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51. 发明授权

US5922865A Process for dyeing natural or synthetic polyamide fiber materials 失效
标题翻译：天然或合成聚酰胺纤维材料染色工艺
公开(公告)号：US5922865A
公开(公告)日：1999-07-13
申请号：US089141
申请日：1998-06-02
申请人： Jean-Marie Adam , Jean-Pierre Bacher , Francine Casi
发明人： Jean-Marie Adam , Jean-Pierre Bacher , Francine Casi
IPC分类号： C09B1/34 , C09B43/16 , D06P1/39 , D06P1/642 , D06P3/16 , D06P3/24 , D06P5/06 , C07D251/50 , C07D251/54
CPC分类号： D06P1/39 , C09B1/34 , C09B43/16 , D06P1/6426 , D06P3/16 , D06P3/241 , D06P5/06 , Y10S8/917 , Y10S8/924
摘要： Process for dyeing natural or synthetic polyamide fibre materials, which comprises dyeing these fibre materials with at least one anionic acid dye of the formula ##STR1## and treating the fibre material mentioned, during or after the dyeing process, with a colourless fixing agent which contains sulfo or sulfato groups and contains at least two fibre-reactive groups, whereR.sub.1 and R.sub.2 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,X.sub.1 is substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl,or the radical of the formula --N(R.sub.2)--X.sub.1 is a ring, which may contain further heteroatoms,Y.sub.1 is a radical of the formula ##STR2## in which B.sub.1 is a colourless organic bridge member,R.sub.3 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl andR.sub.4 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl, andA.sub.1 is as defined in claim 1.
摘要翻译：用于染色天然或合成聚酰胺纤维材料的方法，其包括用至少一种下式的阴离子酸性染料染色这些纤维材料，并在染色过程中或之后用含有磺基或硫酸酯的无色固色剂处理所述纤维材料并且包含至少两个纤维反应性基团，其中R 1和R 2彼此独立地是氢或取代或未取代的C 1 -C 4烷基，X 1是取代或未取代的C 1 -C 8烷基，C 5 -C 7环烷基，苯基或萘基或式-N（R2）-X1是可以含有其它杂原子的环，Y1是下式的基团，其中B1是无色有机桥连构件，R3是氢或取代或未取代的C1-C4烷基，R4是氢或取代或未取代的C1-C8烷基，C5-C7环烷基，苯基或萘基，A1如权利要求1所定义。

52. 发明授权

US5792222A Process for dyeing natural or synthetic polyamide fibre materials 失效
标题翻译：天然或合成聚酰胺纤维材料染色工艺
公开(公告)号：US5792222A
公开(公告)日：1998-08-11
申请号：US810714
申请日：1997-03-03
申请人： Jean-Marie Adam , Jean-Pierre Bacher , Francine Casi
发明人： Jean-Marie Adam , Jean-Pierre Bacher , Francine Casi
IPC分类号： C09B1/34 , C09B43/16 , D06P1/39 , D06P1/642 , D06P3/16 , D06P3/24 , D06P5/06
CPC分类号： D06P1/39 , C09B1/34 , C09B43/16 , D06P1/6426 , D06P3/16 , D06P3/241 , D06P5/06 , Y10S8/917 , Y10S8/924
摘要： Process for dyeing natural or synthetic polyamide fiber materials, which comprises dyeing these fiber materials with at least one anionic acid dye of the formula ##STR1## and treating the fiber material mentioned, during or after the dyeing process, with a colorless fixing agent which contains sulfo or sulfato groups and contains at least two fiber-reactive groups, where R.sub.1 and R.sub.2 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl, X.sub.1 is substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl, or the radical of the formula --N(R.sub.2)--X.sub.1 is a ring, which may contain further heteroatoms, Y.sub.1 is a radical of the formula ##STR2## in which B.sub.1 is a colorless organic bridge member, R.sub.3 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl and R.sub.4 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl, and A.sub.1 is as defined in claim 1.
摘要翻译：染色天然或合成聚酰胺纤维材料的方法，其包括用至少一种下式的阴离子酸性染料染色这些纤维材料（1），并在染色过程中或之后用无色固色剂处理所述纤维材料其包含磺基或硫酸基并且含有至少两个纤维反应性基团，其中R 1和R 2彼此独立地是氢或取代或未取代的C 1 -C 4烷基，X 1是取代或未取代的C 1 -C 8烷基，C 5 -C 7环烷基，苯基或萘基或式-N（R 2）-X 1的基团是可以含有其它杂原子的环，Y 1是下式的基团：无色有机桥构件，R 3是氢或取代或未取代的 C 1 -C 4烷基和R 4是氢或取代或未取代的C 1 -C 8烷基，C 5 -C 7环烷基，苯基或萘基，并且A 1如权利要求1中所定义。

53. 发明授权

US5762653A Dye mixtures, processes for their preparation and their use 失效
标题翻译：染料混合物，其制备方法及其用途
公开(公告)号：US5762653A
公开(公告)日：1998-06-09
申请号：US811449
申请日：1997-03-03
申请人： Jean-Marie Adam , Jean-Pierre Bacher
发明人： Jean-Marie Adam , Jean-Pierre Bacher
IPC分类号： C09B67/22
CPC分类号： C09B67/004 , Y10S534/01 , Y10S8/917 , Y10S8/924
摘要： Dye mixtures which comprise at least one dye of the formula ##STR1## and at least one dye of the formula ##STR2## in which Y.sub.1 is a radical of the formula ##STR3## and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6, R.sub.7, R.sub.8, X.sub.1, X.sub.2, X.sub.3, L, W.sub.1, B.sub.1, A.sub.1, and A.sub.3 are as defined in claim 1. The dye mixtures according to the invention are particularly suitable for dyeing or printing natural or synthetic polyamide fibre materials.
摘要翻译：包含至少一种下式的染料的染料混合物（1）和至少一种式（IMAGE）（2）的染料，其中Y1是下式的基团：（3a）（（3c）和R1，R2，R3，R4，R5，R6，R7，R8，X1，X2，X3，L，W1，B1，A1和A3如权利要求1中所定义。根据本发明的染料混合物特别适用于染色或印刷天然或合成聚酰胺纤维材料。

54. 发明授权

US5554738A Acyl-aryl disazo having a 6-ureido-1-hydroxy-naphthalene-3-sulfonic acid coupling component 失效
标题翻译：具有6-脲基-1-羟基 - 萘-3-磺酸偶联组分的酰基 - 芳基二偶氮
公开(公告)号：US5554738A
公开(公告)日：1996-09-10
申请号：US781634
申请日：1991-10-18
申请人： Jean-Marie Adam , Adolf K aser
发明人： Jean-Marie Adam , Adolf K aser
IPC分类号： C09B31/072 , C09B31/08 , C09D11/037 , D21H21/28
CPC分类号： C09D11/037 , C09B31/08 , D21H21/28
摘要： Anionic disazo dyes useful for dyeing and printing textile materials, paper and leather and for the preparation of inks of the formula ##STR1## wherein D, R.sup.3, R.sup.4, M, R.sup.5 and R.sup.7 are defined as in the specification.
摘要翻译：用于染色和印刷纺织材料，纸和皮革以及制备式（1）的油墨的阴离子双偶氮染料，其中D，R3，R4，M，R5和R7如说明书中所定义。

55. 发明授权

US4992569A Dicyanobenzanthrone compounds 失效
标题翻译：二氰基苯酮化合物
公开(公告)号：US4992569A
公开(公告)日：1991-02-12
申请号：US360579
申请日：1989-06-01
申请人： Jean-Marie Adam
发明人： Jean-Marie Adam
IPC分类号： C09B3/04 , D06P3/54
CPC分类号： C09B3/04
摘要： The dyes of the formula (1) as defined in claim 1 are suitable in particular for the dyeing of polyester textile material by the exhaust process.
摘要翻译：如权利要求1所定义的式（1）的染料特别适用于通过排气过程染色聚酯纺织材料。

56. 发明授权

US4957847A Heat-sensitive cyclic diazo compound containing recording material with benzotriazine compound and coupling component 失效
标题翻译：含有记录材料的热敏环状重氮化合物与苯并三嗪化合物和偶联组分
公开(公告)号：US4957847A
公开(公告)日：1990-09-18
申请号：US278989
申请日：1988-12-02
申请人： Jean-Marie Adam , Hans Baumann
发明人： Jean-Marie Adam , Hans Baumann
IPC分类号： B41M5/323 , G03C1/52
CPC分类号： G03C1/52
摘要： A heat-sensitive recording material comprising a base and, on top of the said base, a heat-sensitive layer containing a cyclic diazo component and a coupling component, the cyclic diazo component being a benzotriazine compound of the formula ##STR1## wherein Q is --CH.sub.2 --, --CO-- or --SO.sub.2 --, R is hydrogen, hydroxyl, or aryl or alkenyl, each unsubstituted or substituted by halogen, hydroxyl, cyano, lower alkoxy, lower alkylthio, acyloxy, lower alkoxycarbonyl or lower alkylsulfonyl, or is acyl, acyloxy or acylamino, cycloalkyl, or is aryl or aralkyl such as phenyl, phenylalkyl or naphthyl each unsubstituted or substituted on the ring by cyano, halogen, nitro, trifluoromethyl, lower alkyl, lower alkylthio, lower alkoxy, lower alkylcarbonyl or lower alkoxycarbonyl, or is a heterocyclic radical, and the benzene ring A is unsubstituted or substituted by halogen, cyano, nitro, lower alkyl, lower alkoxy, lower alkylthio, lower alkylcarbonyl or lower alkoxycarbonyl.
摘要翻译：一种热敏记录材料，其包含碱，并且在所述碱的顶部上包含含有环状重氮组分和偶联组分的热敏层，所述环状重氮组分为下式的苯并三嗪化合物（1）其中Q为-CH 2 - ， - CO - 或-SO 2 - ，R 2为氢，羟基或芳基或链烯基，各自未被取代或被卤素，羟基，氰基，低级烷氧基，低级烷硫基，酰氧基，低级烷氧基羰基或低级烷基磺酰基或者是酰基，酰氧基或酰氨基，环烷基，或芳基或芳烷基，例如苯基，苯基烷基或萘基，其各自未被取代或在环上被氰基，卤素，硝基，三氟甲基，低级烷基，低级烷硫基，低级烷氧基，低级烷基羰基或低级烷氧基羰基，或为杂环基，苯环A为未取代的或被卤素，氰基，硝基，低级烷基，低级烷氧基，低级烷硫基，低级烷基羰基或低级烷氧羰基取代。

57. 发明授权

US4785096A Process for the preparation of 1,4-diamino-2,3-dicyanoanthraquinones 失效
公开(公告)号：US4785096A
公开(公告)日：1988-11-15
申请号：US145024
申请日：1988-01-19
申请人： Jean-Marie Adam
发明人： Jean-Marie Adam
IPC分类号： C07C255/58 , C07C67/00 , C07C253/00 , C07F5/04 , C09B1/22 , C07C97/24 , C07D223/26
CPC分类号： C07F5/04 , C09B1/22
摘要： There is disclosed a process for the preparation of 1,4-diamino-2,3-dicyanoanthraquinones by reacting compounds of formula ##STR1## wherein X.sub.1 and X.sub.2 are hydroxyl, halogen, acetate or sulfato ester, or, when taken together, are an oxygen atom attached by a double bond to the boron atom, R is a substituent and n is 0, 1 or 2, with an inorganic cyanide in a polar aprotic solvent and in the presence of an oxidizing agent, and subsequently hydrolyzing the reaction product.

58. 发明授权

US4693727A Process for dyeing synthetic polyamide materials with fibre-reactive anthraquinone dyes 失效
标题翻译：用纤维反应性蒽醌染料染色合成聚酰胺材料的方法
公开(公告)号：US4693727A
公开(公告)日：1987-09-15
申请号：US841064
申请日：1986-03-18
申请人： James B. Bowles , Marshall White, Jr. , Alois Puentener , Jean-Marie Adam , Peter Loew
发明人： James B. Bowles , Marshall White, Jr. , Alois Puentener , Jean-Marie Adam , Peter Loew
IPC分类号： C09B62/467 , C09B67/22 , D06P3/24 , D06P1/38 , C09B67/26
CPC分类号： C09B67/0038 , C09B62/467 , D06P3/248 , Y10S8/924 , Y10S8/929
摘要： Process for preparing ozone-fast dyeings on synthetic polyamide fibre materials from aqueous liquor with anthraquinone dyes which comprises using at least one anthraquinone dye which contains one or two fibre-reactive groups and one or two sulfo groups.The process according to the invention is suitable for dyeing synthetic polyamide materials producing with the monosulfoanthraquinone or disulfoanthraquinone dyes which contain one or two fibre-reactive groups level dyeings having good fastness properties, in particular good ozone fastness.
摘要翻译：在含有蒽醌染料的水性液体中制备合成聚酰胺纤维材料上的臭氧快速染色的方法，其包括使用至少一种含有一个或两个纤维反应性基团和一个或两个磺基的蒽醌染料。根据本发明的方法适用于用单磺酸蒽醌或二磺基蒽醌染料生产合成聚酰胺材料，所述染料含有一种或两种具有良好牢度性质的纤维反应性基团染色，特别是良好的耐臭氧性。

59. 发明授权

US4656268A Benzoquinophthalone quaternary ammonium salt derivatives 失效
标题翻译：苯并喹酞酮季铵盐衍生物
公开(公告)号：US4656268A
公开(公告)日：1987-04-07
申请号：US788811
申请日：1985-10-18
申请人： Jean-Marie Adam
发明人： Jean-Marie Adam
IPC分类号： C09B25/00 , D21H21/28 , C07D401/12 , C07D401/14 , C07D413/12
CPC分类号： D21H21/28 , C09B25/00
摘要： There are described novel cationic quinophthalone compounds of the formula I ##STR1## wherein the symbols have the meanings defined in claim 1, and also processes for producing them. These novel quinophthalone compounds can be used in particular as dyes for dyeing and printing paper, greenish-yellow dyeings having good fastness to water and to light being obtained.
摘要翻译：描述了式I（I）的新型阳离子喹酞酮化合物，其中符号具有权利要求1中定义的含义，并且还涉及制备它们的方法。这些新颖的喹酞酮化合物特别可用作染色和印刷纸的染料，具有良好的耐水牢度和获得光的绿黄色染色剂。

60. 发明授权

US4244691A Novel water-soluble anthraquinone dyes 失效
标题翻译：新型水溶性蒽醌染料
公开(公告)号：US4244691A
公开(公告)日：1981-01-13
申请号：US94852
申请日：1979-11-16
申请人： Jean-Marie Adam
发明人： Jean-Marie Adam
IPC分类号： C09B1/54 , C09B62/004 , C07C143/665 , C09B1/52 , C09B5/62
CPC分类号： C09B62/004 , C09B1/547
摘要： The invention relates to novel, water-soluble anthraquinone dyes which, in the form of the free acid, have the formula I ##STR1## in which X is halogen, R.sub.1 is an unbranched or branched alkyl radical having 4 to 8 carbon atoms, R.sub.2 and R.sub.3 independently of one another are an unbranched or branched alkyl radical having 1 to 4 carbon atoms, R.sub.4 is hydrogen, an unbranched or branched alkyl radical having 1 to 4 carbon atoms, a free or acylated amino group or a fibre-reactive radical bonded via an amino group, R.sub.5 is hydrogen or an unbranched or branched alkyl radical having 1 to 4 carbon atoms and R.sub.6 and R.sub.7 independently of one another are hydrogen, an unbranched or branched alkyl radical having 1-4 carbon atoms, a --SO.sub.3 H group, halogen or a radical of the formula --CH.sub.2 --NH--CO--Y, in which Y is an alkyl or alkenyl radical having 1 to 4 carbon atoms which is unsubstituted or substituted by one or two halogen atoms, or is a substituted or unsubstituted phenyl radical, with the proviso that at least one of the radicals R.sub.6 or R.sub.7 is a --SO.sub.3 H group.
摘要翻译：本发明涉及新的水溶性蒽醌染料，其以游离酸的形式具有其中X为卤素的式I（I），R 1为具有4-8个碳原子的无支链或支链烷基原子，R2和R3彼此独立地是具有1至4个碳原子的无支链或支链烷基，R4是氢，具有1至4个碳原子的无支链或支链烷基，游离或酰化氨基或纤维 - 通过氨基键合的反应性自由基，R 5是氢或具有1至4个碳原子的无支链或支链烷基，R 6和R 7彼此独立地是氢，具有1-4个碳原子的无支链或支链烷基， SO 3 H基，卤素或式-CH 2 -NH-CO-Y的基团，其中Y是未被取代或被一个或两个卤素原子取代的具有1至4个碳原子的烷基或烯基，或是取代的或未取代的苯基，条件是在下列化合物中基团R6或R7中的一个是-SO 3 H基团。

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