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    • 51. 发明授权
    • Process for hydroshifting dimethyl ether
    • 氢化二甲醚的方法
    • US5626794A
    • 1997-05-06
    • US597209
    • 1996-02-06
    • Alakananda BhattacharyyaArunabha Basu
    • Alakananda BhattacharyyaArunabha Basu
    • C01B3/38C01B3/32F02C3/22C07C1/00C07C1/02
    • C01B3/326C01B3/323C01B2203/1047C01B2203/1052C01B2203/1076Y02P20/52
    • A process for hydroshifting dimethyl ether is described which comprises passing a feed stream which includes dimethyl ether and steam to a hydroshifting reaction zone including an essentially alkali metal-free catalytic composition substantially composed of copper or nickel in elemental form. The process produces a hydroshifted product stream which is relatively rich in hydrogen, carbon monoxide, and carbon dioxide.The feed stream can be transported relatively easily in liquid form at comparatively low pressures. The hydroshifting reaction zone can include a hydrolysis reaction zone and a water-gas shift reaction zone. The hydrolyzed product and the water-gas shift product can be recovered to obtain hydrogen and carbon dioxide, respectively. Additionally, the hydroshifted product stream can be blended with an oxidizing stream and combusted to drive a turbine in order to generate mechanical energy.
    • 描述了一种用于氢化二甲醚的方法,其包括将包括二甲醚和蒸汽的进料流传送到包含基本上不含碱金属的催化剂组合物的水移动反应区,所述催化组合物基本上由元素形式的铜或镍组成。 该方法产生氢转移产物流,其相对富含氢,一氧化碳和二氧化碳。 进料流可以在相当低的压力下相对容易地以液体形式输送。 加氢反应区可包括水解反应区和水煤气变换反应区。 可以回收水解产物和水煤气变换产物以分别获得氢气和二氧化碳。 此外,氢化转化产物流可与氧化流混合并燃烧以驱动涡轮以产生机械能。