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51. 发明授权

EP1401795B1 SELECTIVE PRODUCTION OF META-DIISOPROPYLBENZENE 有权
标题翻译：工艺荟萃二异丙苯的选择性生产
公开(公告)号：EP1401795B1
公开(公告)日：2007-12-05
申请号：EP02728659.0
申请日：2002-04-03
申请人： ExxonMobil Chemical Patents Inc.
发明人： BRYAN, Francis, S. , WEBER, William, A. , BROWN, Stephen, H. , CHENG, Jane, C. , SMITH, Morris, C.
IPC分类号： C07C15/02 , C07C6/12
CPC分类号： C07C15/02 , C07C2/66 , C07C6/126 , C07C2529/70
摘要： In a process for the selective production of meta-diisopropylbenzene, a C9+ aromatic hydrocarbon feedstock containing meta- and ortho-diisopropylbenzene is contacted with benzene under conversion conditions with a catalyst comprising a molecular sieve selected from the group consisting of zeolite beta, mordenite and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including the d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom. The contacting step selectively converts ortho-diisopropylbenzene in the feedstock to produce an effluent in which the ratio of meta-diisopropylbenzene to ortho-diisopropylbenzene is greater than that of the feedstock. The effluent is the fed to a separation zone for recovery of a product rich in meta-diisopropylbenzene.

52. 发明授权

EP2435390B1 TRANSALKYLATION OF POLYCYCLOHEXYLBENZENES 有权
标题翻译：过氧化物聚氧乙烯苯乙烯
公开(公告)号：EP2435390B1
公开(公告)日：2016-08-17
申请号：EP10780963.4
申请日：2010-04-14
申请人： ExxonMobil Chemical Patents Inc.
发明人： WANG, Kun , CHENG, Jane, C. , HELTON, Terry, Eugene
IPC分类号： C07C4/18 , C07C13/28 , C07C2/74 , C07C37/08 , C07C39/04
CPC分类号： C07C409/14 , C07C2/74 , C07C6/126 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2521/04 , C07C2521/06 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C39/04 , C07C49/403

53. 发明授权

EP2282984B1 PROCESS FOR PRODUCING CYCLOHEXYLBENZENE 有权
标题翻译：生产环己基苯的方法
公开(公告)号：EP2282984B1
公开(公告)日：2012-11-21
申请号：EP09739318.5
申请日：2009-02-23
申请人： Exxonmobil Chemical Patents Inc.
发明人： CHEN, Tan-Jen , CHENG, Jane, C. , BENITEZ, Francisco, M. , HELTON, Terry, E. , STANAT, Jon, E.
IPC分类号： C07C2/74 , C07C45/53 , C07C13/28 , C07C49/403 , C07C6/12 , C07C37/06 , C07C37/08 , C07C39/04
CPC分类号： C07C37/06 , C07C2/74 , C07C6/126 , C07C37/08 , C07C45/53 , C07C2521/04 , C07C2521/06 , C07C2523/06 , C07C2523/14 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2601/14 , Y02P20/52 , C07C13/28 , C07C49/403 , C07C39/04

54. 发明授权

EP2178813B1 PROCESS FOR PRODUCING SEC-BUTYLBENZENE 有权
标题翻译：用于生产仲丁基苯
公开(公告)号：EP2178813B1
公开(公告)日：2011-03-23
申请号：EP08785026.9
申请日：2008-07-11
申请人： ExxonMobil Chemical Patents Inc. , Exxonmobil Chemical Limited
发明人： CHENG, Jane, C. , DAKKA, Jihad, M. , REINE, Travis, A. , STANAT, Jon, E.
IPC分类号： C07C2/66 , C07C37/08 , C07C39/04 , C07C45/53
CPC分类号： C07C409/08 , C07C2/66 , C07C37/08 , C07C45/53 , C07C407/00 , Y02P20/127 , C07C15/02 , C07C49/10 , C07C39/04
摘要： A process for producing sec-butylbenzene comprises feeding reactants comprising benzene and a C4 olefin to a distillation column reactor having a first reaction zone containing an alkylation catalyst and a second distillation zone, which is located below said first reaction zone and which is substantially free of alkylation catalyst, wherein the ratio of the number of distillation stages in said first reaction zone to the number of distillation stages in said second distillation zone is less than 1 : 1. Concurrently in the distillation column reactor, the reactants are contacted with the alkylation catalyst in the first reaction zone under conditions such that the C4 olefin reacts with the benzene to produce sec-butylbenzene and the sec-butylbenzene is fractionated from the unreacted C4 olefin. The sec-butylbenzene thereby passes as a liquid phase stream from the first reaction zone to the second distillation zone and the liquid phase stream is withdrawn from the distillation column reactor as bottoms.

55. 发明授权

EP1984311B1 PROCESS FOR PRODUCING PHENOL AND METHYL ETHYL KETONE 有权
标题翻译：用于生产苯酚和甲基
公开(公告)号：EP1984311B1
公开(公告)日：2010-09-01
申请号：EP07711517.8
申请日：2007-02-08
申请人： ExxonMobil Chemical Patents Inc.
发明人： DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , CHENG, Jane, C. , BENITEZ, Francisco, M. , STANAT, Jon, E. , BUCHANAN, John, S.
IPC分类号： C07C2/66 , C07C45/36 , C10G29/20 , B01J29/70
CPC分类号： C07C409/08 , C07C2/66 , C07C6/126 , C07C15/02 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/70 , C10G29/205 , C10G2300/1092 , C10G2300/1096 , C10G2300/4018 , Y02P20/52 , C07C49/10 , C07C39/04
摘要： A process for producing phenol and methyl ethyl ketone comprises contacting benzene and a C4 olefin under alkylation conditions and in the presence of an alkylation catalyst to produce an alkylation effluent comprising secbutylbenzene and C8+ olefins. The alkylation effluent is then treated to reduce the amount of said C8+ olefins and produce a treated effluent, whereafter the secbutylbenzene in the treated effluent is oxidized to produce a hydroperoxide and the hydroperoxide is cleaved to produce phenol and methyl ethyl ketone.

56. 发明公开

EP2200954A1 PROCESS FOR PRODUCING CYCLOHEXYLBENZENE 失效
标题翻译：用于生产环己基苯
公开(公告)号：EP2200954A1
公开(公告)日：2010-06-30
申请号：EP08797654.4
申请日：2008-08-12
申请人： ExxonMobil Chemical Patents Inc.
发明人： CHEN, Tan-jen , BENITEZ, Francisco, M. , CHENG, Jane, C. , STANAT, Jon, E. , BUCHANAN, J., Scott
IPC分类号： C07C2/74 , C07C13/28
CPC分类号： C07C2/74 , Y02P20/52 , C07C13/28
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone. The benzene and hydrogen are then contacted in the at least one reaction zone under hydroalkylation conditions with a catalyst system comprising a molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and at least one hydrogenation metal to produce an effluent containing cyclohexylbenzene. The ratio of the total number of moles of hydrogen fed to said at least one reaction zone to the number of moles of benzene fed to said at least one reaction zone is between 0.4 and 0.9: 1.

57. 发明公开

EP2178813A1 PROCESS FOR PRODUCING SEC-BUTYLBENZENE 有权
标题翻译：用于生产仲丁基苯
公开(公告)号：EP2178813A1
公开(公告)日：2010-04-28
申请号：EP08785026.9
申请日：2008-07-11
申请人： ExxonMobil Chemical Patents Inc. , Exxonmobil Chemical Limited
发明人： CHENG, Jane, C. , DAKKA, Jihad, M. , REINE, Travis, A. , STANAT, Jon, E.
IPC分类号： C07C2/66 , C07C37/08 , C07C39/04 , C07C45/53
CPC分类号： C07C409/08 , C07C2/66 , C07C37/08 , C07C45/53 , C07C407/00 , Y02P20/127 , C07C15/02 , C07C49/10 , C07C39/04
摘要： A process for producing sec-butylbenzene comprises feeding reactants comprising benzene and a C4 olefin to a distillation column reactor having a first reaction zone containing an alkylation catalyst and a second distillation zone, which is located below said first reaction zone and which is substantially free of alkylation catalyst, wherein the ratio of the number of distillation stages in said first reaction zone to the number of distillation stages in said second distillation zone is less than 1 : 1. Concurrently in the distillation column reactor, the reactants are contacted with the alkylation catalyst in the first reaction zone under conditions such that the C4 olefin reacts with the benzene to produce sec-butylbenzene and the sec-butylbenzene is fractionated from the unreacted C4 olefin. The sec-butylbenzene thereby passes as a liquid phase stream from the first reaction zone to the second distillation zone and the liquid phase stream is withdrawn from the distillation column reactor as bottoms.

58. 发明公开

EP1218324A1 ALKYLAROMATICS PRODUCTION 有权
标题翻译：用于生产烷基芳烃
公开(公告)号：EP1218324A1
公开(公告)日：2002-07-03
申请号：EP01950620.3
申请日：2001-06-26
申请人： ExxonMobil Chemical Patents Inc.
发明人： CHENG, Jane, C. , SMITH, C., Morris , WEBER, William, A. , BROWN, Stephen, H. , STECKEL, Michael, A. , DANDEKAR, Ajit, B. , BETTER, Michael, A.
IPC分类号： C07C6/12 , C07C15/085
CPC分类号： C07C15/085 , C07C6/126 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2529/80 , Y02P20/52
摘要： The present invention provides a process for producing a monoalkylated aromatic compound, particularly cumene, comprising the step of contacting a polyalkylated aromatic compound with an alkylatable aromatic compound under at least partial liquid phase conditions and in the presence of a transalkylation catalyst to produce the monoalkylated aromatic compound, wherein the transalkylation catalyst comprises a mixture of at least two different crystalline molecular sieves, wherein each of said molecular sieves is selected from zeolite beta, zeolite Y, mordenite and a material having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25,6.9±0.15,3.57±0.07 and 3,42±0.07 Angstrom.

59. 发明公开

EP3371138A2 PROCESS FOR CONVERSION OF ACYCLIC C5 COMPOUNDS TO CYCLIC C5 COMPOUNDS AND CATALYST COMPOSITION FOR USE THEREIN 审中-实审
公开(公告)号：EP3371138A2
公开(公告)日：2018-09-12
申请号：EP16862666.1
申请日：2016-10-07
申请人： ExxonMobil Chemical Patents Inc.
发明人： IACCINO, Larry, L. , BEDARD, Jeremy, W. , LAI, Wenyih, F. , CARR, Robert, T. , CHENG, Jane, C.
IPC分类号： C07C5/333 , C07C13/15 , C07C9/15 , B01J29/42 , B01J38/10 , C07C2/50
CPC分类号： C07C5/373 , B01J29/44 , B01J29/90 , B01J38/12 , B01J2229/186 , C07C2529/44 , Y02P20/584 , C07C13/15
摘要： Disclosed is a process for the conversion of acyclic C5 feedstock to a product comprising cyclic C5 compounds, such as, for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprises the steps of contacting said feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a microporous crystalline aluminosilicate having a constraint index in the range of 3 to 12, a Group 10 metal, and, optionally, a Group 11 metal, in combination with a Group 1 alkali metal and/or a Group 2 alkaline earth metal.

60. 发明公开

EP2411351A2 PROCESS FOR PRODUCING CYCLOHEXYLBENZENE 无效
标题翻译：生产环己基苯的方法
公开(公告)号：EP2411351A2
公开(公告)日：2012-02-01
申请号：EP09840945.1
申请日：2009-11-24
申请人： ExxonMobil Chemical Patents Inc.
发明人： CHEN, Tan-jen , BENITEZ, Francisco, M. , CHENG, Jane, C. , STANAT, Jon, E.
IPC分类号： C07C13/28 , C07C2/74 , B01J29/74 , B01J8/02
CPC分类号： B01J29/7676 , B01J29/7476 , C07C2/76 , Y02P20/52 , C07C13/28
摘要： In a process for producing cyclohexylbenzene, benzene and hydrogen are fed to at least one reaction zone comprising a catalyst system which comprises a molecular sieve and at least one hydrogenation metal. The MCM-22 family molecular sieve having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07 Angstrom, and the hydrogenation metal is selected from the group consisting of palladium, ruthenium, nickel, zinc, tin, cobalt, and combinations of any two or more thereof. Hydroalkylation conditions of temperature and pressure are selected to produce a hydroalkylation conversion in a range of from about 15% to about 75% The benzene and hydrogen are then contacted in the at least one reaction zone under said selected hydroalkylation condition to produce an effluent containing cyclohexylbenzene.
摘要翻译：在生产环己基苯的方法中，将苯和氢进料到至少一个包含催化剂体系的反应区，所述催化剂体系包含分子筛和至少一种氢化金属。具有包括在12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07埃处的d间距最大值的X射线衍射图的MCM-22家族分子筛和氢化金属选自钯，钌，镍，锌，锡，钴及其任何两种或更多种的组合。选择温度和压力的加氢烷基化条件以产生在约15％至约75％范围内的加氢烷基化转化率。然后在所述选定的加氢烷基化条件下，在至少一个反应区中使苯和氢接触以产生含有环己基苯。

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