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    • 54. 发明公开
    • VERFAHREN ZUR HERSTELLUNG VON ULTRAFEINEN PULVERN AUF BASIS POLYMAIDEN, ULTRAFEINEN POLYAMIDPULVERN SOWIE DEREN VERWENDUNG
    • PROCESS基于聚酰胺,超细尼龙粉末和用途及其生产超细粉
    • EP1943296A1
    • 2008-07-16
    • EP06807176.0
    • 2006-10-12
    • Evonik Degussa GmbH
    • HÄGER, HaraldBAUMANN, Franz-ErichLORTZ, WolfgangBATZ-SOHN, Christoph
    • C08J3/12C09D177/00
    • C08J3/12C08J3/128C08J3/14C08J2377/00C09D177/00Y10S524/904
    • Process for producing ultrafine powders based on polyamides, in which polyamides having a relative solution viscosity ηrel in the range from 1.5 to 2.0, measured in 0.5% strength m-cresol solution at 25°C, are brought into contact with an alcoholic medium in the presence of inorganic particles under superatmospheric pressure and/or elevated temperature to produce an at least partial solution and the polyamide is subsequently precipitated from the at least partial solution, characterized in that a suspension of the inorganic particles suspended in the alcoholic medium is used. The resulting ultrafine polyamide powders have a specific surface area determined by the BET method in the range 5-100 m2/g, a fineness d50 of less than 70 µm; a bulk density BD in the range from 250 to 1000 g/l; and a particle content of from 0.1 to 80% by weight of inorganic particles based on the total weight of the polyamide powder. They are suitable both for coatings and for shaped parts and components having improved mechanical properties.
    • 过程,用于基于由在无机的存在下在醇介质中接触聚酰胺在25℃下具有在1.5至2.0的范围内的相对溶液粘度〔η相对,在0.5%间甲酚溶液中测量,以制备聚酰胺超细粉 的压力和/或温度作用下的颗粒以产生用于至少部分解决方案,然后沉淀从所述至少部分解的聚酰胺,其特征在于在没有使用悬浮在醇介质中的无机颗粒的悬浮液。 所得超细聚酰胺粉末具有在5的范围内的BET比表面积为100米2 /克; 小于70微米的细度D50; 到表观密度AD范围为250至1000克/升; 并且基于该聚酰胺粉末的总重量的0.1〜80%的颗粒含量按重量计的无机粒子。 它们同样适用于涂料和用于模制品和组件具有改进的机械性能。
    • 57. 发明授权
    • POLYMERPULVER AUF DER BASIS VON POLYAMIDEN, VERWENDUNG IN EINEM FORMGEBENDEN VERFAHREN UND FORMKÖRPER, HERGESTELLT AUS DIESEM POLYMERPULVER
    • POLYMERPULVER AUF DER BASIS VON POLYAMIDIDEN,VERWENDUNG in EINEM FORMGEBENDEN VERFAHREN UNDFORMKÖRPER,HERGESTELLT AUS DIESEM POLYMERPULVER
    • EP2556115B1
    • 2013-12-04
    • EP11714254.7
    • 2011-04-06
    • Evonik Degussa GmbH
    • BAUMANN, Franz-ErichDIEKMANN, WolfgangKÜTING, BeatriceSTEMMER, HeikeGREBE, MaikWARNKE, KristianeMONSHEIMER, SylviaHÄGER, Harald
    • C08L77/02C08L77/06B29C67/00
    • B29C64/106B29C64/153B33Y70/00C08L77/02C08L77/06C08L2205/02C09D5/03Y10T428/2982
    • The invention relates to a polymer powder for use in a layer-by-layer method in which areas of each powder layer are selectively fused by introducing electromagnetic energy. Said polymer powder contains: at least one AB-type polyamide produced by polymerizing lactams comprising 10 to 12 carbon atoms in the monomer unit or polycondensing the corresponding ω-amino carboxylic acids comprising 10 to 12 carbon atoms in the monomer unit and at least one AABB-type polyamide produced by polycondensing diamines and dicarboxylic acids, each of which comprises 10 to 14 carbon atoms in the monomer units, the AB-type polyamide containing up to 20 mole % of the AABB comonomer units and the AABB-type polyamide containing up to 20 mole % of the AB monomer units. The invention also relates to a method for producing such a powder, a layer-by-layer method for producing a molded article from such a powder in which areas of each layer are selectively fused by introducing electromagnetic energy, the selectivity being obtained using masks or by applying inhibitors, absorbers or susceptors or focusing the applied energy, and molded articles produced in said manner.
    • 本发明涉及一种逐层法使用的聚合物粉末,其中通过引入电磁能将每个粉末层的区域选择性地熔合。 所述聚合物粉末包含:至少一种AB型聚酰胺,其通过在单体单元中聚合包含10至12个碳原子的内酰胺或者在单体单元中缩聚包含10至12个碳原子的相应的ω-氨基羧酸和至少一种 AABB型聚酰胺,其通过缩聚二胺和二羧酸而制备,每种单体在单体单元中包含10至14个碳原子,AB型聚酰胺含有至多20摩尔%的AABB共聚单体单元和AABB型聚酰胺, 至20摩尔%的AB单体单元。 本发明还涉及生产这种粉末的方法,用这种粉末生产模塑制品的逐层方法,其中通过引入电磁能量选择性地熔化每层的区域,使用掩模或 通过施加抑制剂,吸收剂或感受器或聚焦所施加的能量,以及以所述方式生产的模制品。