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51. 发明授权

US5421907A Process for cold cleaning oil-contaminated metal surfaces with 2-ethylhexyl esters of fatty acids 失效
标题翻译：使用脂肪酸的2-乙基己基酯进行冷清洗油污染金属表面的方法
公开(公告)号：US5421907A
公开(公告)日：1995-06-06
申请号：US142390
申请日：1993-11-19
申请人： Claus Nieendick , Karl Schmid , Heinz Mueller , Claus-Peter Herold
发明人： Claus Nieendick , Karl Schmid , Heinz Mueller , Claus-Peter Herold
IPC分类号： C11D7/26 , C11D1/66 , C11D3/20 , C23G1/24 , C23G5/032
CPC分类号： C23G1/24 , C11D3/2093 , C23G5/032
摘要： 2-Ethylhexyl esters of fatty acids, optionally mixed with emulsifiers, solubilizers, corrosion inhibitors, and/or water, are useful as low viscosity agents for the cold cleaning of metal surfaces contaminated mainly with oil. Such agents are non-toxic when inhaled and completely biodegradable.
摘要翻译： PCT No.PCT / EP92 / 01044 Sec。 371日期：1993年11月19日 102（e）1993年11月19日PCT 1992年5月13日提交PCT。任选与乳化剂，增溶剂，腐蚀抑制剂和/或水混合的脂肪酸的乙基己基酯可用作金属冷清洁剂的低粘度剂表面主要被油污染。这些药物在吸入时是无毒的，并且是完全可生物降解的。

52. 发明授权

US5348938A Oleophilic alcohols as a constituent of invert drilling fluids 失效
标题翻译：亲油醇作为反相钻井液的组成部分
公开(公告)号：US5348938A
公开(公告)日：1994-09-20
申请号：US54462
申请日：1993-04-28
申请人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza
发明人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza
IPC分类号： C09K8/32 , C09K8/34 , C09K8/36 , C09K7/02
CPC分类号： C09K8/36 , C09K8/34
摘要： The use is described ofa) mono- and/or polyfunctional alcohols of natural and/or synthetic origin which are at least largely water-insoluble and are fluid and pumpable in the temperature range of 0.degree. to 5.degree. C.,or ofb) solutions, fluid and pumpable in the given temperature range, in ecologically-acceptable water-insoluble oils, of at least largely water-insoluble mono- and/or polyfunctional alcohols of natural and/or synthetic origin,as the continuous oil phase of drilling fluids, which exist as W/O-emulsions, have a dispersed aqueous phase and preferably have further usual additives in the alcohol-containing oil phase, and which are suitable for the environment-friendly development of, e.g., petroleum and natural gas deposits. Drilling fluids of the above type are also described, which are characterized in that they contain as the continuous oil phase, or dissolved in ecologically-acceptable water-insoluble oils, an additive of at least largely water-insoluble mono- and/or polyfunctional alcohols, the oil phase in each case being fluid and pumpable in the temperature range of 0.degree. to 5.degree. C. and having flash points above 80.degree. C.
摘要翻译： PCT No.PCT / EP90 / 00499 Sec。 371日期1991年10月7日 102（e）日期1991年10月7日PCT 1990年3月29日PCT PCT。出版物WO90 / 12070 日期为1990年10月18日。使用描述了a）天然和/或合成来源的单和/或多官能醇，其至少在很大程度上不溶于水并且在0℃至5℃的温度范围内是可流动和可泵送的或者b）在生态上可接受的水不溶性油中的至少大部分天然和/或合成来源的水不溶性单和/或多官能醇的在给定温度范围内的溶液，流体和可泵送的溶液，作为以W / O乳液形式存在的钻井液的连续油相，具有分散的水相，优选在含醇油相中具有其他通常的添加剂，适用于环境友好的开发，例如，石油天然气矿床。还描述了上述类型的钻井液，其特征在于它们包含作为连续油相或溶解在生态上可接受的水不溶性油中，至少主要是水不溶性单和/或多官能醇的添加剂每种情况下的油相在0℃至5℃的温度范围内是可流动的并可泵送，闪点高于80℃。

53. 发明授权

US5318956A Use of selected ester oils in water-based drilling fluids of the O/W emulsion type and corresponding drilling fluids with improved ecological acceptability 失效
标题翻译：在O / W乳液型水相钻井液和相应的钻井液中使用选定的酯油，具有改善的生态可接受性
公开(公告)号：US5318956A
公开(公告)日：1994-06-07
申请号：US055409
申请日：1993-04-29
申请人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Johann Friedrich Fues
发明人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Johann Friedrich Fues
IPC分类号： C09K8/26 , C09K7/06
CPC分类号： C09K8/26
摘要： The use is disclosed of water-dispersible esters, which are fluid or at least plastically deformable at working temperature and have flash points of at least 80.degree. C., from saturated and/or unsaturated carboxylic acids with up to 36 carbon atoms and mono- and/or polyhydric alcohols, as at least the main constituent of the dispersed oil phase of water-based O/W-emulsion drilling fluids which are suitable for the environmentally friendly development of geological formations and which contain, if desired, insoluble, finely particulate weighting agents for the formation of water-based O/W-emulsion drilling muds and/or further additives, such as emulsifiers, fluid-loss additives, wetting agents, alkali reserves and/or auxiliary substances for the inhibition of drilled rock of high water-sensitivity.
摘要翻译：公开了水分散性酯，其是在工作温度下为流体或至少可塑性变形的具有至多80℃的闪点的水分散性酯，其具有至多36个碳原子的饱和和/或不饱和羧酸，和/或多元醇作为至少是水性O / W乳液钻井液的分散油相的主要成分，其适用于地质构造的环境友好型开发，并且如果需要，其含有不溶性的细颗粒用于形成水基O / W乳液钻井泥浆的增重剂和/或其它添加剂，例如乳化剂，流体损失添加剂，润湿剂，碱储备和/或用于抑制高水钻岩的辅助物质 -灵敏度。

54. 发明授权

US5318954A Use of selected ester oils of low carboxylic acids in drilling fluids 失效
标题翻译：在钻井液中使用低羧酸选择的酯油
公开(公告)号：US5318954A
公开(公告)日：1994-06-07
申请号：US84783
申请日：1993-06-29
申请人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Michael Neuss , Frank Burbach
发明人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Michael Neuss , Frank Burbach
IPC分类号： C09K8/34 , C09K8/36 , C09K7/06
CPC分类号： C09K8/34 , C09K8/36
摘要： The invention describes the use of selected esters, fluid at room temperature and with flash points above 80.degree. C., of C.sub.1-5 -monocarboxylic acids and mon- and/or polyfunctional alcohols as the oil phase, or a component of the oil phase of invert drilling muds which are suitable for environment-friendly development of petroleum or natural gas deposits and contain in a continuous oil phase a dispersed aqueous phase together with emulsifiers, weighting agents, fluid-loss additives and preferably further conventional additives. In a further embodiment the invention relates to invert drilling fluids of the type described, which are characterized in that the oil phase contains esters from C.sub.1-5 -monocarboxylic acids with mono- and/or polyfunctional alcohols preferably in admixture with other components from the class of ecologically acceptable compounds.
摘要翻译：本发明描述了在室温下和高于80℃的闪点的选择的酯，作为油相的C1-5-一元羧酸和单和/或多官能醇或油相的组分的用途适用于石油或天然气沉积环境友好型开发的钻井泥浆，并在连续油相中与乳化剂，增重剂，流体损失添加剂以及优选的其它常规添加剂一起含有分散的水相。在另一个实施方案中，本发明涉及所述类型的反相钻井液，其特征在于油相含有来自C 1-5 - 一元羧酸的酯与单和/或多官能醇优选与来自该类的其它组分混合的生态可接受的化合物。

55. 发明授权

US5252554A Drilling fluids and muds containing selected ester oils 失效
标题翻译：钻井液和含有选定酯油的泥浆
公开(公告)号：US5252554A
公开(公告)日：1993-10-12
申请号：US825431
申请日：1992-01-21
申请人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Douglas J. Grimes , Jean-Marc Braun , Stuart P. T. Smith
发明人： Heinz Mueller , Claus-Peter Herold , Stephan von Tapavicza , Douglas J. Grimes , Jean-Marc Braun , Stuart P. T. Smith
IPC分类号： C09K8/34 , C09K7/02 , C09K7/06
CPC分类号： C09K8/34
摘要： Invert emulsion muds for drilling of gas and oil, which are environmentally safe, and which contain:A. a continuous oil phase composed predominantly of at least one monocarboxylic acid ester of a C.sub.2 C.sub.12 monofunctional alkanol wherein the monocarboxylic acid contains from 12 to 16 carbon atoms and is aliphatically saturated,B. a disperse aqueous phase,C. at least one emulsifier,D. at least one weighting agent,E. at least one fluid loss additive, andF. a mild alkaline reserve.
摘要翻译：反转用于钻井气体和油的乳液泥浆，其是环境安全的，并且其包含：A.主要由至少一种C2C12单官能链烷醇的单羧酸酯组成的连续油相，其中所述一元羧酸含有12至16个碳原子并且是脂肪饱和的，B.分散水相，C.至少一种乳化剂，D.至少一种加重剂，E.至少一种流体损失添加剂，F.一种温和的碱性储备。

56. 发明授权

US5225452A Silicone foam forming composition 失效
标题翻译：硅胶泡沫成型组合物
公开(公告)号：US5225452A
公开(公告)日：1993-07-06
申请号：US987832
申请日：1992-12-09
申请人： Andre R. L. Colas , Heinz Mueller
发明人： Andre R. L. Colas , Heinz Mueller
IPC分类号： C08J9/02 , C08L83/04
CPC分类号： C08J9/02 , C08L83/04 , C08G77/12 , C08G77/16 , C08G77/20 , C08G77/24 , C08J2383/04
摘要： A foam forming composition comprises (a) one or more polysiloxanes having not less than three alkylhydrogen siloxane units per molecule, (b) one or more polysiloxanes having not less than two silicon-bonded hydroxyl group per molecule, (c) at least one liquid organic titanium compound and (d) a catalyst. Reaction between the organic titanate (e.g. tetraisopropyltitanate) and the hydroxy functional polysiloxane rapidly increases viscosity of the mixture to restrict flow of the composition as it cures to form a foam within 240 seconds of mixing. A vinyl polysiloxane may be incorporated.

57. 发明授权

US5194422A Use of selected oleophilic alcohols in water-based drilling fluids of the O/W-emulsion type and corresponding drilling fluids with improved ecological acceptability 失效
标题翻译：选择性烯醇在O / W乳液类型和相应钻井液的水基钻井液中的使用具有改善的生态接受性
公开(公告)号：US5194422A
公开(公告)日：1993-03-16
申请号：US773631
申请日：1991-11-15
申请人： Heinz Mueller , Klaus-Peter Herold , Stephan von Tapavicza , Johann F. Fues
发明人： Heinz Mueller , Klaus-Peter Herold , Stephan von Tapavicza , Johann F. Fues
IPC分类号： C09K8/04 , C09K8/26 , C09K8/58
CPC分类号： C09K8/26
摘要： Substantially water-insoluble, oleophilic mono- and/or polyfunctional alcohols of natural and/or synthetic origin which have flash points of at least 80.degree. C., or corresponding solutions of mono- and/or polyhydric alcohols in ecologically acceptable water-insoluble oils as the dispersed oil phase of water-based O/W-emulsion drilling fluids, which are suitable for an environmentally-acceptable development of geological formations and which, if desired, contain insoluble, finely particulate weighting agents for the formation of water-based O/W-emulsions drilling muds and/or further additives, such as emulsifiers, fluid-loss additives, wetting agents, alkali reserves and/or auxiliary substances for the inhibition of drilled rock of high water-sensitivity.
摘要翻译： PCT No.PCT / EP90 / 00735 Sec。 371日期1991年11月15日 102（e）1991年11月15日日期PCT提交1990年5月7日PCT公布。 WO90 / 14401 PCT出版物日期1990年11月29日。具有闪点至少为80℃的天然和/或合成来源的基本上不溶于水的亲油性单和/或多官能醇，或单 - 和/或多元醇的相应溶液在生态上可接受的水不溶性油作为水性O / W乳液钻井液的分散油相，其适用于地质构造的环境可接受的开发，并且如果需要，其包含不溶性的细颗粒加重剂水性O / W乳液钻井泥浆和/或其他添加剂的形成，例如乳化剂，流体损失添加剂，润湿剂，碱储备和/或辅助物质，用于抑制高水敏感性的钻井岩石。

58. 发明授权

US4851142A Fluid loss additive for well drilling fluids 失效
标题翻译：用于钻井液的流体损失添加剂
公开(公告)号：US4851142A
公开(公告)日：1989-07-25
申请号：US191516
申请日：1988-05-09
申请人： William C. Scoggins , Claus P. Herold , Heinz Mueller
发明人： William C. Scoggins , Claus P. Herold , Heinz Mueller
IPC分类号： C09K8/035 , C09K8/36
CPC分类号： C09K8/36 , C09K8/035
摘要： An additive for drilling fluids employed in the deep well drilling industry, which additive comprises an organometal compound of titanium, zirconium or vanadium with humic acid and a further organic moiety which is at least one of fatty acid alkoxylates, fatty alcohol polyalkylene glycol ethers, long-chain amine alkoxylates optionally substituted with a hydroxyl group, or water-insoluble polyalkoxylate all of which are optionally mixed with fatty acids, and fatty acids alone, these having optionally been applied onto an inorganic carrier, mandatorily in the case of fatty acids alone. The fluid loss additive prevents the drilling fluid from streaming into porous drill formations. The additive may be prepared by the reaction of a metal alcoholate with a compound providing the organic moiety and humic acid or a humic acid-containing product.
摘要翻译：一种用于深井钻井工业的钻井液的添加剂，该添加剂包括钛，锆或钒的有机金属化合物与腐殖酸，以及另外的有机部分，其是脂肪酸烷氧基化物，脂肪醇聚亚烷基二醇醚，任选被羟基取代的链胺胺烷氧基化物，或所有这些都是与脂肪酸混合的水不溶性聚烷氧基化物，以及单独的脂肪酸，这些任选地在单独的脂肪酸的情况下被强制施用。流体损失添加剂防止钻井液流入多孔钻井地层。添加剂可以通过金属醇化物与提供有机部分和腐植酸或含腐殖酸的产物的化合物的反应来制备。

59. 发明申请

US20130026198A1 ELECTRIC APPLICATION HEAD FOR DISPENSING A FREE-FLOWING MEDIUM, AND DEVICE COMPRISING SUCH AN ELECTRIC APPLICATION HEAD 审中-公开
标题翻译：用于分配自由流动介质的电子应用头和包含这种电气应用头的装置
公开(公告)号：US20130026198A1
公开(公告)日：2013-01-31
申请号：US13575414
申请日：2011-01-25
申请人： Hanspeter Felix , Roman Kappeler , Heinz Mueller
发明人： Hanspeter Felix , Roman Kappeler , Heinz Mueller
IPC分类号： B67D3/00
CPC分类号： B05C5/0229 , B05C5/0225 , B05C5/0237 , B05C11/10
摘要： The invention relates to an application head (15) for dispensing a free-flowing medium. The application head (15) comprises an injection chamber (10) inside the application head (15) and an injection needle (11) movably mounted inside the injection chamber (10). An opening movement (P) of the injection needle (11) opens an outlet (12). A supply channel (13) and a supply line are also provided in order to introduce the free-flowing medium into the injection chamber (10). A drive (20) generates the opening movement (P) of the injection needle (11). The application head (15) also comprises a lever arm (30), the first end (31) of said arm being movably fixed to a rear end (14) of the injection needle (11) and the second end (32) thereof being connected to the drive. A membrane suspension (33) comprising a membrane (34) is provided, and the lever arm (30) extends through the membrane (34) of the membrane suspension (33). The membrane suspension (33) is used to movably connect the lever arm (30) to the application head (15), and as a seal to prevent the free-flowing medium from leaking out.
摘要翻译：本发明涉及一种用于分配自由流动介质的应用头（15）。应用头（15）包括在施加头（15）内的注射室（10）和可移动地安装在注射室（10）内的注射针（11）。注射针头（11）的打开动作（P）打开出口（12）。还提供供应通道（13）和供应管线，以便将自由流动介质引入注射室（10）。驱动器（20）产生喷射针（11）的打开运动（P）。应用头（15）还包括杠杆臂（30），所述臂的第一端（31）可移动地固定到注射针（11）的后端（14），并且其第二端（32）为连接到驱动器。提供了包括膜（34）的膜悬浮液（33），并且杠杆臂（30）延伸穿过膜悬浮液（33）的膜（34）。膜悬浮液（33）用于将杠杆臂（30）可移动地连接到施加头（15），并且用作密封件以防止自由流动的介质泄漏。

60. 发明授权

US07959743B2 Lithium salts of fatty alcohol sulphates for cleaning boreholes, boring devices and borings 失效
标题翻译：用于清洁钻孔，钻孔装置和钻孔的脂肪醇硫酸盐的锂盐
公开(公告)号：US07959743B2
公开(公告)日：2011-06-14
申请号：US11631450
申请日：2005-07-06
申请人： Heinz Mueller , Diana Maeker , Nadja Herzog
发明人： Heinz Mueller , Diana Maeker , Nadja Herzog
IPC分类号： E21B37/06 , B08B3/00
CPC分类号： C09K8/52
摘要： The invention relates to a process of cleaning boreholes, boring equipment and borings with an aqueous cleaning of one more lithium salts of alkyl sulfates of formula (I): R—O—SO3−Li+ (I) in which R is a saturated, unsaturated, branched or linear alkyl group containing 8 to 22 carbon atoms, preferably the lithium salts of alkyl sulfates are comprised of a mixture of those in which R is a saturated, linear alkyl groups having 8 to 14 carbon atoms.
摘要翻译：本发明涉及一种清洗钻孔，钻孔设备和钻孔的方法，其中还有一种式（I）的烷基硫酸盐的锂盐的水性清洗：R-O-SO 3 -Li +（I），其中R是饱和的，不饱和的含有8-22个碳原子的支链或直链烷基，优选烷基硫酸盐的锂盐由其中R是具有8至14个碳原子的饱和直链烷基的那些的混合物组成。

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