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    • 51. 发明申请
    • DIMERIC BENZYLIDENE MALONATES
    • 二甲基苯亚甲基丙二酸酯
    • WO2009112403A2
    • 2009-09-17
    • PCT/EP2009/052531
    • 2009-03-04
    • BASF SEHANSCH, MarkusEHLIS, ThomasWAGNER, Barbara
    • HANSCH, MarkusEHLIS, ThomasWAGNER, Barbara
    • A61K8/37A61Q17/04C07C67/347C07C69/618
    • A61Q17/04A61K8/37A61K8/585C07C67/03C07C67/31C07C67/343C07C69/734C07C2601/14C07F7/0889C07C69/732
    • Disclosed is the use of benzylidene malonates of formula (1), wherein R 1 and R 2 , independently from each other are hydrogen; OH; C 1 -C 12 alkyl; C 1 -C 12 alkoxy; C 1 -C 12 alkylamino; C 1 -C 12 dialkylamino; water-solubilizing groups, selected from carboxylate, sulfonates or ammonium radicals; R 3 is COOR 5 ; COR 5 ; CONR 5 R 6 ; CN; or SO 2 R 7 , R 4 is COOR 8 ; COR 9 ; CONR 8 R 9 ; CN; or SO 2 R 10 ; R 5 , R 6 , R 7 , R 8 , R 9 and R 10 independently from each other are C 1 -C 18 alkyl; unsubstituted or by one or more than one C 1 -C 4 alkyl substituted C 3 -C 12 -cycloalkyl; unsubstituted or C 1 -C 6 alkyl-substituted C 6 -C 20 aryl; organosilanyl, or organosiloxanyl; A is -C 1 -C 20 alkylene-, -CH 2 CH(OH)CH 2 -, -C 5 -C 20 cycloalkylene, --C 2 -C 20 alkenylene-, -C 5 - C 10 arylene-, or -C 5 -C 10 arylene-(C 1 -C 10 alkylene)- which are unsubstituted or substituted, straight-chain or branched, optionally interrupted by one or more than one heteroatoms selected from -O, -S- or -NH-; for the protection of human and animal hair and skin against UV radiation.
    • 公开了使用式(1)的亚苄基丙二酸酯,其中R 1和R 2彼此独立地为氢; 哦; ç<子> 1 -C <子> 12 烷基; ç<子> 1 -C <子> 12 烷氧基; ç<子> 1 -C <子> 12 烷基氨基; ç<子> 1 -C <子> 12 二烷基氨基; 水溶性基团,选自羧酸根,磺酸根或铵基; R 3 = COOR 5; COR <子> 5 ; CONR <子> 5 ř<子> 6 ; CN; 或SO 2 R 7,R 4是COOR 8; COR <子> 9 ; CONR <子> 8 ř<子> 9 ; CN; 或SO 2 R 10 ; R 5,R 6,R 7,R 8,R 9和 R 10彼此独立地为C 1 -C 18烷基; 未被取代或被一个或多个C 1 -C 4烷基取代的C 3 -C 12 - 环烷基 ; 未取代的或C 1 -C 6烷基取代的C 6 -C 20芳基; 有机硅烷基或有机硅氧烷基; A是-C 1 -C 20亚烷基 - , - CH 2 CH(OH)CH 2 - , - -C≡C-C20亚环烷基,-C≡C-C20亚链烯基,-C≡C (C 1 -C 10)亚芳基 - 或-C 5 -C 10亚芳基 - (C 1 -C 10)亚芳基 - 或-C 5 -C 10亚芳基 - 亚烷基) - 其是未取代的或取代的,直链或支链的,任选地被一个或多个选自-O,-S-或-NH-的杂原子间隔; 用于保护人类和动物毛发和皮肤免受紫外线辐射。
    • 54. 发明申请
    • FABRIC RINSE COMPOSITION CONTAINING A BENZTRIAZOLE UV ABSORBER
    • 含有苯并噻唑紫外线吸收剂的织物组合物
    • WO2002077148A1
    • 2002-10-03
    • PCT/EP2002/003009
    • 2002-03-19
    • CIBA SPECIALITY CHEMICALS HOLDING INC.EHLIS, ThomasHOCHBERG, RobertROHWER, Hauke
    • EHLIS, ThomasHOCHBERG, RobertROHWER, Hauke
    • C11D3/42
    • C11D3/42C11D3/0015
    • Disclosed is a fabric rinse composition comprising a) 0.1 to 10 % by weight of a UV absorber of formula(1), wherein A is a radical of formula (1a); B is a radical of formula (1c); (1d); (1e); (1f), (1g); (1h); (1i); (1k); (1l); or (1m); R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are each independently of the others hydrogen, C 1 -C 18 alkyl; C 5 -C 7 -cycloalkyl; halogen; R 9 is hydrogen, C 1 -C 12 alkyl; or C 5 -C 7 cycloalkyl; R 7 , R 8 and R 10 are each independently of the others hydrogen, C 1 -C 12 alkyl, C 5 -C 7 cycloalkyl, C 1 -C 12 hydroxyalkyl; X is halogen; a radical of formula (1s); or (1u); sulfate, phosphate, lactate, citrate, tartrate; R 11 is C 1 -C 12 alkyl; C 5 -C 7 cycloalkyl or phenyl: x is from 0 to 10; and y is from 1 to 20; b) 5 to 25 % by weight, based on the total weight of the composition of a fabric softener agent; and c) the remainder being substantially water.
    • 公开了一种织物漂洗组合物,其包含a)0.1至10重量%的式(1)的UV吸收剂,其中A为式(1a)的基团; B是式(1c)的基团; (1D); (1E); (1f),(1g); (1H); (1i)中; (1K); (1升); 或(1m); R 1,R 2,R 3,R 4,R 5和R 6各自独立地为氢,C 1 -C 18烷基; C5-C7环烷基; 卤素; R9是氢,C1-C12烷基; 或C 5 -C 7环烷基; R 7,R 8和R 10各自独立地为氢,C 1 -C 12烷基,C 5 -C 7环烷基,C 1 -C 12羟烷基; X是卤素; 式(1s)的基团; 或(1u); 硫酸盐,磷酸盐,乳酸盐,柠檬酸盐,酒石酸盐; R11是C1-C12烷基; C 5 -C 7环烷基或苯基:x为0至10; y为1〜20; b)5至25重量%,基于织物柔软剂的组合物的总重量; 和c)其余部分基本上是水。
    • 55. 发明申请
    • HEAT-SENSITIVE COATING COMPOSITIONS BASED ON RESORCINYL TRIAZINE DERIVATIVES
    • 基于间苯二酚衍生物的热敏涂料组合物
    • WO2008110487A1
    • 2008-09-18
    • PCT/EP2008/052637
    • 2008-03-05
    • CIBA HOLDING INC.CUNNINGHAM, Allan, FrancisEHLIS, ThomasBIRBAUM, Jean-LucHAYOZ, PascalFONDEKAR, Kamalesh Pai
    • CUNNINGHAM, Allan, FrancisEHLIS, ThomasBIRBAUM, Jean-LucHAYOZ, PascalFONDEKAR, Kamalesh Pai
    • C09D5/26C09D7/00C07D251/24C08K5/3492C07D251/14B41M5/333
    • B41M5/3335B41M5/3336C08K5/3492C09D5/26C09D7/41Y10T428/24802
    • The present invention provides heat-sensitive coating compositions, which comprise a a colour developer of formula (1) or mixtures thereof wherein R 1 can be hydrogen, C 1-20 -alkyl, C 3-8 -cycloalkyl, C 2-10 -alkenyl, aryl or SO 3 H, and R 2 and R 3 can be the same or different and can be hydrogen, halogen, C 1-20 -alkyl, C 3-8 -cyclo-alkyl, C 2-10 -alkenyl, aryl, OR 6 , NR 7 R 8 , SR 9 , SO 3 H or COOR 10 and R 4 and R 5 can be the same or different, and can be hydrogen, halogen, C 1-20 -alkyl, C 3-8 -cyclo-alkyl, C 2-10 -alkenyl, aryl, OR 6 , NR 7 R 8 or SR 9 , R 6 , R 7 , R 8 , R 9 and R 10 can be the same or different and can be hydrogen, C 1-30 -alkyl, C 3-8 -cycloalkyl, C 2-10 -alkenyl or aryl, wherein C 1-20 -alkyl can be unsubstituted or substituted with one or more C 3-8 -cycloalkyl, C 2-10 -alkenyl, phenyl, halogen, OR 11 , NR 12 R 13 , SR 14 , SO 3 H or COOR 15 , and aryl can be unsubstituted or substituted with one or more halogen, C 1-10 -alkyl, halogenated C 1-10 -alkyl, C 3-8 -cycloalkyl, C 2-10 -alkenyl, phenyl, OR 11 , NR 12 R 13 , SR 14 , SO 3 H or COOR 15 , wherein R 11 , R 12 , R 13 , R 14 and R 15 can be the same or different and can be hydrogen, C 1-10 -alkyl, C 3-8 -cycloalkyl or C 2-10 -alkenyl, a process for the preparation of these compositions, a process of coating substrates with these compositions, substrates coated with these compositions, a process for preparing marked substrates using these compositions, marked substrates obtainable by the latter process, and certain colour developers.
    • 本发明提供热敏涂料组合物,其包含式(1)的显色剂或其混合物,其中R 1可以是氢,C 1〜20位 - 烷基 C 3-8 - 环烷基,C 2-10 - 烯基,芳基或SO 3 H,R 2, SO 2和R 3可以相同或不同,并且可以是氢,卤素,C 1-20 - 烷基,C 3-8 - 环烷基,C 2-10 - 烯基,芳基,OR 6,NR 7,R 8, SO 3,SO 3 H或COOR 10和R 4和R 5, 可以是相同或不同的,并且可以是氢,卤素,C 1-20 - 烷基,C 3-8 - 环烷基,C 2- 10个 - 烯基,芳基,OR 6,NR 7 R 8或SR 9,R 7,R 7,R 8,R 9和R 10可以是 相同或不同,可以是氢,C 1-3 - 烷基,C 3-8 - 环烷基,C 2-10 - 烯基或芳基,其中C 1-20 - 烷基可以是未取代的或被一个或多个C 3-8 - 环烷基,C 2-10 - 亚烷基,苯基,卤素,OR 11,NR 12,R 13,SR 14, H 3或COOR 15,且芳基可以是未取代的或被一个或多个卤素取代,C 1-10烷基,卤代C 可以相同或不同,并且可以是氢,C 1-10 - 烷基,C 3-8 - 环烷基或C 2-10 - 烯基,这些组合物的制备方法,用这些组合物涂覆基质的方法,用这些组合物涂覆的基材,使用这些共聚物制备标记的底物的方法 可以通过后一种方法获得的粘合剂,标记的底物和某些彩色显影剂。