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    • 53. 发明申请
    • Aqueous coatings for food containers
    • 食品容器用水性涂料
    • US20060149019A1
    • 2006-07-06
    • US11301622
    • 2005-12-13
    • Christian WamprechtJan MazanekBeate BaumbachWolfram KuttnerDorota Greszta-Franz
    • Christian WamprechtJan MazanekBeate BaumbachWolfram KuttnerDorota Greszta-Franz
    • C08G18/00
    • C08G18/4263C08G18/792C08G18/8067C08G18/8074C08G2390/40C09D175/06
    • The present invention relates to aqueous coating compositions containing A) at least one polyisocyanate which contains an average of at least two NCO groups per molecule and in which at least 85% of the NCO groups are blocked with a blocking agent selected from ε-caprolactam and/or a hydroxycarboxylic acid, and B) at least one hydrophilic polyester polyol containing an average of at least two reactive hydroxyl groups per molecule, or a mixture of hydrophilic and non-hydrophilic polyester polyols, wherein component B) has an acid number of ≧15 mg KOH/g, a hydroxyl number of 20 to 300 mg KOH/g and a weight average molecular weight, Mw, of >1500 g/mol, wherein the equivalent ratio between the blocked isocyanate groups of component A) and the isocyanate-reactive groups of component B) is 0.5 to 5.0:1. The present invention also relates to a process for preparing these aqueous coating compositions, to coatings obtained from these aqueous coating compositions, particularly coatings for packaging and for the interior of cans.
    • 本发明涉及包含A)至少一种多异氰酸酯的水性涂料组合物,其每分子含有平均至少两个NCO基团,其中至少85%的NCO基团用封闭剂封闭,所述封闭剂选自ε-己内酰胺和 /或羟基羧酸,和B)至少一种含有每分子平均至少两个反应性羟基的亲水性聚酯多元醇,或亲水性和非亲水性聚酯多元醇的混合物,其中组分B)的酸值> = 15mg KOH / g,羟值为20-300mg KOH / g,重均分子量M w> 1500g / mol,其中封端异氰酸酯之间的当量比 组分A)和组分B)的异氰酸酯反应性基团为0.5至5.0:1。 本发明还涉及一种制备这些水性涂料组合物的方法,由这些水性涂料组合物获得的涂料,特别是用于包装的涂料和罐内部。
    • 57. 发明申请
    • Self-crosslinking polyurethane dispersions
    • 自交联聚氨酯分散体
    • US20050075470A1
    • 2005-04-07
    • US10953386
    • 2004-09-29
    • Jan MazanekJurgen MeixnerOlaf FleckHeino Muller
    • Jan MazanekJurgen MeixnerOlaf FleckHeino Muller
    • C08G18/08C08G18/12C08G18/40C08G18/76C08G18/00
    • C08G18/12C08G18/0823C08G18/4018C08G18/76C08G18/2805
    • A process for preparing self-crosslinking polyurethane polymers including i) reacting an aromatic isocyanate component (A) or a mixture of aromatic, aliphatic and/or cycloaliphatic isocyanate component having an isocyanate group functionality of greater than or equal to 2 with an at least difunctional polyol component (B1) with an average molecular weight of from 62 to 2500, which includes at least one acid-functional compound (C), to give a prepolymer containing isocyanate groups or containing hydroxyl groups, ii) adding one or more polyol components (B2) having an OH functionality of greater than or equal to 1, and optionally, an isocyanate component (A′), which may be identical to or different from (A), iii) mixing the resulting NCO-functional product with a blocking agent (D), and iv) adding a polyol component (B3). Self-crosslinking polyurethane polymers prepared as described above can be used in paint, varnish or adhesive compositions.
    • 一种制备自交联聚氨酯聚合物的方法,其包括:使异氰酸酯组分(A)或具有大于或等于2的异氰酸酯基官能度的芳族,脂族和/或脂环族异氰酸酯组分的混合物与至少二官能 平均分子量为62〜2500的多元醇成分(B1),其包含至少一种酸官能化合物(C),得到含异氰酸酯基或含羟基的预聚物,ii)添加一种或多种多元醇成分( B2),以及任选地,可以与(A)相同或不同的异氰酸酯组分(A'),iii)将所得的NCO-官能产物与封闭剂 (D),和iv)添加多元醇成分(B3)。 如上所述制备的自交联聚氨酯聚合物可用于油漆,清漆或粘合剂组合物中。
    • 59. 发明授权
    • Electrical insulating enamel binders having a urea and/or hydantoin structure
    • 具有脲和/或乙内酰脲结构的电绝缘搪瓷粘合剂
    • US06512073B2
    • 2003-01-28
    • US09977888
    • 2001-10-15
    • Rolf GertzmannLutz SchmalstiegJan MazanekBernd Hausstätter
    • Rolf GertzmannLutz SchmalstiegJan MazanekBernd Hausstätter
    • C08G1880
    • C08G18/8064C08G18/3821C08G18/8009C08G18/8067C09D175/02
    • The present invention relates to novel binders for electrical insulating enamels, comprising at least one hydroxy- and/or amino-functional polyurethane containing urea and/or hydantoin groups, prepared by reacting: a) from 15 to 40 wt. % of an organic polyisocyanate or of a mixture of organic polyisocyanates, b) from 5 to 20 wt. % of at least one aspartic acid ester, and c) from 5 to 50 wt. % of a polyhydroxy compound having a molar weight from 62 to 3000 g/mol, in d) from 25 to 50 wt. % of a solvent or of a solvent mixture and at least one blocked isocyanate component containing ester, imide, amide, and/or urethane groups, at least one organic solvent, and optionally further auxiliary substances and additives whereby the resulting enamels being distinguished by high temperature stability and good solderability.
    • 本发明涉及用于电绝缘搪瓷的新型粘合剂,其包含至少一种含有尿素和/或乙内酰脲基团的羟基和/或氨基官能聚氨酯,其通过以下步骤制备:a)15至40wt。 %的有机多异氰酸酯或有机多异氰酸酯的混合物,b)5至20wt。 %的至少一种天冬氨酸酯,和c)5至50wt。 %的摩尔重量为62-3000g / mol,ind)的多羟基化合物,25〜50wt。 %的溶剂或溶剂混合物和至少一种含有酯,酰亚胺,酰胺和/或氨基甲酸酯基的封端异氰酸酯组分,至少一种有机溶剂,以及任选的其它辅助物质和添加剂,由此所得到的搪瓷被高 温度稳定性和良好的可焊性。