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    • 56. 发明授权
    • Thermoplastic molding compositions of a polysiloxane block
copolycarbonate and a polycarbonate based on certain
dihydroxydiphenylcycloalkanes
    • 基于某些二羟基二苯基甲烷的聚硅氧烷嵌段共聚碳酸酯和聚碳酸酯的热塑性成型组合物
    • US5100960A
    • 1992-03-31
    • US493036
    • 1990-03-12
    • Ulrich GrigoPeter HorlacherDieter FreitagKarsten-Josef IdelUwe WesteppeWolfgang BeerWerner Nouvertne
    • Ulrich GrigoPeter HorlacherDieter FreitagKarsten-Josef IdelUwe WesteppeWolfgang BeerWerner Nouvertne
    • C08L69/00C08L83/10
    • C08L69/00C08L83/10
    • The invention relates to a thermoplastic molding composition comprising(A) from 10 to 98 parts by weight of a polydiorganosiloxane-polycarbonate block copolymer having a weight average molecular weight of from 10,000 to 200,000 and containing from 75 to 97.5 wt. % of aromatic carbonate structural units and from 25 to 2.5 wt. % of polydiorganosiloxane structural units;(B) from 2 to 90 parts by weight of a thermoplastic, aromatic polycarbonate having a weight average molecular weight of at least 10,000, andcontaining bifunctional carbonate structural units corresponding to ##STR1## wherein R.sup.1 and R.sup.2 independently represent hydrogen, halogen, C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.6 cycloalkyl, C.sub.6 -C.sub.10 aryl or C.sub.7 -C.sub.12 aralkyl;m represents an integer of from 4 to 7,R.sup.3 and R.sup.4, which may be selected individually for each X, independently represent hydrogen or C.sub.1 -C.sub.6 alkyl; andx represents carbon,with the proviso that, on at least one atom X, R.sup.3 and R.sup.4 both represent alkyl; and(C) from 0.5 to 30 parts by weight of a rubber having a glass transition temperature of less than -20.degree. C.The composition of the invention is useful for the preparation of injection molded articles having an excellent surface and a particularly good toughness at low temperatures.
    • 本发明涉及一种热塑性模塑组合物,其包含(A)10至98重量份的重均分子量为10,000至200,000的聚二有机硅氧烷 - 聚碳酸酯嵌段共聚物,并且含有75至97.5重量% %的芳族碳酸酯结构单元和25〜2.5wt。 %的聚二有机硅氧烷结构单元; (B)2至90重量份的重均分子量为至少10,000的热塑性芳族聚碳酸酯,并且含有对应于(Ia)的双官能碳酸酯结构单元,其中R 1和R 2独立地表示氢,卤素 C 1 -C 8烷基,C 5 -C 6环烷基,C 6 -C 10芳基或C 7 -C 12芳烷基; m表示4至7的整数,可以为每个X单独选择的R 3和R 4独立地表示氢或C 1 -C 6烷基; 并且x表示碳,条件是在至少一个原子X,R 3和R 4都表示烷基; 和(C)0.5〜30重量份玻璃化转变温度低于-20℃的橡胶。本发明的组合物可用于制备具有优异表面和特别良好韧性的注塑制品 在低温下。