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    • 52. 发明授权
    • Triazolylthiophosphoric acid esters
    • 三唑基硫代磷酸酯
    • US3956306A
    • 1976-05-11
    • US299488
    • 1972-10-20
    • Dag DawesBeat Bohner
    • Dag DawesBeat Bohner
    • A01N57/24C07F9/6518C07D249/12
    • A01N57/24C07F9/65183
    • Triazolylthiophosphonic esters corresponding to the formula ##SPC1##Wherein R.sub.1 represents a phenyl radical which is substituted by one or more fluorine, bromine and/or iodine atoms, by lower alkyl, lower alkoxy, lower alkylthio, lower trihalogenoalkyl, lower alkyl-SO, lower alkyl-SO.sub.2 or O.sub.2 N groups, which may be the same or different, or by at least one chlorine and at least one fluorine, bromine or iodine atom, one lower alkyl, lower alkoxy, lower alkylthio, lower trihalogenoalkyl, lower alkyl-SO, lower alkyl-SO.sub.2 or O.sub.2 N group, or represents an unsubstituted or halogenated and/or alkoxylated phenyl-lower alkyl radical or diphenylmethyl, and one of the symbols R.sub.2 and R.sub.3 represents hydrogen or a lower alkyl radical and the other represents the radical ##EQU1## wherein R.sub.4 represents a lower alkyl radical or the phenyl radical and R.sub.5 represents a lower alkyl radical their manufacture and their use in pest control.
    • 对应于式WHEREIN R1的三唑基硫代膦酸酯代表被一个或多个氟,溴和/或碘原子取代的苯基,被低级烷基,低级烷氧基,低级烷硫基,低级三卤代烷基,低级烷基-SO,低级烷基-SO 2 或O 2 N基团,其可以相同或不同,或至少一个氯和至少一个氟,溴或碘原子,一个低级烷基,低级烷氧基,低级烷硫基,低级三卤代烷基,低级烷基-SO,低级烷基 - SO 2或O 2 N基团,或表示未取代或卤化的和/或烷氧基化的苯基 - 低级烷基或二苯基甲基,并且符号R2和R3之一表示氢或低级烷基,另一个表示基团R 4 -OP ANGLE PARALLEL SOR5 其中R4代表低级烷基或苯基,R5表示低级烷基,它们的制备及其在病虫害防治中的用途。
    • 56. 发明授权
    • Herbicidal esters, compositions and use
    • 除草酯,组合物和用途
    • US4917721A
    • 1990-04-17
    • US10927
    • 1987-02-05
    • Georg PissiotasHans MoserBeat Bohner
    • Georg PissiotasHans MoserBeat Bohner
    • A01N43/00C07D209/48C07D401/12C07D403/12C07D405/12C07D409/12C07D413/12C07D417/12C07D521/00
    • C07D209/48C07D231/12C07D233/56C07D249/08C07D401/12C07D403/12C07D405/12C07D409/12C07D417/12
    • Novel 5-(N-3,4,5,6-tetrahydrophthalimido)benzoic acid esters of formula I below have good selective herbicidal properties pre- and postemergence and also influence or inhibit plant growth.The novel compounds are of formula I ##STR1## wherein n is 0, 1 or 2,R is C.sub.1 -C.sub.3 alkyl,R.sub.1 is hydrogen or halogen,R.sub.2 is halogen,X is oxygen or sulfur,A is a straight chain or branched C.sub.1 -C.sub.4 alkylene bridge,Q is a 5- or 6-membered heterocycle which is bound through carbon or nitrogen and contains 1 to 3 hetero atoms and may further contain one or two carbonyl groups, which heterocycle may be fused to benzene rings and substituted by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy, nitro, cyano, C.sub.1 -C.sub.3 alkylamino or di(C.sub.1 -C.sub.3)alkylamino, or Q is C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfonyl, C.sub.2 -C.sub.8 alkoxyalkyl, nitro or di(C.sub.1 -C.sub.4)alkylamino, or is a benzyloxy, phenoxy or phenylthio radical, each of which may be substituted in the phenyl nucleus by halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy, nitro, cyano, C.sub.1 -C.sub.3 alkylamino or di(C.sub.1 -C.sub.3)alkylamino, or, if X is sulfur, Q may also be a COOR.sub.3 radical, in which R.sub.3 is C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.6 alkenyl, C.sub.3 -C.sub.6 alkynyl or C.sub.3 -C.sub.7 cycloalkyl, each of which is unsubstituted or substituted by halogen or C.sub.1 -C.sub.4 alkoxy.
    • 下面式I的新型5-(N-3,4,5,6-四氢邻苯二甲酰亚氨基)苯甲酸酯在芽前和芽后具有良好的选择性除草性,并且还影响或抑制植物生长。 新化合物具有式I的化合物,其中n为0,1或2,R为C 1 -C 3烷基,R 1为氢或卤素,R 2为卤素,X为氧或硫,A为直链或 支链C1-C4亚烷基桥,Q是5-或6-元杂环,其通过碳或氮结合并含有1至3个杂原子,并且可以进一步含有一个或两个羰基,该杂环可以与苯环稠合并被取代 卤素,C1-C4烷基,C1-C3卤代烷基,C1-C3烷氧基,C1-C3卤代烷氧基,硝基,氰基,C1-C3烷基氨基或二(C1-C3)烷基氨基,或Q是C1-C4烷硫基,C1-C4烷基磺酰基,C2-C8烷氧基烷基, 硝基或二(C1-C4)烷基氨基,或是苄氧基,苯氧基或苯硫基,它们各自可以在苯基中被卤素,C 1 -C 4烷基,C 1 -C 3卤代烷基,C 1 -C 3烷氧基,C 1 -C 3卤代烷氧基,硝基 ,氰基,C 1 -C 3烷基氨基或二(C 1 -C 3)烷基氨基,或者如果X是硫,则Q也可以是COOR 3基团,其中R 3是C 1 -C 20烷基,C 3 -C 6烯基,C 3 -C 6炔基或C 3 -C 7环 烷基,其各自是未取代的或被卤素或C 1 -C 4烷氧基取代。
    • 58. 发明授权
    • Herbicidal and insecticidal triazinones
    • 除草和杀虫三嗪酮
    • US4801708A
    • 1989-01-31
    • US133204
    • 1987-12-15
    • Beat BohnerHans Tobler
    • Beat BohnerHans Tobler
    • C07D253/06A01N43/707C07C67/00C07C239/00C07C281/16C07D249/08C07D253/075C07D333/00C07D405/04C07D409/04C07D487/04
    • C07D253/075A01N43/707C07D405/04C07D409/04C07D487/04
    • The invention relates to 4-methylamino-1,2,4-triazin-5-one of the formula I ##STR1## wherein R.sup.1 is C.sub.3 -C.sub.8 cycloalkyl or C.sub.3 -C.sub.8 cycloalkyl which is substituted by C.sub.1 -C.sub.4 alkyl; C.sub.3 -C.sub.8 halocycloalkyl, C.sub.3 -C.sub.8 alkyl, C.sub.3 -C.sub.8 haloalkyl, 2-furyl, 2-thienyl, phenyl, benzyl, or phenyl or benzyl each substituted by one or more members selected from the group consisting of halogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 haloalkoxy,R.sup.2 is hydrogen or methyl, andR.sup.3 is cyclopropyl, cyclopropylmethyl, C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.4 alkenyl or C.sub.3 -C.sub.4 alkynyl.These compounds have selective herbicidal properties and are therefore pre-eminently suitable for controlling weeds in crops of useful plants, for example in cereals, maize, soybeans and sugar cane. They are also suitable for controlling harmful insects.
    • 本发明涉及式I(I)的4-甲基氨基-1,2,4-三嗪-5-酮,其中R 1是被C 1 -C 4烷基取代的C 3 -C 8环烷基或C 3 -C 8环烷基; C 3 -C 8卤代烷基,C 3 -C 8烷基,C 3 -C 8卤代烷基,2-呋喃基,2-噻吩基,苯基,苄基或苯基或苄基,其各自被一个或多个选自卤素,C 1 -C 4烷基,C 1 -C 4卤代烷基 ,C 1 -C 4烷氧基或C 1 -C 4卤代烷氧基,R 2是氢或甲基,R 3是环丙基,环丙基甲基,C 1 -C 4烷基,C 3 -C 4链烯基或C 3 -C 4炔基。 这些化合物具有选择性除草性质,因此特别适用于控制有用植物作物中的杂草,例如在谷物,玉米,大豆和甘蔗中。 它们也适用于防治害虫。