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    • 52. 发明专利
    • MX9204955A
    • 1993-03-01
    • MX9204955
    • 1992-08-27
    • HOECHST AG
    • BECK THOMASRUSS WERNER HUMBERTSPRINGER HARTMUTBANFER MARCUS
    • C07D487/22C09B62/44C09B62/517C09B62/00
    • Phthalocyanine dyes, in particular copper and nickel phthalocyanine dyes, which contain one or more groups of the formula given and defined below … … or one or more carboxyl groups or both groups and which furthermore can contain one or more sulpho groups, customary sulphonamide groups and/or groups of the formula given and defined below … … dye materials containing hydroxyl and/or carboxamide groups, in particular fibre materials, such as, for example, cellulose fibre materials, wool and polyamide fibres, in intense, fast, mainly green shades. … In the formulae:… R and R are both, independently of one another, hydrogen or a lower, optionally substituted, aliphatic radical, G is lower alkylene or is phenylene which can be substituted by lower alkyl, lower alkoxy, halogen, sulpho, carboxyl and/or nitro, or the group -N(R )-G-N(R )-forms the bivalent radical of a saturated heterocycle, W is halogen, lower alkoxy, aryloxy, sulpho, phenylsulphonyl, lower alkylsulphonyl or an optionally substituted amino group or is a radical of the formula N(R )-A-(Y-Z)m where R , A, Y, Z and m have the meaning given below, A is an aromatic carbocyclic or aromatic heterocyclic radical or an alkylene radical which can be interrupted by 1 or 2 hetero groups, or is an alkylenephenylene radical or the bivalent radical of a saturated heterocycle containing two N atoms, Y, in the case in which A represents an aromatic radical, is a direct bond or a carbamoylalkylene group or a methylene, ethylene, methylamino or b-cyanoethylamino group, or Y is lower alkylene, where in this case A compulsorily is a direct bond and m is equal to 2, Z is a fibre-reactive group of the vinylsulphone series, m is the number 1 or 2 and R is hydrogen or lower alkyl.
    • 53. 发明专利
    • BR9105942A
    • 1992-10-27
    • BR9105942
    • 1991-01-14
    • HOECHST AG
    • SPRINGER HARTMUTGLEISSNER ROLFSCHWAIGER GUENTHER
    • C09B62/503D06P1/384
    • PCT No. PCT/EP91/00041 Sec. 371 Date Jul. 17, 1992 Sec. 102(e) Date Jul. 17, 1992 PCT Filed Jan. 14, 1991 PCT Pub. No. WO91/10709 PCT Pub. Date Jul. 25, 1991.Water-soluble fiber-reactive dyes are described conforming to the below-indicated formula (1) which are capable of dyeing hydroxyl- and/or carboxamido-containing material, in particular fiber material, such as wool and in particular cellulose fiber materials, in strong, fast shades. (* CHEMICAL STRUCTURE *) (1) in which F is the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, triphenoldioxazine, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, formazan, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye; Rx is hydrogen or alkyl of 1 to 4 carbon atoms; R is hydrogen, sulfo, carboxyl, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms or chlorine; w is 1, 2, 3 or 4; Y is vinyl or an ethyl group which contains in the (beta)-position a substituent which is eliminable by alkali to form a vinyl group; n is 1 or 2.
    • 54. 发明专利
    • MX164319B
    • 1992-08-03
    • MX358186
    • 1986-08-28
    • HOECHST AG
    • SPRINGER HARTMUTSCHWAIGER GUNTHERHELMLING WALTER
    • C07D265/38C09B62/503D06P1/384D06P3/10D06P3/66
    • Water-soluble triphendioxazine compounds of the formula (1) having at least one sulfato or sulfo group, in which R is a hydrogen atom, a water-solubilizing group, an alkyl group having 1 to 6 carbon atoms which is substituted by an acidic group, or an optionally substituted sulfonamide group, B is an oxygen or sulfur atom or a group of the formula -NH-or -N(R')-, where R' equals optionally substituted alkyl, cycloalkyl which is optionally substituted by certain substituents, or optionally substituted phenyl, or naphthyl which is optionally substituted by sulfo and/or a -SO2-Y' group, B1 has one of the meanings stated for B and is identical to B or different from B, W is a bivalent aliphatic, araliphatic or aromatic radical which may be interrupted by 1 or 2 hetero groups from the series comprising groups of the formulae -O-, -NH-and -N(R')-, where R' has the above meaning, W1 has one of the meanings stated for W and is identical to W or different from W, T is a hydrogen atom or sulfo, sulfato, phosphato or carboxy, T1 has one of the meanings stated for T and is identical to T or different from T and T1 is necessarily a water-solubilizing group when R denotes hydrogen, R3 R4, identical or different, are each hydrogen, alkyl, alkoxy, halogen, carboxy or sulfo, X1 is hydrogen, halogen, cycloalkyl, arylkyloxy, alkoxy, aryloxy, alkyl, aryl, aralkyl, cyano, carboxyl, carbalkoxy, N-alkyl-substituted carbamoyl or N-aryl-substituted carbamoyl, alkanoylamino or optionally substituted aroylamino, X2 has one of the meanings stated for X1 and is identical to X1 or different from X1, Y is vinyl or ethyl which is substituted in the beta position by a substituent which can be eliminated by means of an alkali, Y' has one of the meanings stated for Y and is identical to Y or different from Y. These new compounds have fiber-reactive dyestuff properties and are particularly suitable for dyeing cellulose fiber materials so that they are fast.