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    • 59. 发明专利
    • BRPI0904824A2
    • 2010-11-03
    • BRPI0904824
    • 2009-02-27
    • BAYER MATERIALSCIENCE AG
    • OOMS PIETERBULAN ANDREASWEBER RAINERRECHNER JOHANN
    • C08G64/02
    • Making polycarbonate by phase boundary process and processing a part of resulting alkali metal chloride-containing solution (S1) in a downstream alkali metal chloride electrolysis involves: a) preparing phosgene by reacting chlorine with carbon monoxide; b) reacting phosgene with bisphenol (I) in presence of a base and optionally a basic catalyst and organic solvent to give a polycarbonate and (S1), followed by isolating and working-up polycarbonate, separating (S1), oxidating a part of (S1) and recycling chlorine formed to (a) and a part of alkali metal hydroxide solution formed to (b). Preparing polycarbonate by the phase boundary process and processing at least a part of the resulting alkali metal chloride-containing solution in a downstream alkali metal chloride electrolysis, involves: a) preparing phosgene by reacting chlorine with carbon monoxide; b) reacting the phosgene of (a) with at least one bisphenol (I) in the presence of at least one base, optionally at least one basic catalyst, and optionally at least one organic solvent, to give a polycarbonate and an alkali metal chloride-containing solution; c) isolating and working-up the polycarbonate of (b); d) separating the alkali metal chloride-containing solution remaining in (c) from solvent residues and optionally catalyst residues; e) electrochemically oxidating at least a part of the alkali metal chloride-containing solution of (d) to form chlorine, alkali metal hydroxide solution, and optionally hydrogen; where, in (d) the solution is adjusted to a pH of = 8 prior to treatment with adsorbents; f) at least a part of the chlorine prepared in (e) is recycled to (a); and/or g) at least a part of the alkali metal hydroxide solution prepared in (e) is recycled to (b).