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51. 发明授权

US5770671A Process for polymerizing isocyanates 失效
标题翻译：聚合异氰酸酯的方法
公开(公告)号：US5770671A
公开(公告)日：1998-06-23
申请号：US905256
申请日：1997-08-01
申请人： Hartmut Nefzger , Bernd Quiring
发明人： Hartmut Nefzger , Bernd Quiring
IPC分类号： C08G18/16 , C08G18/10 , C08G18/22
CPC分类号： C08G18/10
摘要： Isocyanates are polymerized in a simple manner by polymerizing aliphatic and/or aromatic isocyanates in the presence of metallocenes at temperatures from 20.degree. to 220.degree. C., optionally subject to increased or reduced pressure and optionally in the presence of an inert organic solvent, the metallocene being used in an amount of 5 to 50,000 ppm relative to the amount of isocyanates used.
摘要翻译：异氰酸酯通过在金属茂存在下在20℃至220℃的温度下聚合脂族和/或芳族异氰酸酯，任选地经受增加或降低的压力以及任选在惰性有机溶剂存在下，以简单的方式聚合，茂金属相对于所用的异氰酸酯的用量为5〜50,000ppm。

52. 发明授权

US5508312A Process for the production of compounds containing hydroxyl groups from (polyurethane) polyurea waste materials 失效
标题翻译：从（聚氨酯）聚脲废料生产含羟基的化合物的方法
公开(公告)号：US5508312A
公开(公告)日：1996-04-16
申请号：US429411
申请日：1995-04-26
申请人： Thomas Munzmay , Hartmut Nefzger , Werner Rasshofer , Walter Meckel
发明人： Thomas Munzmay , Hartmut Nefzger , Werner Rasshofer , Walter Meckel
IPC分类号： C08J11/24 , C08G18/65 , C08G18/83 , C08J11/18 , C08J11/28 , C08L75/00 , C08J11/04
CPC分类号： C08J11/18 , C08J2375/04 , Y02W30/706
摘要： Compounds containing hydroxyl groups, which are suitable for the polyisocyanate addition polymerization process, are prepared from polyurethane-polyurea and/or polyurea waste materials. These compounds are produced by reacting a finely divided polyurethane-polyurea and/or polyurea waste material with a low molecular weight diol and/or polyol (and optionally a higher molecular weight polyol) and a low molecular weight urea and/or carbamic acid ester. This reaction may be carried in either one stage or two stages. In the two stage process, the waste material and diol/polyol are reacted in a first stage at a temperature of from about 100 to about 260.degree. C. In the second stage, the amine-containing alcoholysis product obtained in the first stage is reacted with a low molecular weight urea and/or carbamic acid ester. In the single stage process, the polyurethane-polyurea and/or polyurea waste material is reacted with a low molecular weight diol and/or polyol in the presence of a low molecular weight urea and/or carbamic acid ester.
摘要翻译：含有羟基的化合物，适用于多异氰酸酯加成聚合方法，由聚氨酯 - 聚脲和/或聚脲废料制备。这些化合物通过使细分散的聚氨酯 - 聚脲和/或聚脲废料与低分子量二醇和/或多元醇（和任选的较高分子量的多元醇）和低分子量的脲和/或氨基甲酸酯反应来制备。该反应可以在一个阶段或两个阶段中进行。在二阶段工艺中，废料和二醇/多元醇在约100至约260℃的温度下在第一阶段中反应。在第二阶段中，使第一阶段获得的含胺醇解产物反应与低分子量尿素和/或氨基甲酸酯。在单阶段方法中，聚氨酯 - 聚脲和/或聚脲废料在低分子量脲和/或氨基甲酸酯的存在下与低分子量二元醇和/或多元醇反应。

53. 发明授权

US09751279B2 Composite elements composed from thermoplastic polymers and polyurethanes, and process for production thereof 有权
公开(公告)号：US09751279B2
公开(公告)日：2017-09-05
申请号：US14235102
申请日：2012-07-25
申请人： Rolf William Albach , Hartmut Nefzger , Harald Knaup , Frank Hahn , Petra Venner , Monika Haselbach
发明人： Rolf William Albach , Hartmut Nefzger , Harald Knaup , Frank Hahn , Petra Venner , Monika Haselbach
IPC分类号： B32B5/20 , B32B27/40 , B32B27/06 , B29C44/12 , C08J7/04 , C08J5/12 , C08G18/48 , C08G18/50 , C08G18/63 , C08G18/66 , C08G18/76 , C08G18/32 , C08G18/40 , C08G18/42 , C09J175/04 , C08G101/00
CPC分类号： B32B5/20 , B29C44/12 , B32B27/065 , B32B27/40 , C08G18/324 , C08G18/4018 , C08G18/4072 , C08G18/4216 , C08G18/4238 , C08G18/482 , C08G18/4841 , C08G18/5021 , C08G18/632 , C08G18/6618 , C08G18/7664 , C08G2101/0058 , C08G2170/60 , C08J5/128 , C08J7/047 , C08J2327/06 , C08J2375/04 , C08J2475/06 , C08J2475/08 , C09J175/04 , Y10T428/249953 , Y10T428/249992
摘要： The invention relates to composite elements comprising a thermoplastic polymer and an adjacent polyurethane bonded thereto, to a process for production thereof and to the use thereof.

54. 发明授权

US09062149B2 High-value polyurethane elastomers and production thereof 有权
标题翻译：高价值聚氨酯弹性体及其生产
公开(公告)号：US09062149B2
公开(公告)日：2015-06-23
申请号：US14125836
申请日：2012-06-26
申请人： Florian Hupka , Stephan Reiter , Hartmut Nefzger , Jens Krause
发明人： Florian Hupka , Stephan Reiter , Hartmut Nefzger , Jens Krause
IPC分类号： C08G18/10 , C08G18/72 , C08G18/78 , C08G18/42 , C08G18/71 , C08G18/76
CPC分类号： C08G18/72 , C08G18/10 , C08G18/4238 , C08G18/71 , C08G18/7678 , C08G18/7843 , C08G18/3206
摘要： The present invention relates to high-value polyurethane (PUR) and polyurethaneurea elastomers, which can be processed in a particularly simple manner by use of low-viscosity prepolymers based on naphthalene 1,5-diisocyanate, and to a process for production thereof.
摘要翻译：本发明涉及可以通过使用基于萘-1,5-二异氰酸酯的低粘度预聚物以特别简单的方式加工的高价值聚氨酯（PUR）和聚氨酯脲弹性体及其制备方法。

55. 发明申请

US20140234613A1 PROCESS FOR PRODUCING A RIGID POLYURETHANE-ISOCYANURATE FOAM 审中-公开
标题翻译：生产刚性聚氨酯 - 异氰脲酸酯泡沫的方法
公开(公告)号：US20140234613A1
公开(公告)日：2014-08-21
申请号：US14238254
申请日：2012-08-16
申请人： Hartmut Nefzger , Jörg Hofmann , Klaus Lorenz , Stephanie Vogel , Reinhard Albers , Patrick Klasen
发明人： Hartmut Nefzger , Jörg Hofmann , Klaus Lorenz , Stephanie Vogel , Reinhard Albers , Patrick Klasen
IPC分类号： C08G18/48
CPC分类号： C08G18/4895 , C08G18/092 , C08G18/4018 , C08G18/4261 , C08G18/4841 , C08G2101/0025 , C08G2101/005 , C08G2105/02 , Y10T428/249987 , Y10T428/24999 , Y10T428/249992
摘要： The invention provides a process for producing rigid polyurethane-polyisocyanurate foams using polyols having a high proportion of secondary hydroxyl end groups. The invention further relates to the rigid polyurethane-polyisocyanurate foams thus obtainable and to the use thereof in the production of composite elements from rigid polyurethane-polyisocyanurate foams and suitable outer layers. The invention further provides the composite elements thus obtainable.
摘要翻译：本发明提供了使用具有高比例的仲羟基端基的多元醇生产刚性聚氨酯 - 聚异氰脲酸酯泡沫的方法。本发明还涉及由此获得的硬质聚氨酯 - 聚异氰脲酸酯泡沫及其在从硬质聚氨酯 - 聚异氰脲酸酯泡沫和合适的外层生产复合材料的用途。本发明还提供了由此获得的复合元件。

56. 发明申请

US20140142243A1 HIGH-VALUE POLYURETHANE ELASTOMERS AND PRODUCTION THEREOF 有权
标题翻译：高价值聚氨酯弹性体及其生产
公开(公告)号：US20140142243A1
公开(公告)日：2014-05-22
申请号：US14125836
申请日：2012-06-26
申请人： Florian Hupka , Stephan Reiter , Hartmut Nefzger , Jens Krause
发明人： Florian Hupka , Stephan Reiter , Hartmut Nefzger , Jens Krause
IPC分类号： C08G18/72
CPC分类号： C08G18/72 , C08G18/10 , C08G18/4238 , C08G18/71 , C08G18/7678 , C08G18/7843 , C08G18/3206
摘要： The present invention relates to high-value polyurethane (PUR) and polyurethaneurea elastomers, which can be processed in a particularly simple manner by use of low-viscosity prepolymers based on naphthalene 1,5-diisocyanate, and to a process for production thereof.
摘要翻译：本发明涉及可以通过使用基于萘-1,5-二异氰酸酯的低粘度预聚物以特别简单的方式加工的高价值聚氨酯（PUR）和聚氨酯脲弹性体及其制备方法。

57. 发明申请

US20110133598A1 ELECTROMECHANICAL TRANSDUCER COMPRISING A POLYURETHANE POLYMER WITH POLYTETRAMETHYLENE GLYCOL ETHER UNITS 审中-公开
标题翻译：聚氨酯乙二醇单体聚氨酯聚合物的机电传感器
公开(公告)号：US20110133598A1
公开(公告)日：2011-06-09
申请号：US12959935
申请日：2010-12-03
申请人： Werner Jenninger , Sebastian Dörr , Joachim Wagner , Evelyn Peiffer , Stephanie Vogel , Hartmut Nefzger , Manfred Schmidt
发明人： Werner Jenninger , Sebastian Dörr , Joachim Wagner , Evelyn Peiffer , Stephanie Vogel , Hartmut Nefzger , Manfred Schmidt
IPC分类号： H01L41/193 , H01L41/22
CPC分类号： H01L41/193 , C08G18/089 , C08G18/10 , C08G18/4825 , C08G18/4837 , C08G18/4854 , C08G18/73 , H01L41/45 , Y10T29/42 , C08G18/48
摘要： The present invention provides an electromechanical transducer comprising a dielectric elastomer with contact by a first electrode and a second electrode, said dielectric elastomer comprising a polyurethane polymer comprising the reaction product of A) a polyisocyanate and/or B) a polyisocyanate prepolymer with C) a compound having at least two isocyanate-reactive groups wherein the polyisocyanate prepolymer B) and/or the compound C) having at least two isocyanate-reactive groups comprise polytetramethylene glycol ether units of the formula (I): —[O—CH2-CH2-CH2-CH2-]n (I) where n≧25; and with a minimum value nmin for the value n and a maximum value nmax for the value n in the formula (I) selected such that the difference between nmax and nmin is ≧0 to ≦4. The present invention further provides a process for producing such an electromechanical transducer, and to an electric and/or electronic device including the inventive electromechanical transducer.
摘要翻译：本发明提供一种机电换能器，其包括与第一电极和第二电极接触的电介质弹性体，所述介电弹性体包含聚氨酯聚合物，其包含A）多异氰酸酯和/或B）多异氰酸酯预聚物与C）具有至少两个异氰酸酯反应性基团的化合物，其中多异氰酸酯预聚物B）和/或具有至少两个异氰酸酯反应性基团的化合物C）包括式（I）的聚四亚甲基二醇醚单元： - [O-CH 2 -CH 2 - CH2-CH2-] n（I）其中n≥25; 并且对于值n和对于选择的公式（I）中的值n的最大值nmax，使得nmax和nmin之间的差为≥0至＆lt; 1EE;对于值n为最小值nmin。本发明还提供了一种用于制造这种机电换能器的方法，以及包括本发明的机电换能器的电和/或电子装置的方法。

58. 发明授权

US07893189B2 Poly(ether-ester) polyols and processes for their production 失效
标题翻译：聚（醚 - 酯）多元醇及其生产方法
公开(公告)号：US07893189B2
公开(公告)日：2011-02-22
申请号：US12700050
申请日：2010-02-04
申请人： Klaus Lorenz , Jorg Hofmann , Hartmut Nefzger
发明人： Klaus Lorenz , Jorg Hofmann , Hartmut Nefzger
IPC分类号： C08G63/06
CPC分类号： C08G18/4887 , C08G65/2615 , C08G65/3311
摘要： The invention is directed to novel poly(ether-ester)polyols, processes for their production from monocarboxylic or polycarboxylic acid esters with one or more bound polyether chain(s). This invention also relates to the production of polyurethane materials in which the isocyanate-reactive component comprises these poly(ether-ester)polyols.
摘要翻译：本发明涉及新的聚（醚 - 酯）多元醇，其由具有一个或多个结合的聚醚链的单羧酸酯或多元羧酸酯生产的方法。本发明还涉及其中异氰酸酯反应性组分包含这些聚（醚 - 酯）多元醇的聚氨酯材料的生产。

59. 发明申请

US20100137552A1 POLY(ETHER-ESTER) POLYOLS AND PROCESSES FOR THEIR PRODUCTION 失效
标题翻译： POLY（ETER-ESTER）POLYOLS及其生产工艺
公开(公告)号：US20100137552A1
公开(公告)日：2010-06-03
申请号：US12700050
申请日：2010-02-04
申请人： Klaus Lorenz , Jorg Hofmann , Hartmut Nefzger
发明人： Klaus Lorenz , Jorg Hofmann , Hartmut Nefzger
IPC分类号： C08G63/16 , C08G18/34
CPC分类号： C08G18/4887 , C08G65/2615 , C08G65/3311
摘要： The invention is directed to novel poly(ethcr-ester) polyols, processes for their production from monocarboxylic or polycarboxylic acid esters with one or more bound polyether chain(s). This invention also relates to the production of polyurethane materials in which the isocyanate-reactive component comprises these poly(ether-ester)polyols.
摘要翻译：本发明涉及新的聚（乙酸酯）多元醇，其由具有一个或多个结合的聚醚链的单羧酸酯或多元羧酸酯生产的方法。本发明还涉及其中异氰酸酯反应性组分包含这些聚（醚 - 酯）多元醇的聚氨酯材料的生产。

60. 发明申请

US20090221071A1 Polyurea Systems, Processes for Preparing the Same and Use Thereof for Postoperative Adhesion Barriers 有权
标题翻译：聚脲系统，其制备方法及其应用于术后粘合屏障
公开(公告)号：US20090221071A1
公开(公告)日：2009-09-03
申请号：US12370639
申请日：2009-02-13
申请人： Heike Heckroth , Hartmut Nefzger , Christian Wamprecht
发明人： Heike Heckroth , Hartmut Nefzger , Christian Wamprecht
IPC分类号： C12N5/06 , C08G18/00 , C08L75/04 , C08K5/053
CPC分类号： C08G18/3821 , A61L15/26 , A61L31/06 , A61L31/148 , A61L2430/00 , C08G18/10 , C08G18/4252 , C08G18/4841 , C08G18/485 , C08G18/73 , C08G18/7621 , Y10T428/31551 , Y10T428/31594 , C08L75/02
摘要： Polyurea systems comprising: (a) an amino-functional aspartic ester of the general formula (I) wherein X represents an n-valent organic radical derived from a corresponding n-functional primary amine X(NH2)n, R1 and R2 each independently represent an organic radical having no Zerevitinov active hydrogens and n represents an integer of at least 2; and (b) an isocyanate functional prepolymer having a residual monomer content of less than 1% by weight, the prepolymer prepared by reacting: (b1) an aliphatic isocyante; and (b2) a polyol component having a number average molecular weight of ≧400 g/mol and an average OH functionality of 2 to 6, wherein the polyol component comprises one or more constituents selected from the group consisting of polyester polyols, polyester-polyether polyols and mixtures thereof; processes for making the same; postoperative adhesions barriers prepared therewith and dispensing systems for such polyurea systems.
摘要翻译：聚脲体系包括：（a）通式（I）的氨基官能天冬氨酸酯，其中X表示衍生自相应的正官能伯胺X（NH 2）n的n价有机基团，R 1和R 2各自独立地表示没有泽列维诺夫活性氢的有机基团，n表示至少2的整数; 和（b）具有小于1重量％的残余单体含量的异氰酸酯官能预聚物，所述预聚物通过使（b1）脂族异氰酸酯反应制备; 和（b2）数均分子量> = 400g / mol，平均OH官能度为2-6的多元醇组分，其中多元醇组分包括一种或多种选自聚酯多元醇，聚酯 - 聚醚多元醇及其混合物; 制作相同的过程; 用其制备的术后粘连屏障和用于这种聚脲系统的分配系统。

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