE型化合物的方法
公开(公告)号：US20080089826A1
公开(公告)日：2008-04-17
申请号：US11948053
申请日：2007-11-30
申请人： Hideo Hosono , Katsuro Hayashi , Sung Kim , Masahiro Hirano , Satoru Narushima , Setsuro Ito
发明人： Hideo Hosono , Katsuro Hayashi , Sung Kim , Masahiro Hirano , Satoru Narushima , Setsuro Ito
IPC分类号： C01F7/02 , C01F17/00
CPC分类号： C01F7/164 , C01F7/002 , C01F7/166 , C01P2002/50 , C01P2002/84 , C01P2006/40 , C01P2006/60 , C03C4/14 , C03C10/0036 , C04B35/44 , C04B35/6262 , C04B35/62675 , C04B35/6268 , C04B2235/3201 , C04B2235/3203 , C04B2235/3206 , C04B2235/3208 , C04B2235/3213 , C04B2235/3215 , C04B2235/3224 , C04B2235/3229 , C04B2235/3232 , C04B2235/3239 , C04B2235/3241 , C04B2235/3262 , C04B2235/3272 , C04B2235/3275 , C04B2235/3279 , C04B2235/3281 , C04B2235/3287 , C04B2235/3409 , C04B2235/3418 , C04B2235/44 , C04B2235/444 , C04B2235/445 , C04B2235/446 , C04B2235/652 , C30B29/22 , C30B33/00 , H01B1/08
摘要： Provided is a method for preparing an electroconductive mayenite type compound with good properties readily and stably at low cost. A production method of an electroconductive mayenite type compound comprising a step of subjecting a precursor to heat treatment, is a method for preparing an electroconductive mayenite type compound, comprising a step of subjecting a precursor to heat treatment; wherein the precursor is a vitreous or crystalline material, which contains Ca and Al, in which a molar ratio of (CaO:Al2O3) is from (12.6:6.4) to (11.7:7.3) as calculated as oxides, and in which a total amount of CaO and Al2O3 is at least 50 mol %, and wherein the heat treatment is heat treatment comprising holding the precursor at a heat treatment temperature T of from 600 to 1415° C. and in an inert gas or vacuum atmosphere with an oxygen partial pressure PO2 in a range of PO2≦105×exp[{−7.9×l04/(T+273)}+14.4] in the unit of Pa.
摘要翻译：提供了一种以低成本容易且稳定地制备具有良好性能的导电性钙铝石型化合物的方法。包括对前体进行热处理的步骤的导电性钙铝石型化合物的制造方法是制备导电性钙铝石型化合物的方法，包括使前体进行热处理的工序; 其中所述前体是含有Ca和Al的玻璃质或结晶材料，其中（CaO：Al 2 O 3 3）的摩尔比为（12.6:6.4））至（11.7:7.3），其中CaO和Al 2 O 3 3的总量为至少50摩尔％，其中热量处理是热处理，包括将前体保持在600-1415℃的热处理温度T下，在氧分压P

58. 发明授权

US07235225B2 12CaO·7A12O3 compound and method for preparation thereof 有权
标题翻译： 12CaO.7A12O3化合物及其制备方法
公开(公告)号：US07235225B2
公开(公告)日：2007-06-26
申请号：US10492938
申请日：2002-10-17
申请人： Hideo Hosono , Masahiro Hirano , Katsuro Hayashi
发明人： Hideo Hosono , Masahiro Hirano , Katsuro Hayashi
IPC分类号： C01F7/00 , A01N59/06 , B01J23/02 , H01M8/10
CPC分类号： H01M4/8605 , A01N59/06 , B01J23/002 , B01J23/02 , B01J37/08 , B01J2523/00 , C01F7/164 , C01P2002/76 , C01P2002/77 , C01P2002/82 , C01P2002/86 , C01P2002/90 , H01M4/9016 , H01M4/9025 , B01J2523/23 , B01J2523/31
摘要： There is provided a C12A7 compound capable of selectively and reversibly clathrating X− ions, such as active oxygen radicals, with improved controllability. The C12A7 compound clathrating OH− ions and On− at a concentration of 2×1019 cm−3 or less can be prepared by subjecting a mixed material containing Ca and Al to a solid phase reaction at a firing temperature not lower than 1200° C. and lower than 1449° C. in a dry oxygen atmosphere having an oxygen partial pressure of 0.1 atm or more and a water vapor partial pressure of 10−3 atm or less, keeping the resultant product at a temperature of 1200° C. or higher, and cooling rapidly. The C12A7 compound is heat-treated to clathrate OH− ions at a concentration of 2×1019 cm−3 or less, and On− at a high concentration of more than 2×1019 cm−3. The compound can reversibly clathrate or release On− ion radicals through the elevation or lowering of the temperature thereof in a temperature range of 300 to 850° C. The compound is useful for an oxidation catalyst, an anti-bacterial agent, an ion conducting material, an electrode for a solid-electrolyte fuel cell, and the like.
摘要翻译：提供了一种C12A7化合物，其能够选择性地和可逆地包合诸如活性氧自由基之类的X - O - 离子，具有改进的可控性。浓度为2×10 19 -3 -3或更低的C12A7化合物包合OH - O 2和O 2 - 通过在氧分压为0.1atm以上的干氧气氛中，在不低于1200℃且低于1449℃的烧成温度下对含有Ca和Al的混合材料进行固相反应来制备，以及水蒸汽分压为10 -3 atm或更低，保持所得产物在1200℃或更高的温度，并快速冷却。将C12A7化合物热处理以2×10 19 -3 -3或更低的浓度包合OH - O 2离子， - 超过2×10 9 cm -3 -3的高浓度。化合物可以通过在300至850℃的温度范围内升高或降低其温度来可逆地包合或释放离子自由基。该化合物可用于氧化催化剂，抗 - 细菌剂，离子导电材料，固体电解质燃料电池用电极等。

59. 发明申请

US20060276326A1 Method for preparing electroconductive mayenite type compound 有权
标题翻译：导电钙铝石型化合物的制备方法
公开(公告)号：US20060276326A1
公开(公告)日：2006-12-07
申请号：US11503244
申请日：2006-08-14
申请人： Hideo Hosono , Katsuro Hayashi , Masashi Miyakawa , Masahiro Hirano , Sungwng Kim , Setsuro Ito , Satoru Narushima
发明人： Hideo Hosono , Katsuro Hayashi , Masashi Miyakawa , Masahiro Hirano , Sungwng Kim , Setsuro Ito , Satoru Narushima
IPC分类号： C04B35/00
CPC分类号： C04B35/653 , C01F7/164 , C01P2006/40 , C04B35/44 , C04B2235/3205 , C04B2235/3208 , C04B2235/3213 , C04B2235/96
摘要： To provide a method for preparing a mayenite type compound having electroconductivity imparted. A method for preparing an electroconductive mayenite type compound, which comprises melting a raw material containing Al and at least one element selected from the group consisting of Ca and Sr, holding the melt in a low oxygen partial pressure atmosphere having an oxygen partial pressure of not higher than 10 Pa, followed by cooling or annealing in a low oxygen partial pressure atmosphere or in atmospheric air for solidification, thereby to replace oxygen present in cages by electrons in a high concentration.
摘要翻译：提供制备具有导电性的钙铝石型化合物的方法。一种制备导电性钙铝石型化合物的方法，其包括熔融含有Al的原料和选自Ca和Sr中的至少一种元素，将熔体保持在氧分压不为低的氧分压气氛中高于10Pa，然后在低氧分压气氛或大气中进行冷却或退火以固化，从而以高浓度的电子代替笼中存在的电子。

60. 发明申请

US20050201682A1 Fiber grating and method for making the same 审中-公开
标题翻译：光纤光栅及其制作方法
公开(公告)号：US20050201682A1
公开(公告)日：2005-09-15
申请号：US10507014
申请日：2003-04-24
申请人： Hideo Hosono , Masahiro Hirano , Kenichi Kawamura , Masanori Oto
发明人： Hideo Hosono , Masahiro Hirano , Kenichi Kawamura , Masanori Oto
IPC分类号： G02B6/02 , G02B6/122 , G02B6/34
CPC分类号： G02B6/02133
摘要： A femtosecond laser radiation or a picosecond laser radiation output from light source 6 is split into a first beam reflected to an angle of 90 degrees by a beam splitter 7 and a straightly advancing second beam cut out by the beam splitter 7. The first beam is reflected at an angle of 90 degrees by a second reflecting mirror 9, reflected again at an angle of 90 degrees by a fourth reflecting mirror 11, and is collimated by a second lens 15 to be irradiated onto an optical fiber core wire 13 to be written. The second beam is reflected at an angle of 90 degrees by a first reflection mirror 8, reflected again at an angle of 90 degrees by a second reflection mirror 10, and is collimated by a first lens 14 to be irradiated onto the optical fiber core wire 13 to be written. The femtosecond laser output from the light source 6 is split into two by the beam splitter 7, which interfere with each other in the vicinity of the core of the optical fiber core wire 13 to generate a change in the refractive indices of the glass depending on the light intensity distribution of the interference fringes, such that the gratings are written in the core 1.
摘要翻译：从光源6输出的飞秒激光辐射或皮秒激光辐射通过分束器7被分裂成以90度的角度反射成90度的第一光束，以及由分束器7切出的直线前进的第二光束。第一光束是通过第二反射镜9以90度的角度反射，由第四反射镜11再次以90度的角度反射，并被第二透镜15准直照射到待被写入的光纤芯线13上。第二光束通过第一反射镜8以90度的角度反射，再次以90度的角度被第二反射镜10反射，并被第一透镜14准直照射到光纤芯线 13要写从光源6输出的飞秒激光由光束分离器7分成两部分，它们在光纤芯线13的芯部附近彼此干涉，以产生玻璃的折射率随着干涉条纹的光强度分布，使得光栅被写入核心1。

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