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    • 53. 发明授权
    • Multi-layer cover golf ball having non-ionomeric intermediate cover layer
    • 具有非离聚物中间覆盖层的多层覆盖高尔夫球
    • US08251838B2
    • 2012-08-28
    • US12399322
    • 2009-03-06
    • Michael J. SullivanBrian ComeauMark L. Binette
    • Michael J. SullivanBrian ComeauMark L. Binette
    • A63B37/06
    • A63B37/0043A63B37/0003A63B37/0039
    • A golf ball including a core and a cover disposed adjacent the core, the cover including an ionomeric thermoplastic inner cover layer disposed about the core and having a hardness of 55 Shore D to 60 Shore D; a castable thermoset polyurethane outer cover layer having a hardness between 55 Shore D and 60 Shore D; and a non-ionomeric thermoplastic intermediate cover layer disposed between the inner and outer cover layers, the non-ionomeric intermediate cover layer being formed of a polyester/polycarbonate blend and having a hardness greater than both the inner and outer cover layers; wherein the inner cover layer has a first thickness, the outer cover layer has a second thickness, and the intermediate cover layer has a third thickness less than the first or second thickness by at least 20%.
    • 一种高尔夫球,其包括芯和邻近所述芯布置的盖,所述盖包括围绕所述芯设置并具有55肖氏D至60肖氏D的硬度的离聚物热塑性内覆盖层; 硬度为55肖氏D和60肖氏D之间的硬质聚氨酯外覆盖层; 以及设置在所述内层和外层之间的非离聚物热塑性中间覆盖层,所述非离聚物中间覆盖层由聚酯/聚碳酸酯共混物形成并且具有大于所述内层和外覆盖层的硬度; 其中所述内覆盖层具有第一厚度,所述外覆盖层具有第二厚度,并且所述中间覆盖层的第三厚度小于所述第一或第二厚度至少20%。
    • 55. 发明申请
    • GOLF BALL HAVING REDUCED SURFACE HARDNESS
    • 高尔夫球具有减少的表面硬度
    • US20110237349A1
    • 2011-09-29
    • US13153525
    • 2011-06-06
    • Michael J. SullivanMark L. BinetteBrian Comeau
    • Michael J. SullivanMark L. BinetteBrian Comeau
    • A63B37/06
    • A63B37/0063A63B37/0018
    • A golf ball comprising a core and at least one cover layer disposed about the core, the core comprising a geometric center and an outer surface, the core further comprising an untreated region extending radially from the geometric center a predetermined distance DUTr and a treated region disposed about the untreated region and extending inward from the outer surface a predetermined depth DTr. The treated region has been exposed to and comprises a fatty acid and/or fatty acid salt composition wherein the treated region comprises a first hardness and the untreated region comprises a second hardness wherein the first hardness is greater than the second hardness. Additionally, the golf ball may comprise an intermediate untreated region disposed about the untreated region and adjacent the treated region wherein the intermediate untreated region comprises a third hardness and wherein the first hardness is greater than the second hardness and the third hardness. In another embodiment, the first hardness is greater than the second hardness and substantially similar to the third hardness. In yet another embodiment, the first hardness is less than the second hardness and the third hardness.
    • 一种高尔夫球,其包括芯和围绕所述芯设置的至少一个覆盖层,所述芯包括几何中心和外表面,所述芯还包括从几何中心径向延伸预定距离DUTr的未处理区域和设置的处理区域 围绕未处理区域并从外表面向内延伸预定深度DTr。 经处理的区域已经暴露于脂肪酸和/或脂肪酸盐组合物,并且包含脂肪酸和/或脂肪酸盐组合物,其中处理区域包含第一硬度,未处理区域包括第二硬度,其中第一硬度大于第二硬度。 此外,高尔夫球可以包括围绕未处理区域设置并且邻近处理区域的中间未处理区域,其中中间未处理区域包括第三硬度,并且其中第一硬度大于第二硬度和第三硬度。 在另一个实施方案中,第一硬度大于第二硬度并且基本上类似于第三硬度。 在又一实施例中,第一硬度小于第二硬度和第三硬度。
    • 56. 发明申请
    • GOLF BALL HAVING REDUCED SURFACE HARDNESS
    • 高尔夫球具有减少的表面硬度
    • US20100227708A1
    • 2010-09-09
    • US12781245
    • 2010-05-17
    • Michael J. SullivanMark L. BinetteBrian Comeau
    • Michael J. SullivanMark L. BinetteBrian Comeau
    • A63B37/12A63B37/00
    • A63B37/0032A63B37/0003A63B37/0024A63B37/0031A63B37/0033A63B37/12
    • The invention is directed to golf ball comprising a core and a cover disposed about the core, the cover comprising at least one cover layer comprising an cover outer surface and a cover inner surface, the cover outer surface comprising a fatty acid and/or fatty acid salt composition, the cover outer surface further comprising a hardness α and the cover inner surface comprising a hardness β, wherein the hardness α is different than the hardness β. In another embodiment, the at least one cover layer comprises a treated cover region and an untreated cover region, the treated cover region extending inward from the cover outer surface a depth of about 1% or greater of a distance between the cover outer surface and the cover inner surface, and the untreated cover region being disposed about the cover inner surface and adjacent the treated cover region. In yet another embodiment, the treated cover region extends inward from the cover outer surface a predetermined depth DCTr and the untreated cover region is disposed between the cover inner surface and the treated cover region a predetermined depth DCUTr, said treated cover region being treated with and/or a comprising a fatty acid and/or fatty acid salt composition wherein the treated cover region comprises a hardness α and the untreated cover region comprises a hardness β that is different than the hardness α.
    • 本发明涉及一种高尔夫球,包括芯和围绕芯设置的盖,所述盖包括至少一个包括盖外表面和盖内表面的覆盖层,所述盖外表面包含脂肪酸和/或脂肪酸 盐组成,所述盖外表面还包含硬度α,所述盖内表面包含硬度bgr;其中所述硬度α不同于硬度bgr。 在另一个实施例中,至少一个覆盖层包括经处理的覆盖区域和未处理的覆盖区域,经处理的覆盖区域从覆盖物外表面向内延伸约1%或更大的盖外表面和 覆盖内表面,并且未处理的覆盖区域围绕盖内表面设置并且邻近经处理的覆盖区域。 在另一个实施例中,经处理的覆盖区域从盖外表面向内延伸预定深度DCTr,未处理覆盖区域设置在预定深度DCUTr的盖内表面和经处理的覆盖区域之间,所述处理的覆盖区域被处理和 /或包含脂肪酸和/或脂肪酸盐组合物的组合物,其中所述经处理的覆盖区域包含硬度α,并且所述未处理的覆盖区域包含硬度和bgr; 这不同于硬度α。
    • 57. 发明申请
    • GOLF BALL HAVING REDUCED SURFACE HARDNESS
    • US20100222156A1
    • 2010-09-02
    • US12781281
    • 2010-05-17
    • Michael J. SullivanMark L. BinetteBrian Comeau
    • Michael J. SullivanMark L. BinetteBrian Comeau
    • A63B37/12A63B37/00
    • A63B37/0032A63B37/0003A63B37/0024A63B37/0031A63B37/0033A63B37/12
    • The invention is directed to a golf ball comprising a core comprising at least one layer, a cover disposed about the core, the cover comprising at least one cover layer comprising a cover inner surface and a cover outer surface, the cover layer further comprising a treated cover region and an untreated cover region, the treated cover region extending inward from the cover outer surface a depth DCTr, the untreated cover region disposed between the cover inner surface and the treated cover region and having a depth DCUTr, the treated cover region comprising a fatty acid and/or fatty acid salt composition, wherein the treated cover region comprises a hardness α and the untreated cover region comprises n regions of hardness wherein n≧1 and wherein at least one of the n regions of hardness has a hardness H1 that is different than the hardness α, and wherein each of said n regions of hardness further comprise a depth DCUTn such that DCTr≦(1/n)(DUT1+DUT2+ . . . +DUTn). In another embodiment, the treated cover region has been exposed to and comprises a fatty acid and/or fatty acid salt composition wherein the treated cover region comprises a hardness α and the untreated cover region comprises n regions of hardness within depth DCUTr wherein n≧1 and wherein at least one of the n regions of hardness has a hardness H2 different than the hardness α, each of said n regions further having a depth DCUTn such that DCTr≦(n)(DCUT1+DCUT2+ . . . +DCUTn). In yet another embodiment, said treated cover region comprises a fatty acid and/or fatty acid salt composition wherein the treated cover region comprises a hardness α and the untreated cover region comprises n regions of hardness within depth DCUTr wherein n≧1 and wherein at least one of said n regions of hardness has a hardness H3 that is different than the hardness α, each of said n regions of hardness further having a depth DCUTn such that DCTr≦(1/n2)(DCUT1+DCUT2+ . . . +DCUTn).
    • 58. 发明申请
    • GOLF BALL LAYER HAVING REDUCED SURFACE HARDNESS AND METHOD OF MAKING SAME
    • 具有降低的表面硬度的高尔夫球层及其制造方法
    • US20090176023A1
    • 2009-07-09
    • US12394942
    • 2009-02-27
    • Michael J. SullivanMark L. BinetteBrian Comeau
    • Michael J. SullivanMark L. BinetteBrian Comeau
    • B05D3/10
    • B29D99/0042A63B37/0018A63B37/0062A63B37/0063B29C71/0009B29K2009/00B29K2609/00B29L2031/54B29L2031/545
    • A method of making a golf ball comprising the steps of providing an untreated golf ball core comprising a thermoset rubber composition, the untreated golf ball core comprising an untreated outer surface having a hardness; treating the untreated outer surface of the untreated golf ball core with a surface-softening material comprising at least one fatty acid or fatty acid salt composition to form a golf ball core comprising a treated outer surface having a hardness less than the hardness of the untreated outer surface; and forming at least one cover layer about the core to form the golf ball. Also, the untreated core may comprise a geometric center and an untreated outer surface, each having a hardness such that the hardness of the treated outer surface is less than both the hardness of the untreated geometric center and the hardness of the untreated outer surface. A golf ball comprising a core and a cover, wherein the core has an outer surface that is treated with at least one fatty acid such that the outer surface has a hardness ratio (R) of the hardness after treatment (H2) to the hardness before treatment (H1) of less than about 0.95. A golf ball comprising a core and a cover, wherein the core has a geometric center having a hardness (Hg) and the core has an outer surface that is treated with at least one fatty acid or fatty acid salt such that the outer surface has an extrapolated hardness (HE) and an actual hardness (HOS) wherein HE is derived from a five point extrapolation within three quarters of an outer core diameter and HOS is measured on the curved surface of the core, and the cover has a hardness (HC), wherein HC>HE>Hg>HOS.
    • 一种制造高尔夫球的方法,包括以下步骤:提供包含热固性橡胶组合物的未处理的高尔夫球芯,所述未处理的高尔夫球芯包括具有硬度的未处理的外表面; 用包含至少一种脂肪酸或脂肪酸盐组合物的表面软化材料处理未处理的高尔夫球芯的未处理的外表面,以形成高尔夫球芯,其包括具有小于未处理外部硬度的硬度的经处理的外表面 表面; 以及围绕所述芯形成至少一个覆盖层以形成所述高尔夫球。 此外,未处理的芯可以包括几何中心和未处理的外表面,每个具有硬度使得经处理的外表面的硬度小于未处理的几何中心的硬度和未处理的外表面的硬度。 一种高尔夫球,包括芯和盖,其中所述芯具有用至少一种脂肪酸处理的外表面,使得外表面具有处理后的硬度(H2)与硬度之前的硬度比(R) 治疗(H1)小于约0.95。 一种高尔夫球,包括芯和盖,其中所述芯具有具有硬度(Hg)的几何中心,并且所述芯具有用至少一种脂肪酸或脂肪酸盐处理的外表面,使得所述外表面具有 外部硬度(HE)和实际硬度(HOS),其中HE是从外芯直径的四分之三内的五点外推得到的,并且在芯的弯曲表面上测量HOS,并且该盖具有硬度(HC) ,其中HC> H 2> HOS。
    • 59. 发明授权
    • Golf ball having reduced surface hardness
    • 高尔夫球具有降低的表面硬度
    • US08523709B2
    • 2013-09-03
    • US12781281
    • 2010-05-17
    • Michael J. SullivanMark L. BinetteBrian Comeau
    • Michael J. SullivanMark L. BinetteBrian Comeau
    • A63B37/04A63B37/12
    • A63B37/0032A63B37/0003A63B37/0024A63B37/0031A63B37/0033A63B37/12
    • A golf ball comprising a core and a cover layer disposed about the core, the cover layer comprising a cover inner surface, a cover outer surface, a treated cover region, and an untreated cover region, the treated cover region extending inward from the cover outer surface a depth D.sub.CTr, the untreated cover region disposed between the cover inner surface and the treated cover region and having a depth D.sub.CUTr, the treated cover region comprising a fatty acid and/or fatty acid salt composition, wherein the treated cover region comprises a hardness .alpha. and the untreated cover region comprises n regions of hardness wherein n.gtoreq.1 and wherein at least one of the n regions of hardness has a hardness H.sub.1 that is different than the hardness .alpha., and wherein each of said n regions of hardness further comprise a depth D.sub.CUTn such that D.sub.CTr.ltoreq.(1/n)(D.sub.UT1+D.sub.UT2+ . . . +D.sub.UTn).
    • 一种高尔夫球,其包括芯和围绕所述芯设置的覆盖层,所述覆盖层包括盖内表面,盖外表面,处理覆盖区域和未处理覆盖区域,所述处理覆盖区域从所述盖外侧向内延伸 表面深度D.sub.CTr,未处理的覆盖区域,设置在盖内表面和处理的覆盖区域之间并具有深度D.sub.CUTr,处理的覆盖区域包含脂肪酸和/或脂肪酸盐组合物, 其中所述经处理的覆盖区域包括硬度α。 并且未处理的覆盖区域包括n个硬度区域,其中n区域硬度的n个区域中的至少一个具有不同于硬度α的硬度H.并且其中每个所述 硬度的n个区域还包括深度D.sub.CUTn,使得D.sub.CTr.ltoreq。(1 / n)(D.sub.UT1 + D.sub.UT2 +。... + D.sub.UTn) 。
    • 60. 发明授权
    • Process for manufacturing golf balls having multi-layered covers
    • 制造具有多层盖的高尔夫球的方法
    • US08343406B2
    • 2013-01-01
    • US13088595
    • 2011-04-18
    • William E. MorganMichael J. SullivanMark L. BinetteBrian Comeau
    • William E. MorganMichael J. SullivanMark L. BinetteBrian Comeau
    • B29C39/18
    • A63B37/0074A63B37/0003A63B37/0019A63B37/0031A63B37/0033A63B37/0043A63B37/0045A63B45/00B29C43/027B29C43/18B29C65/483B29C65/52B29C65/7802B29C65/7841B29C66/54B29C66/73921B29D99/0042B29L2031/546Y10T156/1041
    • The invention is directed to a process for making a golf ball having a multi-layered cover including a very thin outermost cover layer, the process comprising for example: forming first and second substantially hemispherical half shells having a thickness and comprising a thermoplastic composition, each half shell further having an outer surface and an inner surface, the inner surface forming an hemispherical cavity; securing the first half shell in a golf ball mold; securing a core subassembly in a subassembly holder; dispensing an uncured liquid thermoset composition into the hemispherical cavity of the first half shell; inserting a first half of the core subassembly into the hemispherical cavity of the first half shell and displacing an amount of the uncured liquid thermoset composition such that the uncured liquid thermoset composition forms an inner cover layer having a thickness; disengaging the core subassembly from the subassembly holder when the thermoset composition has gelled to a point of rigidity; securing the second half shell in a golf ball mold; dispensing the uncured liquid thermoset composition into the hemispherical cavity of the second half shell; inserting a second half of the core subassembly into the hemispherical cavity of the second half shell and displacing an amount of the uncured liquid thermoset composition such that the uncured liquid thermoset composition forms an inner cover layer having a thickness and thereby mating the first and second half shells; and curing the thermoset inner cover layer to complete the golf ball and then removing the resulting golf ball from the golf ball mold.
    • 本发明涉及一种用于制造具有包括非常薄的最外覆盖层的多层覆盖层的高尔夫球的方法,该方法包括例如:形成具有厚度并包含热塑性组合物的第一和第二基本上半球形的半壳,每个半壳包含热塑性组合物 半壳体还具有外表面和内表面,所述内表面形成半球形腔; 将前半壳固定在高尔夫球模具中; 将芯子组件固定在子组件固定器中; 将未固化的液体热固性组合物分配到第一半壳的半球形腔中; 将所述芯子组件的前半部分插入所述第一半壳体的所述半球形空腔中并移动一定量的未固化液体热固性组合物,使得所述未固化液体热固性组合物形成具有厚度的内覆盖层; 当热固性组合物凝胶化成刚性点时,使芯子组件与子组件保持器脱离; 将第二半壳固定在高尔夫球模具中; 将未固化的液体热固性组合物分配到第二半壳的半球形腔中; 将所述芯子组件的第二半部分插入所述第二半壳体的所述半球形空腔中并且移动一定量的未固化液体热固性组合物,使得所述未固化液体热固性组合物形成具有厚度的内覆盖层,从而将所述第一和第二半 贝壳 并固化热固性内覆盖层以完成高尔夫球,然后从高尔夫球模具中除去所得到的高尔夫球。