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51. 发明申请

WO2007121006A2 LOW THERMAL DISTORTION SILICONE COMPOSITE MOLDS 审中-公开
标题翻译：低热失真硅胶复合材料
公开(公告)号：WO2007121006A2
公开(公告)日：2007-10-25
申请号：PCT/US2007/063651
申请日：2007-03-09
申请人： DOW CORNING CORPORATION , ZHU, Bizhong , CHEN, Wei
发明人： ZHU, Bizhong , CHEN, Wei
IPC分类号： C08L83/04 , C08G77/34 , C08K5/00
CPC分类号： H01L31/0481 , B29C37/0064 , B82Y10/00 , B82Y40/00 , C08G77/12 , C08G77/20 , C08K5/5425 , C08L83/04 , G03F7/0002 , H01L31/022441 , H01L31/048 , Y02E10/50 , C08L83/00
摘要： The present invention provides compositions and methods that may be used to form low thermal distortion molds. The composition may include a curable elastomeric silicone composition formed using a de-volatilized polymer and at least one de-volatilized cross-linker. One embodiment of the method may include forming a pattern on a first side of an elastomer that is impregnated with a fibrous material proximate a second side of the elastomer.
摘要翻译：本发明提供可用于形成低热变形模具的组合物和方法。组合物可以包括使用去挥发的聚合物和至少一种去挥发的交联剂形成的可固化的弹性体硅氧烷组合物。该方法的一个实施方案可以包括在弹性体的第一侧上形成图案，所述弹性体的第一侧被浸渍在靠近弹性体的第二侧的纤维材料。

52. 发明申请

WO2007120905A2 CADMIUM TELLURIDE-BASED PHOTOVOLTAIC DEVICE AND METHOD OF PREPARING THE SAME 审中-公开
标题翻译：基于碲化镉的光伏器件及其制备方法
公开(公告)号：WO2007120905A2
公开(公告)日：2007-10-25
申请号：PCT/US2007/009364
申请日：2007-04-18
申请人： DOW CORNING CORPORATION , KATSOULIS, Dimitris, Elias , ZHU, Bizhong
发明人： KATSOULIS, Dimitris, Elias , ZHU, Bizhong
IPC分类号： H01L31/0392 , H01L31/048
CPC分类号： H01L31/0392 , C08G77/12 , C09D183/04 , H01L31/03925 , H01L31/03926 , H01L31/073 , H01L31/1836 , Y02E10/543
摘要： A cadmium telluride (CdTe)-based photovoltaic device includes a CdTe layer including cadmium and telluride. The CdTe-based photovoltaic device further includes a substrate including a silicone layer formed from a silicone composition. The substrate, because it includes the silicone layer formed from the silicone composition, is both flexible and sufficiently able to withstand annealing temperatures in excess of 350°C, and frequently in excess of 500°C, to obtain maximum efficiency of the device.
摘要翻译：基于碲化镉（CdTe）的光伏器件包括CdTe层，包括镉和碲化物。基于CdTe的光电器件还包括由硅氧烷组合物形成的硅氧烷层的衬底。由于其包括由硅氧烷组合物形成的硅氧烷层，基体是柔性的并且足以承受超过350℃并且经常超过500℃的退火温度，以获得器件的最大效率。

53. 发明申请

WO2007097835A3 SILICONE RESIN FILM, METHOD OF PREPARING SAME, AND NANOMATERIAL-FILLED SILICONE COMPOSITION 审中-公开
公开(公告)号：WO2007097835A3
公开(公告)日：2007-08-30
申请号：PCT/US2007/000721
申请日：2007-01-11
申请人： DOW CORNING CORPORATION , FISHER, Mark , ZHU, Bizhong
发明人： FISHER, Mark , ZHU, Bizhong
IPC分类号： C09D183/04 , C08K7/06
摘要： A method of preparing a silicone resin film comprising coating a release liner with a nanomaterial-filled silicone composition comprising (i) a free radical-curable silicone composition comprising a silicone resin and (ii) a carbon nanomaterial, and curing the silicone resin of the coated release liner; a silicone resin film prepared according to the preceding method; and a nanomaterial-filled silicone composition.

54. 发明申请

WO2007092032A3 REINFORCED SILICONE RESIN FILM AND METHOD OF PREPARING SAME 审中-公开
公开(公告)号：WO2007092032A3
公开(公告)日：2007-08-16
申请号：PCT/US2006/018168
申请日：2006-05-11
申请人： DOW CORNING CORPORATION , ANDERSON, Nicole , ZHU, Bizhong
发明人： ANDERSON, Nicole , ZHU, Bizhong
IPC分类号： C08J3/00 , C08K7/00
摘要： A method of preparing a reinforced silicone resin film, the method comprising the steps of impregnating a fiber reinforcement in a hydrosilylation-curable silicone composition comprising a silicone resin and a photoactivated hydrosilylation catalyst; and exposing the impregnated fiber reinforcement to radiation having a wavelength of from 150 to 800 nm at a dosage sufficient to cure the silicone resin; wherein the reinforced silicone resin film comprises from 10 to 99% (w/w) of the cured silicone resin and the film has a thickness of from 15 to 500 μm; and a reinforced silicone resin film prepared according to the method.

55. 发明申请

WO2006055232A3 ORGANOHYDROGENPOLY SILOXANE RESIN AND SILICON COMPOSITION 审中-公开
公开(公告)号：WO2006055232A3
公开(公告)日：2006-05-26
申请号：PCT/US2005/039377
申请日：2005-10-31
申请人： DOW CORNING CORPORATION , ZHU, Bizhong
发明人： ZHU, Bizhong
IPC分类号： C08L83/04 , C08G77/12 , C08L83/14 , C08G77/50
摘要： An organohydrogenpoly siloxane resin having the formula (I): (R 1 R 3 2 SiO ½)w(R 3 2 SiO½)x(R l SiO 3/2 )y(SiO 4/2 )z, wherein R l is C 1 to C 10 hydrocarbyl or C 1 to C 10 halogen-substituted hydrocarbyl, both free of aliphatic unsaturation, R 3 is R 1 or an organosilylalkyl group having at least one siliconbonded hydrogen atom, w is from 0 to 0.8, x is from 0 to 0.6, y is from 0 to 0.99, z is from 0 to 0.35, w+x+y+z=1, y+z/(w+x+y+z) is from 0.2 to 0.99, w+x/(w+x+y+z) is from 0.01 to 0.8, and at least 50 mol% of the groups R 3 are organosilylalkyl; a silicone composition containing the resin, and a cured silicone resin prepared by curing the silicone composition.

56. 发明申请

WO2006055231A1 SILICONE COMPOSITION AND CURED SILICONE RESIN 审中-公开
标题翻译：硅胶组合物和固化硅树脂
公开(公告)号：WO2006055231A1
公开(公告)日：2006-05-26
申请号：PCT/US2005/039376
申请日：2005-11-01
申请人： DOW CORNING CORPORATION , SMITH, Michael, Andrew , ZHU, Bizhong
发明人： SMITH, Michael, Andrew , ZHU, Bizhong
IPC分类号： C08L83/04 , C08K5/54
CPC分类号： C08K5/5403 , C08G77/12 , C08G77/20 , C08K5/5425 , C08L83/04 , C08L2205/02 , C08L83/00
摘要： A silicone composition according to the present invention comprises (A) an organopolysiloxane resin having an average of at least two silicon-bonded alkenyl groups per molecule, (B) an organohydrogensilane in an amount sufficient to cure the composition, (C) an effective amount of a reactive diluent comprising (i) an organosiloxane having an average of at least two alkenyl groups per molecule and a viscosity of from 0.001 to 2 Pa . s at 25 °C, wherein the viscosity of (C)(i) is not greater than 20% of the viscosity of component (A), and (ii) an organohydrogensiloxane having an average of at least two silicon-bonded hydrogen atoms per molecule and a viscosity of from 0.001 to 2 Pa . s at 25 °C, in an amount sufficient to provide from 0.5 to 3 moles of silicon-bonded hydrogen atoms in (C)(ii) to moles of alkenyl groups in (C)(i), and (D) a catalytic amount of a hydrosilylation catalyst; and a cured silicone resin prepared by curing the silicone composition.
摘要翻译：根据本发明的硅氧烷组合物包含（A）每分子平均具有至少两个硅键合的烯基的有机聚硅氧烷树脂，（B）足以固化组合物的量的有机氢硅烷，（C）有效量的反应性稀释剂，其包含（i）每分子平均具有至少两个烯基的有机硅氧烷和在25℃下的粘度为0.001至2Pa·s，其中（C ）（i）不大于组分（A）的粘度的20％，和（ii）每分子平均具有至少两个与硅键合的氢原子的有机氢硅氧烷，粘度为0.001-2Pa

57. 发明申请

WO2008134241A1 NANOMATERIAL-FILLED SILICONE COMPOSITION AND REINFORCED SILICONE RESIN FILM 审中-公开
标题翻译：纳米填料硅胶组合物和增强硅树脂薄膜
公开(公告)号：WO2008134241A1
公开(公告)日：2008-11-06
申请号：PCT/US2008/060422
申请日：2008-04-16
申请人： DOW CORINING CORPORATION , ZHU, Bizhong
发明人： ZHU, Bizhong
IPC分类号： C08G77/58 , C08K7/26 , C09D183/14
CPC分类号： C08G77/48 , C08G77/60 , C08K7/26 , C08L83/04 , C09D183/14
摘要： A nanomaterial-filled silicone composition comprising a silicone resin comprising disilyloxane units, a carbon nanomaterial, and an organic solvent; and a reinforced silicone resin film comprising a cured product of the silicone resin, and a carbon nanomaterial dispersed in the cured product.
摘要翻译：一种纳米材料填充的硅氧烷组合物，其包含含有硅氧烷树脂的硅氧烷树脂，碳纳米材料和有机溶剂; 以及包含有机硅树脂的固化物和分散在固化物中的碳纳米材料的增强有机硅树脂膜。

58. 发明申请

WO2017044735A1 3D PRINTING METHOD UTILIZING THERMOPLASTIC SILICONE COMPOSITION 审中-公开
标题翻译：利用热塑性硅酮组合物的3D印刷方法
公开(公告)号：WO2017044735A1
公开(公告)日：2017-03-16
申请号：PCT/US2016/050933
申请日：2016-09-09
申请人： DOW CORNING CORPORATION
发明人： MILROY, Zachary , SCHAUBROECK, Sara , ZHU, Bizhong
IPC分类号： C08L83/04 , B33Y80/00 , B33Y70/00 , B33Y10/00
CPC分类号： C08L83/04 , B29C64/106 , B33Y70/00 , C08G77/12 , C08G77/20
摘要： A method of forming a three-dimensional (3D) article is disclosed. The method comprises I) printing a first thermoplastic silicone composition with a 3D printer to form an at least partially solidified layer. The method further comprises II) printing a second thermoplastic silicone composition on the at least partially solidified layer with the 3D printer to form a subsequent at least partially solidified layer. Optionally, step II) may be repeated with independently selected thermoplastic silicone composition(s) for any additional layer(s) to form the 3D article. The first and second thermoplastic silicone compositions are the same as or different from one another.
摘要翻译：公开了形成三维（3D）制品的方法。该方法包括I）用3D打印机印刷第一热塑性硅氧烷组合物以形成至少部分固化的层。该方法还包括：II）用3D打印机在至少部分固化的层上印刷第二热塑性有机硅组合物以形成随后的至少部分固化的层。任选地，步骤II）可以用独立选择的热塑性硅酮组合物用于任何附加层，以形成3D制品。第一和第二热塑性硅酮组合物彼此相同或不同。

59. 发明申请

WO2014130948A1 METHOD OF RECYCLING SILICONE WASTE WITH THE USE OF ORGANIC POLYMER AND DEPOLYMERIZATION CATALYST 审中-公开
标题翻译：使用有机聚合物和分解催化剂回收硅酮废物的方法
公开(公告)号：WO2014130948A1
公开(公告)日：2014-08-28
申请号：PCT/US2014/018028
申请日：2014-02-24
申请人： DOW CORNING CORPORATION
发明人： JULIAN, Dan J. , KATSOULIS, Dimitris , LINK, Bernard A. , PEITZ, Thomas Alexander , ZHU, Bizhong
IPC分类号： C08J11/16 , C08J11/18
CPC分类号： C08J11/16 , C08J11/18 , C08J2383/04 , Y02W30/705 , Y02W30/706
摘要： A method that includes: (a) heating a mixture that includes: (i) silicone, (ii) an organic polymer, and (iii) a depolymerization catalyst, wherein the heating is sufficient to depolymerize at least a portion of the silicone, to provide heated mixture comprising a cyclosiloxane and a residue. The method also optionally further includes (b) degassing the heated mixture to remove at least a portion of the cyclosiloxane, (c) forming an extrudate from the residue; and (d) heating the extrudate, sufficient to depolymerize at least a portion of remaining silicone located therein.
摘要翻译：一种方法，其包括：（a）加热混合物，所述混合物包括：（i）硅氧烷，（ii）有机聚合物，和（iii）解聚催化剂，其中加热足以将至少一部分硅氧烷解聚至提供包含环硅氧烷和残余物的加热混合物。该方法还任选地还包括（b）将加热的混合物脱气以除去至少一部分环硅氧烷，（c）从残余物形成挤出物; 和（d）加热挤出物，足以使位于其中的至少一部分剩余的硅氧烷解聚。

60. 发明申请

WO2017040874A1 3D PRINTING METHOD UTILIZING HEAT-CURABLE SILICONE COMPOSITION 审中-公开
标题翻译：利用热固性硅酮组合物的3D印刷方法
公开(公告)号：WO2017040874A1
公开(公告)日：2017-03-09
申请号：PCT/US2016/050023
申请日：2016-09-02
申请人： DOW CORNING CORPORATION
发明人： BACKER, Michael W. , MILROY, Zachary , SCHAUBROECK, Sara , WOLF, Hans Peter , ZHU, Bizhong
IPC分类号： B29C67/00 , B33Y80/00 , B29K83/00 , C08L83/04 , B33Y70/00 , B33Y10/00
CPC分类号： B29C64/295 , B29C64/00 , B29C64/112 , B29C64/118 , B29C64/153 , B29C64/209 , B29K2083/00 , B33Y10/00 , B33Y70/00 , B33Y80/00 , C08G77/12 , C08G77/16 , C08L83/04
摘要： A method of forming a three-dimensional (3D) article comprises the steps of I) printing a first heat-curable silicone composition with a 3D printer to form a layer, II) heating the layer to form an at least partially cured layer, III) printing a second heat-curable silicone composition on the at least partially cured layer with the 3D printer to form a subsequent layer, and IV) heating the subsequent layer to form an at least partially cured subsequent layer. Optionally, steps III) and IV) can be repeated with independently selected heat-curable silicone composition(s) for any additional layer(s) to form the 3D article. The first and second heat-curable silicone compositions may be the same as or different from one another.
摘要翻译：形成三维（3D）制品的方法包括以下步骤：I）用3D打印机印刷第一可热固化的硅氧烷组合物以形成层，II）加热该层以形成至少部分固化的层III ）用所述3D打印机在所述至少部分固化的层上印刷第二可热固化的硅氧烷组合物以形成后续层，以及IV）加热所述后续层以形成至少部分固化的后续层。任选地，步骤III）和IV）可以用独立选择的可热固化的硅氧烷组合物用于任何附加层，以形成3D制品。第一和第二可热固化硅氧烷组合物可以彼此相同或不同。

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